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Free Radical Research Communications Volume 4, 1988 - Issue 6
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Original Article

Photocatalyzed Anaerobic Oxidation of Nicotinamide Coenzyme Dimers to NAD+ by Adriamycin

Vincenzo Carelli Institute of Pharmaceutical Chemistry and Toxicology, University of Rome “La Sapienza”, Rome, Italy
,
Antonio Casini Institute of Pharmaceutical Chemistry and Toxicology, University of Rome “La Sapienza”, Rome, Italy
,
Alessandro Finazzi-Agro Department of Experimental Medicine and Biochemical Sciences, University of Rome “Tor Vergata”, Rome, Italy
,
Felice Liberatore Institute of Pharmaceutical Chemistry and Toxicology, University of Rome “La Sapienza”, Rome, Italy
&
Silvano Tortorella Institute of Pharmaceutical Chemistry and Toxicology, University of Rome “La Sapienza”, Rome, Italy
Pages 397-402 | Published online: 07 Jul 2009
 
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Abstract

The nicotinamide adenine dinucleotide dimers (NAD)2 obtained by electrochemical reduction of NAD+ are oxidized by adriamycin in anaerobic photocatalyzed reaction yielding NAD+ and 7-deoxyadriamyci-none. Under the same conditions NADH is not oxidized.

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