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The Journal of Adhesion Volume 58, 1996 - Issue 1-2
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Original Articles

Electrochemistry as a Tool to Monitor Lewis Acid-Base Reactions between Methacrylonitrile and Metallic Surfaces: A Theoretical and Experimental Proposal

Christophe Bureau CEA-Saclay, DSM-DRECAM-SRSIM, bǎt. 462, F-91191, Gif-sur-Yvette Cedex, France
,
Guy Deniau CEA-Saclay, DSM-DRECAM-SRSIM, bǎt. 462, F-91191, Gif-sur-Yvette Cedex, France
,
Pascal Viel CEA-Saclay, DSM-DRECAM-SRSIM, bǎt. 462, F-91191, Gif-sur-Yvette Cedex, France
,
Gerard Lecayon CEA-Saclay, DSM-DRECAM-SRSIM, bǎt. 462, F-91191, Gif-sur-Yvette Cedex, France
&
Joseph Delhalle Laboratoire de Chimie Théoretique Appliquée, Facultés Universitaires Notre-Dame de la Paix, 61, rue de Bruxelles, B-5000, Namur, Belgium
Pages 101-121 | Received 14 Dec 1995, Published online: 24 Sep 2006

Citations (24)

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J. Charlier, V. Detalle, C. Bureau, F. Valin & G. Lécayon. (1998) Influence of the Electronic Structure of the Metal at the Polymer/Metal Interface: A Tentative Interpretation on the Basis of Lewis Acid-Base Reactions. The Journal of Adhesion 66:1-4, pages 275-287.
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Articles from other publishers (23)

Alice Mesnage, Guy Deniau, Lorraine Tessier, Vincent Mévellec & Serge Palacin. (2011) Localized grafting through chemical lift-off. Applied Surface Science 257:17, pages 7805-7812.
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Daniel Bélanger & Jean Pinson. (2011) Electrografting: a powerful method for surface modification. Chemical Society Reviews 40:7, pages 3995.
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Catherine Combellas, Frédéric Kanoufi & Sandra Nunige. (2007) Surface Modification of Halogenated Polymers. 10. Redox Catalysis Induction of the Polymerization of Vinylic Monomers. Application to the Localized Graft Copolymerization of Poly(tetrafluoroethylene) Surfaces by Vinylic Monomers. Chemistry of Materials 19:15, pages 3830-3839.
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Guy Deniau, Laurent Azoulay, Luc Bougerolles & Serge Palacin. (2006) Surface Electroinitiated Emulsion Polymerization:  Grafted Organic Coatings from Aqueous Solutions. Chemistry of Materials 18:23, pages 5421-5428.
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Guy Deniau, Laurent Azoulay, Pascale Jégou, Gilles Le Chevallier & Serge Palacin. (2006) Carbon-to-metal bonds: Electrochemical reduction of 2-butenenitrile. Surface Science 600:3, pages 675-684.
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Serge Palacin, Christophe Bureau, Julienne Charlier, Guy Deniau, Brigitte Mouanda & Pascal Viel. (2004) Molecule-to-Metal Bonds: Electrografting Polymers on Conducting Surfaces. ChemPhysChem 5:10, pages 1468-1481.
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J. Charlier, S. Ameur, J. P. Bourgoin, C. Bureau & S. Palacin. (2004) Mask-free Localized Grafting of Organic Polymers at the Micrometer or Submicrometer Scale on Composite Conductors or Semiconductor Substrates. Advanced Functional Materials 14:2, pages 125-132.
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C. Bureau, S. Kranias, X. Crispin & J. -L. Bredas. 2002. Quantum Systems in Chemistry and Physics Volume 2. Quantum Systems in Chemistry and Physics Volume 2 169 192 .
Xavier Crispin, V. M. Geskin, C. Bureau, R. Lazzaroni, W. Schmickler & J. L. Brédas. (2001) A density functional model for tuning the charge transfer between a transition metal electrode and a chemisorbed molecule via the electrode potential. The Journal of Chemical Physics 115:22, pages 10493-10499.
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X Crispin, R Lazzaroni, A Crispin, V.M Geskin, J.L Brédas & W.R Salaneck. (2001) Understanding the initial stages of polymer grafting on metals: a photoelectron spectroscopy study of acrylonitrile adsorption on transition metal surfaces. Journal of Electron Spectroscopy and Related Phenomena 121:1-3, pages 57-74.
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Guy Deniau, Pascal Viel, Christophe Bureau, Gilbert Zalczer, Patricia Lixon & Serge Palacin. (2001) Study of the polymers obtained by electroreduction of methacrylonitrile. Journal of Electroanalytical Chemistry 505:1-2, pages 33-43.
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Christophe Bureau. (1999) Polymerization reaction coupled to charge transfer: propagation versus termination as a source of permanent travelling waves and multi-peak voltammograms. Journal of Electroanalytical Chemistry 479:1, pages 43-56.
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X. Crispin, C. Bureau, V. M. Geskin, R. Lazzaroni, W. R. Salaneck & J. L. Brédas. (1999) Chemisorption of acrylonitrile on the Cu(100) surface: A local density functional study. The Journal of Chemical Physics 111:7, pages 3237-3251.
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Pascal Viel, Christophe Bureau, Guy Deniau, Gilbert Zalczer & Gérard Lecayon. (1999) Electropolymerization of methacrylonitrile on a rotating disk electrode at high spinning rate. Journal of Electroanalytical Chemistry 470:1, pages 14-22.
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Christophe Bureau, Jean-Maı̈k Soudan & Gérard Lecayon. (1999) On the influence of RRC and RSC dimerizations on the shape of semi-integrated voltammograms: a mixed asymptotic and numerical analysis. Electrochimica Acta 44:19, pages 3303-3320.
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Julienne Charlier, Christophe Bureau & Gérard Lecayon. (1999) Electropolymerization of methacrylonitrile and N-vinyl-2-pyrrolidone as probed by an EQCM. Journal of Electroanalytical Chemistry 465:2, pages 200-208.
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Xavier Crispin, Christophe Bureau, Victor Geskin, Roberto Lazzaroni & Jean‐Luc Brédas. (1999) Local Density Functional Study of Copper Clusters: A Comparison between Real Clusters, Model Surface Clusters, and the Actual Metal Surface. European Journal of Inorganic Chemistry 1999:2, pages 349-360.
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X. Crispin, R. Lazzaroni, V. Geskin, N. Baute, P. Dubois, R. Jérôme & J. L. Brédas. (1998) Controlling the Electrografting of Polymers onto Transition Metal Surfaces through Solvent vs Monomer Adsorption. Journal of the American Chemical Society 121:1, pages 176-187.
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Guy Deniau, Tristan Thomé, Daniel Gaudin, Christophe Bureau & Gérard Lécayon. (1998) Coupled chemistry revisited in the tentative cathodic electropolymerization of 2-butenenitrile. Journal of Electroanalytical Chemistry 451:1-2, pages 145-161.
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C. Doneux, R. Caudano, J. Delhalle, E. Léonard-Stibbe, J. Charlier, C. Bureau, J. Tanguy & G. Lécayon. (1997) Polymerization of N -Vinyl-2-Pyrrolidone under Anodic Polarization:  Characterization of the Modified Electrode and Study of the Grafting Mechanism . Langmuir 13:18, pages 4898-4905.
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Christophe Bureau & Gérard Lécayon. (1997) On a modeling of voltage-application to metallic electrodes using density functional theory. The Journal of Chemical Physics 106:21, pages 8821-8829.
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Christophe Bureau, Guy Deniau, Pascal Viel & Gérard Lecayon. (1997) Comments on “The Electroreduction of Acrylonitrile:  A New Insight into the Mechanism” by Mertens et al.. Macromolecules 30:2, pages 333-336.
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Christophe Bureau & Delano P. Chong. (1997) Density functional calculations of core-electron binding energies of amines. Application to (CH3)3NNi and (CH3)4N+Ni. Chemical Physics Letters 264:1-2, pages 186-192.
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