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Combustion Science and Technology Volume 45, 1986 - Issue 5-6
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Original Articles

A Flow Reactor Study of the Oxidation of Iso-butylene and an Iso-butyleneln-octane Mixture

K. Brezinsky Department of Mechanical and AerospaceEngineering, Princeton University, Princeton, New Jersey, 08544
&
F. L. Dryer Department of Mechanical and AerospaceEngineering, Princeton University, Princeton, New Jersey, 08544
Pages 225-232 | Received 18 Mar 1985, Published online: 25 Apr 2007

Citations (39)

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P. DAGAUT & M. CATHONNET. (1998) Isobutene Oxidation and Ignition: Experimental and Detailed Kinetic Modeling Study. Combustion Science and Technology 137:1-6, pages 237-275.
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C. MORLEY. (1987) A Fundamentally Based Correlation Between Alkane Structure and Octane Number. Combustion Science and Technology 55:4-6, pages 115-123.
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Articles from other publishers (37)

Chong-Wen Zhou, Aamir Farooq, Lijun Yang & Alexander M. Mebel. (2022) Combustion chemistry of alkenes and alkadienes. Progress in Energy and Combustion Science 90, pages 100983.
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Tobias Preitschopf, Florian Hirsch, Alexander K. Lemmens, Anouk M. Rijs & Ingo Fischer. (2022) The gas-phase infrared spectra of the 2-methylallyl radical and its high-temperature reaction products. Physical Chemistry Chemical Physics 24:13, pages 7682-7690.
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Sabrina Gossler, Lena Ruwe, Wenhao Yuan, Jiuzhong Yang, Xiamin Chen, Steffen Schmitt, Lubow Maier, Katharina Kohse-Höinghaus, Fei Qi & Olaf Deutschmann. (2021) Exploring the interaction kinetics of butene isomers and NOx at low temperatures and diluted conditions. Combustion and Flame 233, pages 111557.
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Juan Guzman & Kenneth Brezinsky. (2021) Experimental and modeling study of the oxidation of F-24 jet fuel, and its mixture with an iso-paraffinic synthetic jet fuel, ATJ. Combustion and Flame 224, pages 108-125.
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Qianpeng Wang, Xingyan Tang, Jiuzhong Yang, Yitong Zhai, Yan Zhang, Chuangchuang Cao & Juan Wang. (2019) Investigations on Pyrolysis of Isooctane at Low and Atmospheric Pressures. Energy & Fuels 33:4, pages 3518-3528.
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A. Parandaman & B. Rajakumar. (2017) Addition and abstraction kinetics of H atom with propylene and isobutylene between 200 and 2500 K: A DFT study. Chemical Physics 491, pages 82-94.
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Kun Wang, Stephanie M. Villano & Anthony M. Dean. (2017) Experimental and kinetic modeling study of butene isomer pyrolysis: Part II. Isobutene. Combustion and Flame 176, pages 23-37.
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Fethi Khaled, Binod Raj Giri & Aamir Farooq. (2017) A high-temperature shock tube kinetic study for the branching ratios of isobutene + OH reaction. Proceedings of the Combustion Institute 36:1, pages 265-272.
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Ruben De Bruycker, Olivier Herbinet, Hans-Heinrich Carstensen, Frédérique Battin-Leclerc & Kevin M. Van Geem. (2016) Understanding the reactivity of unsaturated alcohols: Experimental and kinetic modeling study of the pyrolysis and oxidation of 3-methyl-2-butenol and 3-methyl-3-butenol. Combustion and Flame 171, pages 237-251.
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Pradeep Singh & Chih-Jen Sung. (2016) PAH formation in counterflow non-premixed flames of butane and butanol isomers. Combustion and Flame 170, pages 91-110.
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Chong-Wen Zhou, Yang Li, Eoin O'Connor, Kieran P. Somers, Sébastien Thion, Charles Keesee, Olivier Mathieu, Eric L. Petersen, Trent A. DeVerter, Matthew A. Oehlschlaeger, Goutham Kukkadapu, Chih-Jen Sung, Majed Alrefae, Fathi Khaled, Aamir Farooq, Patricia Dirrenberger, Pierre-Alexandre Glaude, Frédérique Battin-Leclerc, Jeffrey Santner, Yiguang Ju, Timothy Held, Francis M. Haas, Frederick L. Dryer & Henry J. Curran. (2016) A comprehensive experimental and modeling study of isobutene oxidation. Combustion and Flame 167, pages 353-379.
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Sang Hee Won, Francis M. Haas, Aniket Tekawade, Graham Kosiba, Matthew A. Oehlschlaeger, Stephen Dooley & Frederick L. Dryer. (2016) Combustion characteristics of C4 iso-alkane oligomers: Experimental characterization of iso-dodecane as a jet fuel surrogate component. Combustion and Flame 165, pages 137-143.
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Sijie Li, S. Mani Sarathy, David F. Davidson, Ronald K. Hanson & Charles K. Westbrook. (2015) Shock tube and modeling study of 2,7-dimethyloctane pyrolysis and oxidation. Combustion and Flame 162:5, pages 2296-2306.
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Yann Fenard, Philippe Dagaut, Guillaume Dayma, Fabien Halter & Fabrice Foucher. (2015) Experimental and kinetic modeling study of trans-2-butene oxidation in a jet-stirred reactor and a combustion bomb. Proceedings of the Combustion Institute 35:1, pages 317-324.
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R.M. Spearrin, S. Li, D.F. Davidson, J.B. Jeffries & R.K. Hanson. (2015) High-temperature iso-butene absorption diagnostic for shock tube kinetics using a pulsed quantum cascade laser near 11.3 μm. Proceedings of the Combustion Institute 35:3, pages 3645-3651.
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Frederick L. Dryer, Francis M. Haas, Jeffrey Santner, Tanvir I. Farouk & Marcos Chaos. (2014) Interpreting chemical kinetics from complex reaction–advection–diffusion systems: Modeling of flow reactors and related experiments. Progress in Energy and Combustion Science 44, pages 19-39.
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Sijie Li, Ashley Campos, David F. Davidson & Ronald K. Hanson. (2014) Shock tube measurements of branched alkane ignition delay times. Fuel 118, pages 398-405.
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Yijun Zhang, Jianghuai Cai, Long Zhao, Jiuzhong Yang, Hanfeng Jin, Zhanjun Cheng, Yuyang Li, Lidong Zhang & Fei Qi. (2012) An experimental and kinetic modeling study of three butene isomers pyrolysis at low pressure. Combustion and Flame 159:3, pages 905-917.
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Gabriel M. P. Just, Bogdan Negru, Dayoung Park & Daniel M. Neumark. (2012) Photodissociation of isobutene at 193 nm. Phys. Chem. Chem. Phys. 14:2, pages 675-680.
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Patrick Oßwald, Hanna Güldenberg, Katharina Kohse-Höinghaus, Bin Yang, Tao Yuan & Fei Qi. (2011) Combustion of butanol isomers – A detailed molecular beam mass spectrometry investigation of their flame chemistry. Combustion and Flame 158:1, pages 2-15.
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Véronique Dias & Jacques Vandooren. (2010) Experimental and modeling study of a lean premixed iso-butene/hydrogen/oxygen/argon flame. Fuel 89:9, pages 2633-2639.
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Kenji Yasunaga, Yuma Kuraguchi, Ryota Ikeuchi, Hiromitsu Masaoka, Osamu Takahashi, Tohru Koike & Yoshiaki Hidaka. (2009) Shock tube and modeling study of isobutene pyrolysis and oxidation. Proceedings of the Combustion Institute 32:1, pages 453-460.
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M. Yahyaoui, N. Djebaili-Chaumeix, P. Dagaut & C.-E. Paillard. (2008) Ethyl Tertiary Butyl Ether Ignition and Combustion Using a Shock Tube and Spherical Bomb. Energy & Fuels 22:6, pages 3701-3708.
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Marcos Chaos, Andrei Kazakov, Zhenwei Zhao & Frederick L. Dryer. (2007) A high‐temperature chemical kinetic model for primary reference fuels. International Journal of Chemical Kinetics 39:7, pages 399-414.
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X. L. Zheng, H. Y. Sun & C. K. Law. (2005) Thermochemical and Kinetic Analyses on Oxidation of Isobutenyl Radical and 2-Hydroperoxymethyl-2-propenyl Radical. The Journal of Physical Chemistry A 109:40, pages 9044-9053.
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Charles S McEnally, Dragos M Ciuparu & Lisa D Pfefferle. (2003) Experimental study of fuel decomposition and hydrocarbon growth processes for practical fuel components: heptanes. Combustion and Flame 134:4, pages 339-353.
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Chiung-Ju Chen & Joseph W. Bozzelli. (2000) Thermochemical Property, Pathway and Kinetic Analysis on the Reactions of Allylic Isobutenyl Radical with O 2 :  an Elementary Reaction Mechanism for Isobutene Oxidation . The Journal of Physical Chemistry A 104:43, pages 9715-9732.
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Charles S. McEnally & Lisa D. Pfefferle. (1998) Species and Soot Concentration Measurements in a Methane/Air Nonpremixed Flame Doped With C4 Hydrocarbons. Combustion and Flame 115:1-2, pages 81-92.
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J. C. Bauge, F. Battin-Leclerc & F. Baronnet. (1998) Experimental and modeling study of the oxidation of isobutene. International Journal of Chemical Kinetics 30:9, pages 629-640.
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Karlhein Hoyermann & Frank Nacke. (1996) Elementary reactions of the methoxymethyl radical in the gas phase: CH3OCH3+F, CH2OCH3+CH2OCH3, CH2OCH3+O2 and CH2OCH3+O. Symposium (International) on Combustion 26:1, pages 505-512.
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Jeffrey A. Gray & Charles K. Westbrook. (2004) High‐temperature ignition of propane with MTBE as an additive: Shock tube experiments and modeling. International Journal of Chemical Kinetics 26:7, pages 757-770.
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Henry J. Curran, Mary P. Dunphy, John M. Simmie, Charles K. Westbrook & William J. Pitz. (1992) Shock tube ignition of ethanol, isobutene and MTBE: Experiments and modeling. Symposium (International) on Combustion 24:1, pages 769-776.
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Y. Henig, S. Addagarla, D. L. Miller, R. D. Wilk & N. P. Cernansky. Autoignition of n-Butane/lsobutane Blends in a Knock Research Engine. Autoignition of n-Butane/lsobutane Blends in a Knock Research Engine.
K. Brezinsky, G.T. Linteris, T.A. Litzinger & I. Glassman. (1988) High temperature oxidation of n-alkyl benzenes. Symposium (International) on Combustion 21:1, pages 833-840.
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E.I. Axelsson, K. Brezinsky, F.L. Dryer, W.J. Pitz & C.K. Westbrook. (1988) Chemical kinetic modeling of the oxidation of large alkane fuels: N-octane and iso-octane. Symposium (International) on Combustion 21:1, pages 783-793.
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Gregory P. Smith. (2004) Laser pyrolysis studies of OH reaction rates with several butenes at 1200 K. International Journal of Chemical Kinetics 19:4, pages 269-276.
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C. K. Westbrook & W. J. Pitz. 1987. Complex Chemical Reaction Systems. Complex Chemical Reaction Systems 39 54 .

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