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Ferroelectrics Volume 397, 2010 - Issue 1
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Original Articles

The Effect of PbO-Nonstoichiometry on Dielectric and Semiconducting Properties of PbFe0.5Nb0.5O3-Based Ceramics

I. P. Raevski Institute of Physics and Physical Department of Southern Federal University, Stachki Ave. 194, Rostov on Don, 344090, Russia
,
S. P. Kubrin Institute of Physics and Physical Department of Southern Federal University, Stachki Ave. 194, Rostov on Don, 344090, Russia
,
S. A. Kovrigina Institute of Physics and Physical Department of Southern Federal University, Stachki Ave. 194, Rostov on Don, 344090, Russia
,
S. I. Raevskaya Institute of Physics and Physical Department of Southern Federal University, Stachki Ave. 194, Rostov on Don, 344090, Russia
,
V. V. Titov Institute of Physics and Physical Department of Southern Federal University, Stachki Ave. 194, Rostov on Don, 344090, Russia
,
A. S. Emelyanov Institute of Physics and Physical Department of Southern Federal University, Stachki Ave. 194, Rostov on Don, 344090, Russia
,
M. A. Malitskaya Institute of Physics and Physical Department of Southern Federal University, Stachki Ave. 194, Rostov on Don, 344090, Russia
&
I. N. Zakharchenko Institute of Physics and Physical Department of Southern Federal University, Stachki Ave. 194, Rostov on Don, 344090, Russia
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Pages 96-101 | Received 22 Sep 2009, Accepted 20 Jan 2010, Published online: 23 Jun 2010

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S. I. Raevskaya, M. A. Malitskaya, E. I. Sitalo, I. P. Raevski, A. G. Lutokhin, Y. N. Zakharov, V. V. Titov, I. N. Zakharchenko & C.-C. Chou. (2021) x,T-phase diagram of PbFe1/2Ta1/2O3-PbTiO3 solid solution. Ferroelectrics 576:1, pages 8-18.
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S. I. Raevskaya, V. V. Titov, I. P. Raevski, S. P. Kubrin, C.-C. Chou, S. I. Shevtsova, M. A. Malitskaya & I. N. Zakharchenko. (2020) Studies of ferroelectric and magnetic phase transitions in Pb(Fe0.5Nb0.5)1-xCexO3 multiferroic ceramics. Ferroelectrics 567:1, pages 230-243.
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S. I. Raevskaya, S. P. Kubrin, I. P. Raevski, C. C. Chou, H. Chen, V. V. Titov, M. A. Malitskaya, D. A. Sarychev & I. N. Zakharchenko. (2017) The effect of quenching on semiconductive properties and magnetic phase transition temperature of multiferroic Pb(Fe1/2Nb1/2)O3 ceramics. Ferroelectrics 509:1, pages 64-73.
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S. I. Raevskaya, S. P. Kubrin, A. V. Pushkarev, N. M. Olekhnovich, Yu. V. Radyush, V. V. Titov, M. A. Malitskaya, I. N. Zakharchenko, H. Chen, C.-C. Chou & I. P. Raevski. (2017) Structural, dielectric, and Mossbauer studies of multiferroic (1-x)PbFe0.5Nb0.5O3 - xPbCr0.5Nb0.5O3 solid solution ceramics obtained by usual sintering and by high-pressure synthesis. Ferroelectrics 509:1, pages 40-49.
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I. P. Raevski, A. V. Pushkarev, S. I. Raevskaya, N. M. Olekhnovich, Yu. V. Radyush, S. P. Kubrin, H. Chen, C.-C. Chou, D. A. Sarychev, V. V. Titov & M. A. Malitskaya. (2016) Structural, dielectric and Mossbauer studies of PbFe0.5Sb0.5O3 ceramics with differing degree of compositional ordering. Ferroelectrics 501:1, pages 154-164.
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A. A. Gusev, S. I. Raevskaya, I. P. Raevski, V. P. Isupov, E. G. Avvakumov, S. P. Kubrin, H. Chen, V. V. Titov, T. A. Minasyan, C.- C. Chou, S. V. Titov & M. A. Malitskaya. (2016) Electron microscopy, XRD, dielectric, and Mossbauer studies of Li-doped Pb(Fe0.5Nb0.5)O3 ceramics sintered from mechanically activated powders. Ferroelectrics 496:1, pages 250-260.
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S. I. Raevskaya, V. V. Titov, I. P. Raevski, S. P. Kubrin, H. Chen, C.-C. Chou, D. A. Sarychev, S. I. Shevtsova, M. A. Malitskaya & I. N. Zakharchenko. (2016) Electron microscopy, XRD, Mossbauer and dielectric studies of Pb(Fe0.5Nb0.5)1-xSnxO3 multiferroic ceramics. Ferroelectrics 496:1, pages 213-224.
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A. A. Gusev, I. P. Raevski, E. G. Avvakumov, V. P. Isupov, S. I. Raevskaya, H. Chen, V. V. Titov, C.-C. Chou, S. P. Kubrin, S. V. Titov & M. A. Malitskaya. (2015) Dielectric Properties of Undoped and Li-doped Pb(Fe1/2Nb1/2)O3 Ceramics Sintered from Mechanochemically Synthesized Powders. Ferroelectrics 475:1, pages 61-67.
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I. P. Raevski, V. V. Titov, V. V. Laguta, M. Marysko, S. P. Kubrin, H. Chen, C.-C. Chou, A. V. Blazhevich, S. I. Raevskaya, D. A. Sarychev, T. A. Minasyan, L. A. Pustovaya, I. N. Zakharchenko & M. A. Malitskaya. (2015) Comparative Studies of Ferroelectric and Magnetic Phase Transitions in Pb(Fe1/2Nb1/2)O3-PbMO3 (M-Ti, Zr) Multiferroic Solid Solutions. Ferroelectrics 475:1, pages 20-30.
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N.S. Druzhinina, Yu.I. Yuzyuk, I.P. Raevski, M. El Marssi, V.V. Laguta & S.I. Raevskaya. (2012) Raman Spectra of PbFe0.5Nb0.5O3 Multiferroic Single Crystals and Ceramics. Ferroelectrics 438:1, pages 107-114.
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E.I. Sitalo, I.P. Raevski, A.G. Lutokhin, S.P. Kubrin, S.I. Raevskaya, Yu.N. Zakharov, M.A. Malitskaya, A.V. Blazhevich & I.N. Zakharchenko. (2011) Piezoelectric Properties of PbFe1/2Nb1/2O3–PbTiO3 Ceramics from the Morphotropic Phase Boundary Compositional Range. Ferroelectrics 419:1, pages 76-82.
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Articles from other publishers (16)

S. Belkhadir, S. Khardazi, D. Mezzane, M. Amjoud, O. Shapovalova, V. Laguta, I. Raevski, K. Pushkarova, I. Lukyanchuk & M. El Marssi. (2022) Effect of Sn on the energy storage performance and electric conduction mechanisms of BCZT ceramic. Materials Today: Proceedings 51, pages 2005-2014.
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Nicole Bartek, Vladimir V. Shvartsman, Soma Salamon, Heiko Wende & Doru C. Lupascu. (2021) Influence of calcination and sintering temperatures on dielectric and magnetic properties of Pb(Fe0.5Nb0.5)O3 ceramics synthesized by the solid state method. Ceramics International 47:16, pages 23396-23403.
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A. A. Gusev, I. P. Raevski & V. P. Isupov. (2020) Formation of Perovskite and Pyrochlore Phases during Mechanochemical Synthesis of Lead Ferroniobate. Inorganic Materials 56:9, pages 968-974.
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A.T. Kozakov, A.G. Kochur, A.V. Nikolskii, I.P. Raevski, S.P. Kubrin, S.I. Raevskaya, V.V. Titov, A.A. Gusev, V.P. Isupov, G. Li & I.N. Zakharchenko. (2020) Valence state of B and Ta cations in the AB1/2Ta1/2O3 ceramics (A = Ca, Sr, Ba, Pb; B = Fe, Sc) from X-ray photoelectron and Mössbauer spectroscopy data. Journal of Electron Spectroscopy and Related Phenomena 239, pages 146918.
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Yizheng Bao, Xianlin Dong & Genshui Wang. (2019) Latest Designing Principle on the Microstructure and Lattice-Structure for High-Energy-Density Antiferroelectric Materials in Fast Discharging Applications. ACS Applied Energy Materials 2:9, pages 6939-6951.
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I. P. Raevski, V. V. Titov, Haydn Chen, I. N. Zakharchenko, S. I. Raevskaya & S. I. Shevtsova. (2019) Evolution of dielectric properties in the (1−x) PbFe0.5Nb0.5O3–xBaFe0.5Nb0.5O3 solid solution system. Journal of Materials Science 54:16, pages 10984-10997.
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I. P. Raevski, A. A. Gusev, V. P. Isupov, M. A. Evstigneeva, S. I. Raevskaya, A. G. Lutokhin, S. P. Kubrin, I. N. Zakharchenko, Y. A. Kuprina, V. V. Titov, M. A. Malitskaya, G. R. Li & O. A. Bunina. 2019. Advanced Materials. Advanced Materials 47 60 .
I. P. Raevski, Yu. A. Kuprina, I. N. Zakharchenko, A. A. Gusev, V. P. Isupov, O. A. Bunina, V. V. Titov, S. I. Raevskaya, M. A. Malitskaya, A. V. Blazhevich, S. V. Orlov & E. I. Sitalo. 2018. Advanced Materials. Advanced Materials 209 224 .
A. T. Kozakov, A. G. Kochur, A. V. Nikolskii, I. P. Raevski, S. P. Kubrin, S. I. Raevskaya, V. V. Titov, M. A. Malitskaya, I. N. Zakharchenko & S. I. Shevtsova. (2017) Phase transitions, dielectric properties and valence of magnetic ions in PbFe0.5−x Cr x Nb0.5O3 multiferroic ceramics. Journal of Materials Science 52:17, pages 10140-10155.
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A. N. Pavlov, I. P. Raevski, T. A. Minasyan, S. I. Raevskaya, M. A. Malitskaya, V. V. Titov, D. Pandey & A. A. Bokov. 2017. Advanced Materials. Advanced Materials 167 178 .
Maalti Puri, Shalini Bahel, I.P. Raevski & Sukhleen Bindra Narang. (2016) Structural, dielectric and magnetic properties of (Pb1−Ca )(Fe0.5Nb0.5)O3 solid solution ceramics. Journal of Magnetism and Magnetic Materials 407, pages 195-200.
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I. P. Raevski, S. P. Kubrin, A. V. Blazhevich, M. S. Molokeev, S. V. Misjul, E. V. Eremin, H. Chen, C.-C. Chou, E. I. Sitalo, S. I. Raevskaya, V. V. Titov, D. A. Sarychev, M. A. Malitskaya & I. N. Zakharchenko. 2014. Advanced Materials. Advanced Materials 109 120 .
I. P. Raevski, S. P. Kubrin, S. I. Raevskaya, S. A. Prosandeev, M. A. Malitskaya, V. V. Titov, D. A. Sarychev, A. V. Blazhevich & I. N. Zakharchenko. (2012) Dielectric and Mossbauer studies of ferroelectric and magnetic phase transitions in a-site and b-site substituted multiferroic PbFe 0.5 Nb 0.5 O 3 . IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control 59:9, pages 1872-1878.
Crossref
A. V. Blazhevich, I. P. Raevski, S. P. Kubrin, E. I. Sitalo, S. I. Raevskaya, V. V. Titov, D. A. Sarychev, M. A. Malitskaya & I. N. Zakharchenko. (2012) Ferroelectric and magnetic phase transitions in multiferroic PbFe<inf>0.5</inf>Ta<inf>0.5</inf>O<inf>3</inf>-PbTiO<inf>3</inf> solid solutions. Ferroelectric and magnetic phase transitions in multiferroic PbFe<inf>0.5</inf>Ta<inf>0.5</inf>O<inf>3</inf>-PbTiO<inf>3</inf> solid solutions.
E. I. Sitalo, I. P. Raevski, A. G. Lutokhin, A. V. Blazhevich, S. P. Kubrin, S. I. Raevskaya, Y. N. Zakharov, M. A. Malitskaya, V. V. Titov & I. N. Zakharchenko. (2011) Dielectric and piezoelectric properties of PbFe 1/2 Nb 1/2 O 3 -PbTiO 3 ceramics from the morphotropic phase boundary compositional range . IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control 58:9, pages 1914-1919.
Crossref
I.P. Raevski, S.P. Kubrin, S.I. Raevskaya, S.A. Prosandeev, M.A. Malitskaya, Yu.N. Zakharov, A.G. Lutokhin, V.V. Titov, D. A. Sarychev, E.I. Sitalo, A.V. Blazhevich & I.N. Zakharchenko. (2011) The effect of A-site and B-site ion substitutions on the temperatures of ferroelectric and magnetic phase transitions in multiferroic PbFe<inf>0.5</inf>Nb<inf>0.5</inf>O<inf>3</inf>. The effect of A-site and B-site ion substitutions on the temperatures of ferroelectric and magnetic phase transitions in multiferroic PbFe<inf>0.5</inf>Nb<inf>0.5</inf>O<inf>3</inf>.

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