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Xenobiotica
the fate of foreign compounds in biological systems
Volume 13, 1983 - Issue 11
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Research Article

2-Mercapto-1-methyl-5-methylmercapto-imidazole: a new metabolite of thiamazole

R. Twele Lehrstuhl für Organische Chemie I der Universität Bayreuth, Universitätsstraße 30, Postfach 3008, D-8580, Bayreuth, FR Germany
,
W. Kern Lehrstuhl für Organische Chemie I der Universität Bayreuth, Universitätsstraße 30, Postfach 3008, D-8580, Bayreuth, FR Germany
&
G. Spiteller Lehrstuhl für Organische Chemie I der Universität Bayreuth, Universitätsstraße 30, Postfach 3008, D-8580, Bayreuth, FR Germany
Pages 661-668 | Received 16 Jul 1982, Published online: 22 Sep 2008
 
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Abstract

1. 2-Mercapto-1-methyl-5-methylmercapto-imidazole (13) was found in urine samples of man and rat after intake of thiamazole (1).

2. It is assumed that the metabolite is produced via a N-oxidation intermediate enabling a nucleophilic attack at carbon-5 in the thiazole ring.

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