Abstract
A novel composite membrane for potential desalination was prepared by coating of sulfonated poly(arylene ether) on the non-woven web. The non-woven web was made of end-group crosslinkable flurorinated poly(arylene ether) nanowires fabricated by electrospinning method. The crosslinked non-woven web was obtained by covalent crosslinking among ethynyl groups at the polymer chain end via thermal curing. The salt rejection and permeability of the crosslinked nonwoven web were controlled by varying degrees of sulfonation (DS) of sulfonated poly(arylene ether). The compostie membranes show the increase of NaCl rejection as DS decreases from 20% to 60%, while water permeability decreases due to the increase of hydrophilicity. The order of salt rejection was as follows: Na2SO4 (88.4%), NaCl (79.3%), MgSO4 (70.2%), Mg2Cl2 (62.3%).