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Bioscience, Biotechnology, and Biochemistry Volume 65, 2001 - Issue 2
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Original Articles

Synthesis and Absolute Configuration of MQ-A3 [1-(14'-Methylhexadecanoyl) pyrrolidine], a Novel Aliphatic Pyrrolidine Amide from the Tropical Convolvulaceous Species

Arata YAJIMADepartment of Fermentation Science, Faculty of Applied Biological Science, Tokyo University of Agriculture
&
Goro YABUTADepartment of Fermentation Science, Faculty of Applied Biological Science, Tokyo University of Agriculture
Pages 463-465 | Received 22 Aug 2000, Accepted 13 Oct 2000, Published online: 22 May 2014
 
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Abstract

A novel pyrrolidine amide (MQ-A3) isolated from the tropical convolvulaceous species was synthesized in 5 steps by starting from commercially available 12-bromododecanol and (S)-2-methylbutylbromide. The absolute configuration of the natural product was confirmed by a comparison of the specific rotation values.

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