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Liquid Crystals

X-Ray Studies on the Mesogen 4′-n-Pentyloxy-4-Biphenylcarbonitrile(5OCB) in the Solid Crystalline State

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Pages 223-235 | Received 21 Jan 1985, Accepted 07 Jun 1985, Published online: 19 Oct 2010

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Read on this site (26)

R. Aneela & DurgaP. Ojha. (2012) Solvent Effects on Phase Stability of a Nematogen—A Molecular Level Approach. Molecular Crystals and Liquid Crystals 562:1, pages 114-122.
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S. Haldar, P. K. Mandal, S. J. Prathap, T. N. Guru Row & R. Dabrowski. (2009) Structural Analysis by X-Ray Diffraction of a Polar Mesogen 4-Cyanobiphenyl-4′-heptylbiphenyl Carboxylate. Molecular Crystals and Liquid Crystals 503:1, pages 99-111.
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S. Haldar, P. K. Mandal, S. J. Prathap, T. N. Guru Row & W. Haase. (2008) X‐ray studies of the crystalline and nematic phases of 4′‐(3,4,5‐trifluorophenyl)‐4‐propylbicyclohexyl. Liquid Crystals 35:11, pages 1307-1312.
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S. Haldar, S. Biswas, P. K. Mandal, K. Goubitz, H. Schenk & W. Haase. (2008) X-Ray Structural Analysis in the Crystalline Phase of a Nematogenic Fluoro-Phenyl Compound. Molecular Crystals and Liquid Crystals 490:1, pages 80-87.
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B. R. Jaishi, P. K. Mandal$suffix/text()$suffix/text(), K. Goubitz, H. Schenk, R. Dabrowski & K. Czuprynski. (2003) The molecular and crystal structure of a polar mesogen 4-cyanobiphenyl-4′-hexylbiphenyl carboxylate . Liquid Crystals 30:11, pages 1327-1333.
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Sajal Giri, Pradip Mandal & Sukla Paul. (2001) Study of Physical Properties of Binary Mixtures of Two Nematogens. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 365:1, pages 711-719.
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V. Krasnoholovets, I. Khakimov, G. Puchkovskaya & E. Gabrusenoks. (2000) Mechanism of Q(C≡N) Band Broadening in Condensed State of Alkoxycyanobiphenyles. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 348:1, pages 101-109.
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Hassan Allouchi, Abdeslam Belaaraj, HenryN. C. Wong, Huu Tinh Nguyen & Michel Cotrait. (1999) Molecular Arrangement in Mesogenic Compounds with a Terminal Cyano Group. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 326:1, pages 279-290.
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Pranab Sarkar, Parimal Sarkar, Pradip Mandal & T. Manisekaran. (1998) Molecular Structure and Packing in the Crystalline State of 4-n-Ethyl-4′-Cyanobiphenyl (2CB) by Single Crystal X-ray Diffractometry. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 325:1, pages 91-97.
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A. Nath, S. Gupta, P. Mandal, S. Paul & H. Schenk. (1996) Structural analysis by X-ray diffraction of a non-polar alkenyl liquid crystalline compound. Liquid Crystals 20:6, pages 765-770.
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M.K. Das, S. Paul & R. Paul. (1995) X-ray Diffraction Studies on Solid and Mesomorphic Phases of Four Members of Alkoxy-Cyanobiphenyls. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 264:1, pages 89-98.
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Sakuntala Gupta & Sukla Paul. (1995) The Structure Property Relationship of a Homologous Series of Mesogenic Compounds. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 260:1, pages 483-489.
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T.I. Shabatina, Yu.N. Morosov, A.I. Konstantinov, V.A. Batyuk & G.B. Sergeev. (1994) Low Temperature Solid States of Mesogenic Alkyl- and Alkoxy-Cyanobiphenyls and Nitroxide Formation Kinetics. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 248:1, pages 103-109.
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Kayako Hori, Yoshiko Koma, Akira Uchida & Yuji Ohashi. (1993) Crystal Structures of 6OCB and 7OCB. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 225:1, pages 15-22.
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P. Mandal, S. Paul, H. Schenk & K. Goubitz. (1992) Crystal and Molecular Structure of a Cybotactic Nematic Compound bis(4′-n-Butoxybenzal—Chloro-1,4-Phenylinediamine. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 210:1, pages 21-30.
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I. Ono & S. Kondo. (1991) Orientational Ordering and Molecular Motion of 4′-Pentyloxy-4-Cyanobiphenyl (50CB) by Molecular Dynamics Simulation. Molecular Crystals and Liquid Crystals Letters 8:4, pages 69-74.
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S. Gupta, P. Mandal, S. Paul, M. de Wit, K. Goubitz & H. Schenk. (1991) An X-Ray Study of Cyanophenylpyrimidines Part III. Crystal Structure of 5-(trans-4- Heptylcyclohexyl)-2-(4-Cyanophenyl) Pyrimidine. Molecular Crystals and Liquid Crystals 195:1, pages 149-159.
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P. Mandal, S. Paul, C.H. Stam & H. Schenk. (1990) X-Ray Studies of Cyanophenyl Pyrimidines Part II The Crystal and Molecular Structure of 5-(4-Ethylcyclohexyl)-2-(4-Cyanophenyl)Pyrimidine. Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics 180:2, pages 369-378.
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P. Mandal, B. Majumdar, S. Paul, H. Schenk & K. Goubitz. (1989) An X-ray Study of Cyanophenyl Pyrimidines. Part I-Crystal Structure of PCCPP. Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics 168:1, pages 135-146.
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G. Winter, H. Hartung, W. Brandt & M. Jaskólski. (1987) Crystal Structure and Conformational Behavior of Smectogenic 2-Phenyl-5-(4-n-pentoxyphenyl) Pyrimidine. Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics 150:1, pages 289-300.
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V. F. Chuvaev, M. N. Rodnikova & N. S. Kucherepa. (2008) Wide-line 1H NMR study of 4′-(pentyloxy)-4-biphenylcarbonitrile in different phase states. Russian Journal of Inorganic Chemistry 53:12, pages 1925-1928.
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S. Biswas, S. Haldar, P. K. Mandal, K. Goubitz, H. Schenk & R. Dabrowski. (2007) Crystal structure of a polar nematogen 4‐( trans‐ 4‐undecylcyclohexyl) isothiocyanatobenzene . Crystal Research and Technology 42:10, pages 1029-1035.
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L. M. Babkov, O. V. Gorshkova, G. A. Puchkovskaya & I. N. Khakimov. (1998) Vibrational spectra and structure of 4-cyano-4′-pentalkoxybiphenyl in different physical states. Journal of Structural Chemistry 39:1, pages 44-48.
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D. Demus, J. Goodby, G. W. Gray, H.‐W. Spiess & V. VillJohn M. Seddon. 1998. Handbook of Liquid Crystals. Handbook of Liquid Crystals 635 679 .
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Natalia V. Ozhegova, Aleksandr V. Nemukhin, Tatiana I. Shabatina & Gleb B. Sergeev. (1998) Modeling structure and spectra of silver complexes in condensate films of polar liquid crystals. Mendeleev Communications 8:6, pages 218-220.
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Sven Hauptmann, Thomas Mosell, Stephan Reiling & Jürgen Brickmann. (1996) Molecular dynamics simulations of the bulk phases of 4-cyano-4′-n-pentyloxybiphenyl. Chemical Physics 208:1, pages 57-71.
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K. Chandramani Singh & Prakash C. Jain. (1996) Study of molecular motions in alkyl cyanobiphenyls using positron lifetime spectroscopy. Structural Chemistry 7:3, pages 215-223.
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Kayako Hori, Yoshiko Koma, Minako Kurosaki, Koichi Itoh, Hidehiro Uekusa, Yasuyuki Takenaka & Yuji Ohashi. (1996) Crystalline Polymorphism and Phase Transition Behavior of Mesogenic 4-Heptyloxy-4′-cyanobiphenyl (7OCB). Bulletin of the Chemical Society of Japan 69:4, pages 891-897.
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A. Pfeil & P. Zugenmaier. (2006) The Crystal and Molecular Structure of 4‐Hydroxy‐4′‐nitro‐ biphenyl and its Potassium Salt. Crystal Research and Technology 31:7, pages 863-873.
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L. M. Babkov, O. V. Gorshkova, E. V. Gabrusyonok, G. A. Puchkovskaya & I. N. Khakimov. (1995) Phase transitions, conformational lability, and intermolecular interactions in alkoxycyanobiphenyls. Journal of Structural Chemistry 36:5, pages 739-746.
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L. M. Babkov, O. V. Gorshkova, N. A. Golovina, G. A. Puchkovskaya & I. N. Khakimov. (1995) Vibrational spectra and the structure of long-chain aliphatic compounds. Journal of Structural Chemistry 36:2, pages 302-308.
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L.M. Babkov, G.A. Puchkovskaya & I.N. Khakimov. (1994) Polymorphism and conformational mobility of mesogens. Journal of Molecular Structure 325, pages 177-188.
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L.M. Babkov, I.N. Khakimov, A.P. Polishchuk, G.A. Puchkovskaya, V.P. Privalko & L.N. Lisetski. (1993) IR study of the conformational mobility of 4-cyano-4-n-alkoxybiphenyl. Journal of Molecular Structure 296:1-2, pages 29-33.
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Isamu Ono & Shoichi Kondo. (1993) A Computational Approach to the Structure of 4-Alkoxy-4′-cyanobiphenyl in Nematic Mesophase. Bulletin of the Chemical Society of Japan 66:2, pages 633-638.
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S. Karl Heeks & Geoffrey R. Luckhurst. (1993) Deuterium nuclear magnetic resonance study of the orientational order in the nematic phase of 4-n-pentyloxy-4′-cyanobiphenyl. Tests of the Emsley–Luckhurst–Stockley theory and of the Haller extrapolation. J. Chem. Soc., Faraday Trans. 89:20, pages 3783-3790.
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L. M. Babkov, N. I. Davydova, G. A. Puchkovskaya & I. N. Khakimov. (1993) IR absorption spectra and structure of 4-cyano-4?,-p-alkoxybiphenyls. Journal of Structural Chemistry 34:1, pages 92-97.
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Akihiro Abe, Noritaka Kimura & Mamoru Nakamura. (2003) Conformation of 4‐ethoxy‐4′‐biphenylyl cyanide in the isotropic and anisotropic liquid‐crystalline state — a rotational isomeric state simulation of 2 H NMR spectra . Macromolecular Theory and Simulations 1:6, pages 401-413.
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Hiroshi Matsubara, Takanori Tanaka, Yoshio Takai, Masami Sawada, Koji Seto, Hideyuki Imazaki & Shigetoshi Takahashi. (1991) Structural Studies of a Liquid Crystalline Compound, 2-(4-Cyanophenyl)-5-(4-butylphenyl)-1,3,2-dioxaborinane, by Means of Nuclear Magnetic Resonance and X-Ray Analyses. Bulletin of the Chemical Society of Japan 64:7, pages 2103-2108.
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Demetri J. Photinos, Edward T. Samulski & Hirokazu Toriumi. (1991) Molecular flexibility and orientational ordering of nematic liquid crystals. The Journal of Chemical Physics 94:4, pages 2758-2772.
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