In-situ monitoring of inorganic and microbial synergistic fouling during nanofi ltration by UTDR

Abstract

This study describes an ultrasonic time-domain refl ectometry (UTDR) as an non-invasive realtime technique for in-situ monitoring of the early-stage CaSO₄ and microbial synergistic fouling on nanofiltration (NF) membranes. The fouling experiments were carried out with 1.0 g/L and 1.5 g/L calcium sulfate solution at the operating pressure of 0.7 MPa, the temperature of 25±0.5°C and the flow rate of 0.13 cm/s. The number of bacteria incubated from lake was 5 × 10⁶ cell/ml. A commercial nanofi ltration membrane was utilized in this study. The permeate flux, rejection and ultrasonic measurements were made at regular intervals during crossfl ow NF. Results show that the flux obtained in the experiment with bacteria declined subtly slower than that without bacteria in the early phase, and then declined to the same level in the later phase of the fouling process. The rejection obtained in the experiment with bacteria was higher than that without. Furthermore, the acoustic measurements indicate that the fouling layer obtained with bacteria was thicker and looser than that without bacteria under the condition of low concentration solution. However, the layer becomes thicker and denser under the condition of high concentration solution. It implies that bacteria could accelerate deposition of inorganic scaling on NF membrane. Independent measurement such as flux-decline date, SEM analysis and weight measurement corroborate the ultrasonic measurement. Overall, this study suggests that the ultrasonic technique, due to its powerful capabilities and its use in monitoring devices, can be of great signifi cance in the membrane industry.

Keywords:

• Nanofiltration
• Membrane fouling
• CaSO₄ and microbial synergistic fouling
• Ultrasonic time-domain reflectometry