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Journal of Macromolecular Science: Part A - Chemistry Volume 4, 1970 - Issue 7
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Original Articles

Monomer Reactivity Ratios from High Conversion Copolymerization of Styrene with meta- and with para-Divinylbenzene

Richard H. Wiley Department of Chemistry, Hunter College of the City University of New York, New York, New York, 10021
,
S. Prabhakara Rao Department of Chemistry, Hunter College of the City University of New York, New York, New York, 10021
,
Jung-Il Jin Department of Chemistry, Hunter College of the City University of New York, New York, New York, 10021
&
K. S. Kim Department of Chemistry, Hunter College of the City University of New York, New York, New York, 10021
Pages 1453-1462 | Received 16 Mar 1970, Accepted 05 Feb 1970, Published online: 13 Dec 2006

Citations (23)

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Read on this site (2)

C.D. Frickm, A. Rudin & R.H. Wiley. (1981) Reactivity Ratios for Divinylbenzene and Ethylene Glycol Dimethacrylate Copolymerizations with Styrene and Methyl Methacrylate. Journal of Macromolecular Science: Part A - Chemistry 16:7, pages 1275-1282.
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RichardH. Wiley & Ki Soo Kim. (1974) Ion Exchange Equilibrium Studies on Sulfonated Polystyrene Cross-Linked with Pure Divinylbenzenes. Journal of Macromolecular Science: Part A - Chemistry 8:4, pages 687-700.
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Articles from other publishers (21)

Yung‐Chun Lin, Chang Liu, Amit K. Tripathi & John G. Tsavalas. (2023) Early bird gets the network: The relative importance of reactivity ratios, Ψ parameter, and crosslinker level on gel formation in FRP . The Canadian Journal of Chemical Engineering 101:9, pages 5382-5394.
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. 2011. Hypercrosslinked Polymeric Networks and Adsorbing Materials. Hypercrosslinked Polymeric Networks and Adsorbing Materials 151 163 .
H.-P. Brack, D. Fischer, G. Peter, M. Slaski & G. G. Scherer. (2004) Infrared and Raman spectroscopic investigation of crosslinked polystyrenes and radiation-grafted films. Journal of Polymer Science Part A: Polymer Chemistry 42:1, pages 59-75.
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Yanhong Li, Yunge Fan & Jianbiao Ma. (2002) The thermal properties of porous polydivinylbenzene beads. Reactive and Functional Polymers 50:1, pages 57-65.
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Yanhong Li, Yunge Fan & Jianbiao Ma. (2001) Thermal, physical and chemical stability of porous polystyrene-type beads with different degrees of crosslinking. Polymer Degradation and Stability 73:1, pages 163-167.
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S. Sajjadi, S.A.M. Keshavarz & M. Nekoomanesh. (1996) Kinetic investigation of the free-radical crosslinking copolymerization of styrene with a mixture of divinylbenzene isomers acting as the crosslinker. Polymer 37:18, pages 4141-4148.
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Ulku S. Ramelow & Qing Hua Qiu. (2003) Monomer reactivity ratios in UV‐initiated free‐radical copolymerization reactions. Journal of Applied Polymer Science 57:8, pages 911-920.
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B. Thomson, A. Rudin & G. Lajoie. (2003) Dispersion copolymerization of styrene and divinylbenzene: Synthesis of monodisperse, uniformly crosslinked particles. Journal of Polymer Science Part A: Polymer Chemistry 33:3, pages 345-357.
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Zheng‐You Ding, Shenmin Ma, Dennis Kriz, J. J. Aklonis & R. Salovey. (2003) Model filled polymers. IX. Synthesis of uniformly crosslinked polystyrene microbeads. Journal of Polymer Science Part B: Polymer Physics 30:11, pages 1189-1194.
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Shiping Zhu & Archie Hamielec. (2011) Kinetics of polymeric network synthesis via free‐radical mechanisms ‐ polymerization and polymer modification. Makromolekulare Chemie. Macromolecular Symposia 63:1, pages 135-182.
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Z. Y. Ding, J. J. Aklonis & R. Salovey. (2003) Model filled polymers. VI. Determination of the crosslink density of polymeric beads by swelling. Journal of Polymer Science Part B: Polymer Physics 29:8, pages 1035-1038.
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Jiang Lu, Wang Shouting & He Binglin. (1990) The mechanism of copolymerization of vinyl/divinyl monomers. VII the role of pendant double bonds in network formation during copolymerization of styrene and divinylbenzene. Reactive Polymers 12:3, pages 269-275.
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Antonios G. Mikos, Christos G. Takoudis & Nikolaos A. Peppas. (1987) Evidence of unequal vinyl group reactivity in copolymerization/crosslinking reactions of mono- and divinyl comonomers. Polymer 28:6, pages 998-1004.
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Gérard Hild & Rouzi Okasha. (2003) Kinetic investigation of the free radical crosslinking copolymerization in the pre‐gel state, 1. Styrene/ m ‐ and p ‐divinylbenzene systems . Die Makromolekulare Chemie 186:1, pages 93-110.
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Johannes Karl Fink. (2003) Kinetics of crosslinking copolymerization of styrene with symmetric divinyl compounds. Journal of Polymer Science: Polymer Chemistry Edition 19:1, pages 195-202.
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A. N. Zeldin, L. E. Kukacka, J. Fontana & N. Carciello. (1981) Properties and structure of polymer concrete composite material with divinyl benzene as a crosslinking agent. Polymer Composites 2:1, pages 1-7.
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P. W. Kwant. (2003) Kinetics of the copolymerization of styrene with small quantities of divinylbenzenes. Journal of Polymer Science: Polymer Chemistry Edition 17:5, pages 1331-1338.
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Yasuhiro Kagiyama, Kazuo Shikata & Yukio Mizutani. (2003) Copolymerization of styrene– m ‐divinylbenzene in the presence of poly(vinyl chloride) . Journal of Applied Polymer Science 23:5, pages 1309-1318.
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R. Van Der Meer, H. N. Linssen & A. L. German. (2003) Improved methods of estimating monomer reactivity ratios in copolymerization by considering experimental errors in both variables. Journal of Polymer Science: Polymer Chemistry Edition 16:11, pages 2915-2930.
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G. Schwachula. (2007) Calculation of the copolymerization parameters in the ternary copolymerization system of styrene/ m ‐divinyl‐benzene/ p ‐divinylbenzene . Journal of Polymer Science: Polymer Symposia 53:1, pages 107-112.
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A. Rudin & R. G. Yule. (2003) Effects of temperature on styrene–methacrylonitrile copolymerization. Journal of Polymer Science Part A-1: Polymer Chemistry 9:10, pages 3009-3025.
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