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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 101, 2003 - Issue 16
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Original Articles

Understanding liquid-liquid immiscibility and LCST behaviour in polymer solutions with a Wertheim TPT1 description

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Pages 2575-2600 | Received 05 Feb 2003, Accepted 11 Apr 2003, Published online: 18 Nov 2009

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Shiqi Zhou & J. R. Solana. (2009) Progress in the Perturbation Approach in Fluid and Fluid-Related Theories. Chemical Reviews 109:6, pages 2829-2858.
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Crossref
Andrew J. Haslam, Øivind Moen, Claire S. Adjiman, Amparo Galindo & George Jacksona. 2006. Multiscale Modelling of Polymer Properties. Multiscale Modelling of Polymer Properties 301 332 .
Patrice Paricaud, Amparo Galindo & George Jackson. (2004) Modeling the Cloud Curves and the Solubility of Gases in Amorphous and Semicrystalline Polyethylene with the SAFT-VR Approach and Flory Theory of Crystallization. Industrial & Engineering Chemistry Research 43:21, pages 6871-6889.
Crossref
A. Galindo, C. Vega, E. Sanz, L. G. MacDowell, E. de Miguel & F. J. Blas. (2004) Computer simulation study of the global phase behavior of linear rigid Lennard-Jones chain molecules: Comparison with flexible models. The Journal of Chemical Physics 120:8, pages 3957-3968.
Crossref
A. Vrij. (1976) Polymers at Interfaces and the Interactions in Colloidal Dispersions. Pure and Applied Chemistry 48:4, pages 471-483.
Crossref

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