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Molecular Crystals and Liquid Crystals Volume 52, 1979 - Issue 1
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Original Articles

A Spectroscopic Study of the Second Order Phase Transition in Bis (p-toluene sulfonate) Diacetylene Polymer Crystals

D. Bloor Department of Physics, Queen Mary College, Mile End Road, London E. 1., England
,
D. A. Fisher Department of Physics, Queen Mary College, Mile End Road, London E. 1., England
,
D. N. Batchelder Department of Physics, Queen Mary College, Mile End Road, London E. 1., England
,
R. Kennedy Department of Physics, Queen Mary College, Mile End Road, London E. 1., England
,
A. C. Cottle Department of Physics, Queen Mary College, Mile End Road, London E. 1., England
,
W. F. Lewis Department of Physics, Queen Mary College, Mile End Road, London E. 1., England
&
M. B. Hursthouse Department of Chemistry, Queen Mary College, Mile End Road, London E. 1., England; Department of Physics, Queen Mary College, Mile End Road, London E. 1., England
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Pages 83-92 | Received 16 Jun 1978, Published online: 12 Oct 2011

Citations (34)

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Juliusz Sworakowski & MaciejE. Orczyk. (1993) Electrical and Dielectric Properties of Polymerizing Mixed Single Crystals of Diacetylenes: pTS-pFBS System. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 230:1, pages 71-76.
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J. Even, M. Bertault, B. Toudic, H. Cailleau, J.L. Fave, M. Schott, F. Moussa & R. Currat. (1992) Dynamical study of the antiferroelectric transition in a polymer crystal : pTS-D. Ferroelectrics 125:1, pages 51-56.
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Xiao Ding Quan, David John Ando & David Bloor. (1983) Pyroelectric and Dielectric Behaviour of the Crystals of The Bis-Toluene Sulphonate Diacetylene Monomer and Polymer. Molecular Crystals and Liquid Crystals 93:1, pages 201-214.
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J.N. Patillon, P. Robin, P.A. Albouy, J.P. Pouget & R. Comes. (1981) X-ray Study of the Incommensurate Phase of Bis-(p-toluene Sulfonate) of 2, 4-Hexadiyne-1, 6 Diol as a Function of Polymer Conversion. Molecular Crystals and Liquid Crystals 76:3-4, pages 297-308.
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Articles from other publishers (30)

J. Even, M. Bertault, A. Girard & Y. Délugeard. (1996) Influence of pressure on the ferroelectric phase transition in a symmetrical polymerizable diacetylene crystal DNP. Chemical Physics 213:1-3, pages 357-363.
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J. Even, M. Bertault, A. Girard, Y. Delugeard & J.-L. Fave. (1994) Dynamical study by Raman scattering of the ferroelectric phase transition of the disubstituted diacetylene 1,6-bis(2,4-dinitrophenoxy)-2,4-hexadiyne (DNP). Chemical Physics 188:2-3, pages 235-246.
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J. Even, M. Bertault, B. Toudic, H. Cailleau, J. L. Fave, R. Currat & F. Moussa. (1994) Dynamics of the phase transition of the fully polymerized and deuterated diacetylene 2,4-hexadiynylene bis( p -toluenesulfonate) . Physical Review B 49:17, pages 11602-11612.
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J. Even, H. Cailleau, B. Toudic, M. Bertault, F. Moussa & R. Currat. (1992) Neutron study of the structural transition in a polymerizable crystal, pTS-D. Physica B: Condensed Matter 180-181, pages 339-341.
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J. Berréhar, P. Hassenforder, C. Lapersonne-Meyer & M. Schott. (1990) Polydiacetylene single-crystal thin films. Thin Solid Films 190:1, pages 181-197.
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J. P Pouget. (1990) Effect of Nonsymmetry-Breaking Extended Defects on the Incommensurate-Commensurate Transition. Europhysics Letters (EPL) 11:7, pages 645-650.
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Maciej E. Orczyk. (1990) Determination of a complete dielectric tensor of polymerizable pTS diacetylene. Chemical Physics 142:3, pages 485-493.
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Du Yinglei, Wu Baimei & He Pingsheng. (1988) Photoacoustic study of PTS (BIS-p-toluene sulfonate of 2,4-hexadiyne-1,6-diol) single crystal and its thermal properties. Journal of Physics and Chemistry of Solids 49:5, pages 499-503.
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D. J. Ando, D. Bloor, S. N. Bedford, J. S. Obhi & S. Mann. 1988. Integration of Fundamental Polymer Science and Technology—2. Integration of Fundamental Polymer Science and Technology—2 173 178 .
Naveenchandra & H. N. Shrivastava. (1987) Crystal and molecular structure of the unreactive form of 1,8-bis (p-chlorophenyl)-octa-1,7-diene-3,5-diyne. Journal of Crystallographic and Spectroscopic Research 17:6, pages 701-711.
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R Zielinski & J Kalinowski. (1987) The dielectric permittivity and phase transition in the bis-(p-toluene sulphonate) of 2,4-hexadiyne-1,6-diol polymer single crystal. Journal of Physics C: Solid State Physics 20:2, pages 177-190.
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M. SCHOTT & G. WEGNER. 1987. Nonlinear Optical Properties of Organic Molecules and Crystals. Nonlinear Optical Properties of Organic Molecules and Crystals 3 49 .
M. Morrow & C.J. Eckhardt. (1986) Investigation of the phase transition in PTS polydiacetylene using piezomodulated reflection spectroscopy. Chemical Physics Letters 131:1-2, pages 118-123.
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R. Nowak, J. Sworakowski, B. Kuchta, M. Bertault, M. Schott, R. Jakubas & H.A. Kołodziej. (1986) Dielectric properties of single crystals of the substituted diacetylene pTS: effect of the solid-state polymerization and phase transitions. Chemical Physics 104:3, pages 467-476.
Crossref
David N. Batchelder. 1985. Polydiacetylenes. Polydiacetylenes 187 212 .
R J Lacey, D N Batchelder & G D Pitt. (1984) Pressure dependence of the 2 eV electronic transition of a polydiacetylene. Journal of Physics C: Solid State Physics 17:25, pages 4529-4537.
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M. Bertault, M. Schott & J. Sworakowski. (1984) Electric polarization generated by the solid-state polymerization of pTS. Chemical Physics Letters 104:6, pages 605-608.
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Costas Galiotis, Robert J. Young, David J. Ando & David Bloor. (2003) The solid‐state polymerization and physical properties of 2,4‐hexadiynylene bis( N ‐ethylcarbamate), 1 crystal modifications and polymerization kinetics . Die Makromolekulare Chemie 184:5, pages 1083-1101.
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Pierre Tolédano & Jean-Claude Tolédano. (1982) Nonferroic phase transitions. Physical Review B 25:3, pages 1946-1964.
Crossref
J.P. Aimé, J. Lefebvre, M. Bertault, M. Schott & J.O. Williams. (1982) Studies of a polymerizable crystal : I. - structure of monomer pts (bis-p-toluenesulphonate of 2,4-hexadiyne 1,6-diol) by neutron diffraction at 120 and 221 k. Journal de Physique 43:2, pages 307-322.
Crossref
R.J. Lacey, R.L. Williams, R.J. Kennedy, D. Bloor & D.N. Batchelder. (1981) Pressure dependence of phase transitions in two diacetylene crystals. Chemical Physics Letters 83:1, pages 65-68.
Crossref
D.N Batchelder, N.J Poole & D Bloor. (1981) Surface enhanced Raman spectroscopy of molecular oxygen adsorbed on polydiacetylene single crystals. Chemical Physics Letters 81:3, pages 560-564.
Crossref
D. N. Batchelder, R. J. Kennedy, D. Bloor & R. J. Young. (2003) Morphology and structure of heavily deformed single crystals of a polydiacetylene. II. Resonance raman and optical spectroscopy. Journal of Polymer Science: Polymer Physics Edition 19:4, pages 677-688.
Crossref
M. Bertault, A. Collet & M. Schott. (1981) A calorimetric study of pTS (bis-p-toluenesulphonate of 2,4-hexadiyne 1,6-diol) and its phase transitions as a function of polymerization. Journal de Physique Lettres 42:6, pages 131-133.
Crossref
I. Hatta, T. Nakayama & T. Matsuda. (1980) Successive phase transitions of partially and fully polymerized crystals of 2,4-Hexadiyne-1,6-Diol bis (p-toluene sulfonate). Physica Status Solidi (a) 62:1, pages 243-248.
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R. R. Chance, M. L. Shand, C. Hogg & R. Silbey. (1980) Three-wave mixing in conjugated polymer solutions: Two-photon absorption in polydiacetylenes. Physical Review B 22:8, pages 3540-3550.
Crossref
R. R. Chance, K. C. Yee, R. H. Baughman, H. Eckhardt & C. J. Eckhardt. (2003) Electronic spectra of two polydiacetylene isomorphs. Journal of Polymer Science: Polymer Physics Edition 18:7, pages 1651-1653.
Crossref
D. Bloor & R.J. Kennedy. (1980) Far infrared studies of the solid-state phase transition in bis(p-toluene sulphonate)diacetylene monomer and polymer. Chemical Physics 47:1, pages 1-7.
Crossref
A.R. Bishop. (1980) Defect states in polyacetylene and polydiacetylene. Solid State Communications 33:9, pages 955-960.
Crossref
P. Robin, J.P. Pouget, R. Comes & A. Moradpour. (1980) Etude par diffusion des rayons X du mécanisme de polymérisation et des transitions de phase du diacétylène : bis-(p-toluène sulfonate) de 2,4 hexadiyne 1,6 diol. Journal de Physique 41:5, pages 415-421.
Crossref

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