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Original Articles

Another Look at Long-Chain Branching

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Pages 1495-1505 | Received 16 Mar 1970, Accepted 09 Mar 1970, Published online: 13 Dec 2006

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Read on this site (10)

Håvard Nordhus, Øsivind Moen & Peter Singstad. (1997) Prediction of Molecular Weight Distribution and Long-Chain Branching Distribution of Low-Density Polyethylene from a Kinetic Model. Journal of Macromolecular Science, Part A 34:6, pages 1017-1043.
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Costas Kiparissides, George Verros & JohnF. Macgregor. (1993) Mathematical Modeling, Optimization, and Quality Control of High-Pressure Ethylene Polymerization Reactors. Journal of Macromolecular Science, Part C 33:4, pages 437-527.
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Hidetaka Tobita. (1993) Kinetics of Long-Chain Branching via Chain Transfer to Polymer: I. Branched Structure. Polymer Reaction Engineering 1:3, pages 357-378.
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LUIGI MARINI & CHRISTOS GEORGAKIS. (1984) THE EFFECT OF IMPERFECT MIXING ON POLYMER QUALITY IN LOW DENSITY POLYETHYLENE VESSEL REACTORS. Chemical Engineering Communications 30:6, pages 361-375.
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Kohji Yamamoto. (1982) An Analytical Method for Long-Chain Branching in Free-Radical Polymerization of Ethylene. Journal of Macromolecular Science: Part A - Chemistry 17:3, pages 415-431.
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Kohji Yamamoto & Matsuo Sugimoto. (1979) Rate Constant for Long-Chain Branch Formation in Free-Radical Polymerization of Ethylene. Journal of Macromolecular Science: Part A - Chemistry 13:8, pages 1067-1080.
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FrancisM. Mirabella$suffix/text()$suffix/text() & JulianF. Johnson. (1975) Polymer Configurational and Compositional Variables as a Function of Molecular Weight. Journal of Macromolecular Science, Part C 12:1, pages 81-108.
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R.V. Mullikin & GeorgeA. Mortimer. (1972) Long-Chain Branching under Conditions of Nonuniform Branching Probability. Journal of Macromolecular Science: Part A - Chemistry 6:7, pages 1301-1310.
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W. Harmon Ray. (1972) On the Mathematical Modeling of Polymerization Reactors. Journal of Macromolecular Science, Part C 8:1, pages 1-56.
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Articles from other publishers (16)

Nazila Yaghini & Piet D. Iedema. (2014) Molecular Weight and Branching Distribution Modeling in Radical Polymerization with Transfer to Polymer and Scission Under Gel Conditions and Allowing for Multiradicals. Macromolecules 47:15, pages 4851-4863.
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Manish K. Saraf, Sylvain Gerard, Louis M. Wojcinski, Paul A. Charpentier, Joseph M. DeSimone & George W. Roberts. (2002) Continuous Precipitation Polymerization of Vinylidene Fluoride in Supercritical Carbon Dioxide:  Formation of Polymers with Bimodal Molecular Weight Distributions. Macromolecules 35:21, pages 7976-7985.
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Hidetaka Tobita. (1997) Copolymerization with Chain Transfer Monomer. 2. Molecular Weight Distribution. Macromolecules 30:6, pages 1693-1700.
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Hidetaka Tobita. (2003) Molecular weight distribution in random branching of polymer chains. Macromolecular Theory and Simulations 5:1, pages 129-144.
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Wai‐Man Chan & Cláudio A. O. Nascimento. (2003) Use of neural networks for modeling of olefin polymerization in high pressure tubular reactors. Journal of Applied Polymer Science 53:10, pages 1277-1289.
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S. Zhu & A. E. Hamielec. (2003) Gel formation in free radical polymerization via chain transfer and terminal branching. Journal of Polymer Science Part B: Polymer Physics 32:5, pages 929-943.
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Hidetaka Tobita. (2003) Molecular weight distribution in free radical polymerization with long‐chain branching. Journal of Polymer Science Part B: Polymer Physics 31:10, pages 1363-1371.
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Pascal Lorenzini, Michel Pons & Jacques Villermaux. (1992) Free-radical polymerization engineering—III. Modelling homogeneous polymerization of ethylene: mathematical model and new method for obtaining molecular-weight distribution. Chemical Engineering Science 47:15-16, pages 3969-3980.
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R.C.M. Zabisky, W.-M. Chan, P.E. Gloor & A.E. Hamielec. (1992) A kinetic model for olefin polymerization in high-pressure tubular reactors: a review and update. Polymer 33:11, pages 2243-2262.
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John K. Beasley. 1989. Comprehensive Polymer Science and Supplements. Comprehensive Polymer Science and Supplements 273 282 .
N.M. Domareva, S.I. Kogan & N.Ya. Tumarkin. (1988) The structure of long-chain branching in polyethylene. Polymer Science U.S.S.R. 30:2, pages 358-363.
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C. H. Chen, J. G. Vermeychuk, J. A. Howell & Paul Ehrlich. (2004) Computer model for tubular high‐pressure polyethylene reactors. AIChE Journal 22:3, pages 463-471.
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Percy A. Small. 1975. Macroconformation of Polymers. Macroconformation of Polymers 1 64 .
P.A. Small. (1973) Effects of long branching on distribution of degree of polymerization: 2. Polymer 14:10, pages 524-525.
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R. A. Jackson, P. A. Small & K. S. Whiteley. (2003) Prediction of molecular weight distributions in branched polymers. Journal of Polymer Science: Polymer Chemistry Edition 11:8, pages 1781-1809.
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P.A. Small. (1972) Effects of long-chain branching on distribution of degree of polymerization. Polymer 13:11, pages 536-540.
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