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Journal of Macromolecular Science: Part A - Chemistry Volume 28, 1991 - Issue 11-12
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Original Articles

Synthesis and Characterization of Polysilanes

Krzysztof Matyjaszewski Department of Chemistry, Carnegie Mellon University Pittsburgh, Pennsylvania, 15213
,
Marek Cypryk Department of Chemistry, Carnegie Mellon University Pittsburgh, Pennsylvania, 15213
,
Holger Frey Department of Chemistry, Carnegie Mellon University Pittsburgh, Pennsylvania, 15213; University of Twente, Chemical Technology, NL-7500 AE Enschede, Holland
,
Jeffrey Hrkach Department of Chemistry, Carnegie Mellon University Pittsburgh, Pennsylvania, 15213
,
Hwan Kyu Kim Department of Chemistry, Carnegie Mellon University Pittsburgh, Pennsylvania, 15213
,
Martin Moeller Department of Chemistry, Carnegie Mellon University Pittsburgh, Pennsylvania, 15213; University of Twente, Chemical Technology, NL-7500 AE Enschede, Holland
,
Karen Ruehl Department of Chemistry, Carnegie Mellon University Pittsburgh, Pennsylvania, 15213
&
Michael White Department of Chemistry, Carnegie Mellon University Pittsburgh, Pennsylvania, 15213
 show all
Pages 1151-1176 | Published online: 23 Oct 2006

Citations (37)

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Km. Meenu, Dibyendu S. Bag, Rekha Lagarkha, Radha Tomar & Arvind Kumar Gupta. (2020) Synthesis of multifunctional copolymers of poly(methylphenylsilane) with (R)-N-(1-phenylethyl)methacrylamide, disperse red 1 methacrylate and their optical and photoluminescence properties. Phosphorus, Sulfur, and Silicon and the Related Elements 195:4, pages 348-358.
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Yusuke Kawakami & Ichiro Imae. (2000) Analysis of Terminal Group and Stereochemistry of Silicon-Containing Compounds and Polymers by NMR. International Journal of Polymer Analysis and Characterization 5:4-6, pages 437-455.
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RichardS. Simons, ScottT. Haubrich, BenjaminV. Mork, Mark Niemeyer & PhilipP. Power. (1998) The Syntheses and Characterization of the Bulky Terphenyl Silanes and Chlorosilanes 2,6-Mes2C6H3SiCl3, 2,6-Trip2C6H3SiCl3, 2,6-Mes2C6H3SiHCl2, 2,6-Trip2C6H3SiHCl2, 2,6-Mes2C6H3SiH3, 2,6-Trip2C6H3SiH3 and 2,6-Mes2C6H3SiCl2SiCl3 . Main Group Chemistry 2:4, pages 275-283.
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Gabriela Sãcãrescu, Nicolae Voiculescu, Mihai Marcu, Liviu Sãcãrescu, Rodinel Ardeleanu & Mihaela Simionescu. (1997) Polyhydrosilanes I. Synthesis. Journal of Macromolecular Science, Part A 34:3, pages 509-516.
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Articles from other publishers (33)

Brandon J. Ackley, Kara L. Martin, Thomas S. Key, Caitlyn M. Clarkson, John J. Bowen, Nicholas D. Posey, James F. Ponder Jr., Zlatomir D. Apostolov, Michael K. Cinibulk, Timothy L. Pruyn & Matthew B. Dickerson. (2023) Advances in the Synthesis of Preceramic Polymers for the Formation of Silicon-Based and Ultrahigh-Temperature Non-Oxide Ceramics. Chemical Reviews 123:8, pages 4188-4236.
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Raghvendra Pratap Chaudhary, Chithra Parameswaran, Muhammad Idrees, Abolaji Sefiu Rasaki, Changyong Liu, Zhangwei Chen & Paolo Colombo. (2022) Additive manufacturing of polymer-derived ceramics: Materials, technologies, properties and potential applications. Progress in Materials Science 128, pages 100969.
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Kristel M. Rabanzo-Castillo, Muhammad Hanif, Tilo Söhnel & Erin M. Leitao. (2019) Synthesis, characterisation and electronic properties of naphthalene bridged disilanes. Dalton Transactions 48:37, pages 13971-13980.
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K. Deller & B. Rieger. (2015) Synthesis of hydrocarbon-soluble, methyl-substituted highly branched polysilanes via the Wurtz-type reductive coupling of trifunctional trisilanes and their pyrolysis to silicon carbide. RSC Advances 5:106, pages 87445-87455.
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Jaeyoung Park, Seongsim Kim, Beomgi Lee, Hyeonsook Cheong, Ji Eun Noh & Hee-Gweon Woo. (2012) Redistribution/Dehydrocoupling of Endocrine n-<TEX>$Bu_3SnH$</TEX> to Polystannanes Catalyzed by Group 4 Metallocene Complexes. Journal of the Chosun Natural Science 5:2, pages 79-83.
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Valerie S. Reuss & Holger Frey. (2010) Multihydroxy-Functional Polysilanes via an Acetal Protecting Group Strategy. Macromolecules 43:20, pages 8462-8467.
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Aroop K. Roy. 2001. Kirk-Othmer Encyclopedia of Chemical Technology. Kirk-Othmer Encyclopedia of Chemical Technology 1 22 .
Zhi‐Fang LI, Jia‐Bang HUANG, Guo‐Qiao LAI, Jian‐Xiong JIANG & Yong‐Min ZHANG. (2008) Synthesis of SiH Functional Poly(phenylsilane) and Organosilane Copolymers: Low‐valent Titanium Induced Polymerization of Organodichlorosilanes. Chinese Journal of Chemistry 26:9, pages 1693-1696.
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Liviu Sacarescu, Rodinel Ardeleanu, Gabriela Sacarescu, Mihaela Simionescu & Ionel Mangalagiu. (2008) Polysilane–Metal Complexes for Organic Semiconductors. High Performance Polymers 19:5-6, pages 501-509.
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Guoqiao Lai, Zhifang Li, Jiabang Huang, Jianxiong Jiang, Huayu Qiu & Yongjia Shen. (2007) Direct construction of silicon–silicon bond by using the low-valent titanium reagent. Journal of Organometallic Chemistry 692:16, pages 3559-3562.
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Yusuke Kawakami. (2001) Stereoregular silicon-containing ­polymers. Polymers for Advanced Technologies 12:11-12, pages 658-664.
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Heinrich Lang, Karin Brüning & G Rheinwald. (2001) Synthese des Cyclotetrasiloxans [(Me)(C6H4CH2NMe2-2)-SiO]4 und dessen strukturanalytische Untersuchung. Journal of Organometallic Chemistry 633:1-2, pages 157-161.
Crossref
Aroop K. Roy. 2001. Kirk-Othmer Encyclopedia of Chemical Technology. Kirk-Othmer Encyclopedia of Chemical Technology.
Victor Y. Lu & T. Don Tilley. (2000) Poly(diaryl)stannanes:  Influence of Substituents on the σ − σ * Transition Energy . Macromolecules 33:7, pages 2403-2412.
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L. A. Schwegler, S. S. Sheiko, M. Möller, E. Fossum & K. Matyjaszewski. (1999) Preparation of Telechelic Polysilylenes:  A General Methodology for the Synthesis of Polysilylene-Based Triblock Copolymers. Macromolecules 32:18, pages 5901-5904.
Crossref
Yuning Li & Yusuke Kawakami. (1999) Synthesis and Polymerization of an Optically Active Bifunctional Disiloxane. 2. Preparation of Optically Active ( S )-2-(1-Naphthyl)-2-phenyl-5,5-dimethyl-1-oxa-2,5-disilacyclopentane and Its Ring-Opening Polymerization . Macromolecules 32:3, pages 548-553.
Crossref
François Gauvin, John F. Harrod & Hee Gweon Woo. 1998. 363 405 .
Wolfram Uhlig. (1996) Modifizierungsreaktionen an Polyphenylsilin und vernetzten polysilanen. Journal of Organometallic Chemistry 516:1-2, pages 147-154.
Crossref
Masato Suzuki, Tomomasa Kaneko, Yoshiyuki Morishima, Tatsuhiko Obayashi & Takeo Saegusa. (1996) Anionic Ring-Opening Polymerization of 1,2,2-Trimethyl-1-phenyl-1,2-disilacyclopentane. Polymer Journal 28:1, pages 16-23.
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Victor Lu & T. Don Tilley. (1996) Low-Band-Gap, σ-Conjugated Polymers:  Poly(diarylstannanes). Macromolecules 29:17, pages 5763-5764.
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Gan Ouyang, Richard Simons & Claire Tessier. 1996. Metal-Containing Polymeric Materials. Metal-Containing Polymeric Materials 189 197 .
Krzysztof Matyjaszewski, Jerzy Chrusciel, Jim Maxka & Manabu Sasaki. (1995) Branched polysilanes from tetrafunctional monomers. Journal of Inorganic and Organometallic Polymers 5:3, pages 261-279.
Crossref
Manabu Sasaki & Krzysztof Matyjaszewski. (2003) Synthesis of branched copolysilanes from trichlorosilanes. Journal of Polymer Science Part A: Polymer Chemistry 33:5, pages 771-778.
Crossref
Danièle Reyx, José Manuel Natário Martins, Irène Campistron & Patrick Noireaux. (2003) Polysilanes réactifs, 5. Optimisation de la synthèse des α,ω‐bis(triméthylsilyl)oligo (méthylphénylsilane)s par prise en considération d'un mécanisme anionique. Macromolecular Chemistry and Physics 196:3, pages 915-927.
Crossref
Shuzi Hayase. (1995) Polysilanes with functional groups. Endeavour 19:3, pages 125-131.
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Krzysztof Matyjaszewski & Jeffrey S. Hrkach. (1995) Modification of polysilanes: Preparation of comb-like graft copolymers. Journal of Inorganic and Organometallic Polymers 5:2, pages 183-193.
Crossref
Danièle Reyx, José Manuel Natário Martins, Irène Campistron & Patrick Noireaux. (2003) Polysilanes fonctionnels, 4. Duplication réductrice de chlorosilanes par le lithium pour la synthèse d'α,ω‐bis(triméthylsilyl) oligo(méthylphénylsilane)s. Réactions parasites de silylation des noyaux phényle. Macromolecular Chemistry and Physics 196:1, pages 149-166.
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Toru Imori & T.Don Tilley. (1994) The influence of catalyst structure on the dehydropolymerization of phenylsilane. Polyhedron 13:15-16, pages 2231-2243.
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Jim Maxka, Jerzy Chrusciel, Manabu Sasaki & Krzysztof Matyjaszewski. (2011) Polysilanes with various architectures. Macromolecular Symposia 77:1, pages 79-92.
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R D Miller, E J Ginsburg & D Thompson. (1993) Low Temperature Wurtz-Type Polymerization of Substituted Dichlorosilanes. Polymer Journal 25:8, pages 807-823.
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M. Cypryk, J. Chrusciel, E. Fossum & K. Matyjaszewski. (2011) Ring‐opening polymerization of strained cyclotetrasilanes as a new route towards well defined polysilylenes. Makromolekulare Chemie. Macromolecular Symposia 73:1, pages 167-176.
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Joseph Kulig, Virginia Jefferis, David Schwamm & Morton Litt. 1990. Inorganic and Metal-Containing Polymeric Materials. Inorganic and Metal-Containing Polymeric Materials 225 232 .
Alain Fradet. 1989. Comprehensive Polymer Science and Supplements. Comprehensive Polymer Science and Supplements 133 162 .

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