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Original Articles

Physical properties of syndiotactic polypropylene

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Pages 319-334 | Accepted 25 Feb 1991, Published online: 19 Aug 2006

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (2)

Jonahira Rodrlguez-Arnold, Zhengzheng Bu & StephenZ. D. Cheng. (1995) Crystal Structure, Morphology, and Phase Transitions in Syndiotactic Polypropylene. Journal of Macromolecular Science, Part C 35:1, pages 117-154.
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Virendra Kumar Gupta, Sheo Satish & Ishwar Singh Bhardwaj. (1994) Metallocene Complexes of Group 4 Elements in the Polymerization of Monoolefins. Journal of Macromolecular Science, Part C 34:3, pages 439-514.
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Articles from other publishers (52)

Simon Cholewa, Lucas Stieglitz, Andreas Jaksch, Bernhard Rieger & Dietmar Drummer. (2023) Tailored Syndiotactic Polypropylene Feedstock Material for Laser-Based Powder Bed Fusion of Polymers: Material Development and Processability. ACS Applied Polymer Materials 5:4, pages 2430-2439.
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Franz J. Lanyi, Nicolai Wenzke, Joachim Kaschta & Dirk W. Schubert. (2019) On the Determination of the Enthalpy of Fusion of α‐Crystalline Isotactic Polypropylene Using Differential Scanning Calorimetry, X‐Ray Diffraction, and Fourier‐Transform Infrared Spectroscopy: An Old Story Revisited. Advanced Engineering Materials 22:9, pages 1900796.
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Ali Abbasi, Mohamed Mahmoud Nasef, Reza Faridi-Majidi, Mohammad Etesami, Matsuura Takeshi & Ebrahim Abouzari-Lotf. (2018) Highly flexible method for fabrication of poly (Glycidyl Methacrylate) grafted polyolefin nanofiber. Radiation Physics and Chemistry 151, pages 283-291.
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Ryo Tanaka, Yuushou Nakayama & Takeshi Shiono. (2016) Theoretical investigation of the mechanism of syndiospecific propylene polymerization using ansa-dimethylsilylene(fluorenyl)(amido)titanium complexes. Journal of Organometallic Chemistry 823, pages 112-115.
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Ying Lu, Yaotao Wang, Lianlian Fu, Zhiyong Jiang & Yongfeng Men. (2014) Crystallization, Recrystallization, and Melting Lines in Syndiotactic Polypropylene Crystallized from Quiescent Melt and Semicrystalline State Due to Stress-Induced Localized Melting and Recrystallization. The Journal of Physical Chemistry B 118:45, pages 13019-13023.
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Bernard Lotz. (2014) Analysis of the structure and morphology of crystalline polymers by electron microscopy imaging and diffraction: a personal journey. Microscopy 63:2, pages 95-109.
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Julian Bejarano, Rosario Benavente, Ernesto Pérez, Manfred Wilhelm, Raúl Quijada & Humberto Palza. (2013) Effect of Polymer Structure and Incorporation of Nanoparticles on the Behavior of Syndiotactic Polypropylenes. Macromolecular Chemistry and Physics 214:22, pages 2567-2578.
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J.M. Gómez-Elvira, R. Benavente & M.C. Martínez. (2013) Unravelling the contribution of chain microstructure in the mechanism of the syndiotactic polypropylene pyrolysis. Polymer Degradation and Stability 98:6, pages 1150-1163.
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Amelia M. Anderson-Wile, Geoffrey W. Coates, Finizia Auriemma, Claudio De Rosa & Amelia Silvestre. (2012) Synthesis and Ring-Opening Metathesis Polymerization of Norbornene-Terminated Syndiotactic Polypropylene. Macromolecules 45:19, pages 7863-7877.
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Ma. Eulalia Vanegas, Raúl Quijada & Griselda B. Galland. (2010) Syndiotactic poly(propene-co-norbornene): Synthesis and properties at low norbornene incorporation. Polymer 51:20, pages 4627-4631.
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Zhigang Wang, Yanhua Niu, Glenn H. Fredrickson, Edward J. Kramer, Yong-Woo Shin, Fumihiko Shimizu, Feng Zuo, Lixia Rong, Benjamin S. Hsiao & Geoffrey W. Coates. (2010) Step-Cycle Mechanical Processing of Gels of sPP- b -EPR- b -sPP Triblock Copolymer in Mineral Oil . Macromolecules 43:16, pages 6782-6788.
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Ma. Eulalia Vanegas, Raúl Quijada, Suzana P. Nunes & Wilfredo Yave. (2010) Syndiotactic polypropylene copolymer membranes and their performance for oxygen separation. Journal of Membrane Science 348:1-2, pages 34-40.
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Ma. Eulalia Vanegas, Raúl Quijada & Daniel Serafini. (2009) Microporous membranes prepared via thermally induced phase separation from metallocenic syndiotactic polypropylenes. Polymer 50:9, pages 2081-2086.
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Ma. Eulalia Vanegas, Raúl Quijada, Daniel Serafini, Griselda B. Galland & Humberto Palza. (2008) Nonisothermal crystallization and melting behavior of syndiotactic polypropylenes of different microstructure. Journal of Polymer Science Part B: Polymer Physics 46:8, pages 798-806.
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Liberata Guadagno, Carlo Naddeo, Marialuigia Raimondo & Vittoria Vittoria. (2008) Structural and morphological changes during UV irradiation of the trans-planar form of syndiotactic polypropylene. Polymer Degradation and Stability 93:1, pages 176-187.
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M. L. Cerrada, V. Rodríguez-Amor & E. Pérez. (2007) Effects of clay nanoparticles and electron irradiation in the crystallization rate of syndiotactic polypropylene. Journal of Polymer Science Part B: Polymer Physics 45:9, pages 1068-1076.
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Javier Arranz-Andrés, Rosario Benavente, M. Rosário Ribeiro, Ernesto Pérez & Maria L. Cerrada. (2006) Evolution of a Metallocenic sPP with Time: Changes in Crystalline Content and Enthalpic Relaxation. Macromolecular Chemistry and Physics 207:17, pages 1564-1574.
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Javier Arranz-Andrés, Juan L. Guevara, Teresa Velilla, Raúl Quijada, Rosario Benavente, Ernesto Pérez & María L. Cerrada. (2005) Syndiotactic polypropylene and its copolymers with alpha-olefins. Effect of composition and length of comonomer. Polymer 46:26, pages 12287-12297.
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Ching-I Huang, Chun-Pin Chang, Katsumi Shimizu & Charles C. Han. (2004) Phase behavior and crystallization analysis in binary crystalline blends of syndiotactic polypropylene and ethylene?Propylene random copolymer. Journal of Polymer Science Part B: Polymer Physics 42:16, pages 2995-3005.
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Konstantinos G Gatos, Georgia Kandilioti, Costas Galiotis & Vasilis G Gregoriou. (2004) Mechanically and thermally induced chain conformational transformations between helical form I and trans-planar form III in syndiotactic polypropylene using FT-IR and Raman spectroscopic techniques. Polymer 45:13, pages 4453-4464.
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Michael S. Sevegney, Gautam Parthasarthy, Rangaramanujam M. Kannan, Derek W. Thurman & Lucia Fernandez-Ballester. (2003) Deformation-Induced Morphology Changes and Orientation Behavior in Syndiotactic Polypropylene. Macromolecules 36:17, pages 6472-6483.
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H. Çatalgil-Giz, A. Giz, A. M. Alb, A. Öncül Koç & W. F. Reed. (2002) Online Monitoring of Composition, Sequence Length, and Molecular Weight Distributions during Free Radical Copolymerization, and Subsequent Determination of Reactivity Ratios. Macromolecules 35:17, pages 6557-6571.
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Zhi-Gang Wang, Xue-Hui Wang, Benjamin S. Hsiao, Roger A. Phillips, Francisco J. Medellin-Rodriguez, Srivatsan Srinivas, Howard Wang & Charles C. Han. (2001) Structure and morphology development in syndiotactic polypropylene during isothermal crystallization and subsequent melting. Journal of Polymer Science Part B: Polymer Physics 39:23, pages 2982-2995.
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Yukio Imanishi & Naofumi Naga. (2001) Recent developments in olefin polymerizations with transition metal catalysts. Progress in Polymer Science 26:8, pages 1147-1198.
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Ravi K. Sura, Prashant Desai & A. S. Abhiraman. (2001) Oriented crystallization in fiber formation: Inferences from the structure and properties of melt spun syndiotactic polypropylene filaments. Journal of Applied Polymer Science 81:10, pages 2305-2317.
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Zhi-Gang Wang, Roger A. Phillips & Benjamin S. Hsiao. (2001) Morphology development during isothermal crystallization. II. Isotactic and syndiotactic polypropylene blends. Journal of Polymer Science Part B: Polymer Physics 39:16, pages 1876-1888.
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Pitt Supaphol. (2001) Unbiased evaluation of literature data on equilibrium melting temperature and enthalpy of fusion of perfectly syndiotactic polypropylene. Journal of Applied Polymer Science 79:9, pages 1603-1609.
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Joachim Loos & Tilo Schimanski. (2004) Morphology–mechanical property relations in syndiotactic polypropylene (sPP) fibers. Polymer Engineering & Science 40:3, pages 567-572.
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Pitt Supaphol & Joseph E. Spruiell. (2000) Thermal properties and isothermal crystallization of syndiotactic polypropylenes: Differential scanning calorimetry and overall crystallization kinetics. Journal of Applied Polymer Science 75:1, pages 44-59.
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Junting Xu, Linxian Feng, Zhengxi Liu, Yi Deng, Chunming Cui & Wei Chen. (1999) Influence of syndiotacticity and annealing temperature on the double melting peak behaviour of syndiotactic polypropylene. Polymer International 48:1, pages 53-56.
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Yirong Hu, Mark T. Krejchi, Chirag D. Shah, Charles L. Myers & Robert M. Waymouth. (1998) Elastomeric Polypropylenes from Unbridged (2-Phenylindene)zirconocene Catalysts:  Thermal Characterization and Mechanical Properties. Macromolecules 31:20, pages 6908-6916.
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Claudio De Rosa, Finizia Auriemma, Valeria Vinti & Maurizio Galimberti. (1998) Equilibrium Melting Temperature of Syndiotactic Polypropylene. Macromolecules 31:18, pages 6206-6210.
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Naofumi Naga, Kooji Mizunuma, Hajime Sadatoshi & Masahiro Kakugo. (1997) Properties and Crystalline Structures of Syndiotactic Poly(propylene- co -1-butene) . Macromolecules 30:7, pages 2197-2200.
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