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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 106, 2008 - Issue 15
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Research Article

Direct observation of the symmetric stretching modes of Ã1Au acetylene by pulsed supersonic jet laser induced fluorescence

Adam H. Steeves Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA, USA
,
Anthony J. Merer Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, Taiwan; Department of Chemistry, University of British Columbia, Vancouver, Canada
,
Hans A. Bechtel Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA, USA
,
Annelise R. Beck Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA, USA
&
Robert W. Field Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA, USACorrespondence[email protected]
Pages 1867-1877 | Received 23 May 2008, Accepted 17 Jul 2008, Published online: 07 Oct 2008

Citations (16)

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Read on this site (2)

Brian J. Orr. (2018) Collision-induced rovibrational energy transfer in small polyatomic molecules: the role of intramolecular perturbations. Molecular Physics 116:23-24, pages 3666-3700.
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J.H. Baraban, J.F. Stanton, A.J. Merer & R.W. Field. (2012) Anharmonic force fields of cis- and trans-S1 C2H2 . Molecular Physics 110:21-22, pages 2725-2733.
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Articles from other publishers (14)

Kirill ProzumentJoshua H. Baraban, P. Bryan Changala, G. Barratt ParkRachel G. ShaverJohn S. MuenterStephen J. Klippenstein, Vladimir Y. Chernyak & Robert W. Field. (2019) Photodissociation transition states characterized by chirped pulse millimeter wave spectroscopy. Proceedings of the National Academy of Sciences 117:1, pages 146-151.
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Jun Jiang, Catherine A. Saladrigas, Trevor J. Erickson, Clare L. Keenan & Robert W. Field. (2018) Probing the predissociated levels of the S1 state of acetylene via H-atom fluorescence and photofragment fluorescence action spectroscopy. The Journal of Chemical Physics 149:17.
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J. H. Baraban, P. B. Changala, G. C. Mellau, J. F. Stanton, A. J. Merer & R. W. Field. (2015) Spectroscopic characterization of isomerization transition states. Science 350:6266, pages 1338-1342.
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P. Bryan Changala, Joshua H. Baraban, Anthony J. Merer & Robert W. Field. (2015) Probing cis-trans isomerization in the S1 state of C2H2 via H-atom action and hot band-pumped IR-UV double resonance spectroscopies . The Journal of Chemical Physics 143:8.
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Adam H. Steeves, G. Barratt Park, Hans A. Bechtel, Joshua H. Baraban & Robert W. Field. (2015) Communication: Observation of local-bender eigenstates in acetylene. The Journal of Chemical Physics 143:7.
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G. Barratt Park, Joshua H. Baraban & Robert W. Field. (2014) Full dimensional Franck-Condon factors for the acetylene $\tilde{\mathbf {A}}$Ã  1 A u —$\mathbf {\tilde{X}}$X̃ $\mathbf {^1\Sigma _g^+}$Σg+1 transition. II. Vibrational overlap factors for levels involving excitation in ungerade modes . The Journal of Chemical Physics 141:13.
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G. Barratt Park. (2014) Full dimensional Franck-Condon factors for the acetylene $\tilde{\mathbf {A}}$Ã  1 A u —$\mathbf {\tilde{X}}$X̃ $\mathbf {^1\Sigma _g^+}$Σg+1 transition. I. Method for calculating polyatomic linear—bent vibrational intensity factors and evaluation of calculated intensities for the gerade vibrational modes in acetylene . The Journal of Chemical Physics 141:13.
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P. Bryan Changala, Joshua H. Baraban, John F. Stanton, Anthony J. Merer & Robert W. Field. (2014) Reduced dimension rovibrational variational calculations of the S1 state of C2H2. II. The S1 rovibrational manifold and the effects of isomerization. The Journal of Chemical Physics 140:2.
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P. Bryan Changala. (2014) Reduced dimension rovibrational variational calculations of the S1 state of C2H2. I. Methodology and implementation. The Journal of Chemical Physics 140:2.
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Jun Jiang, Joshua H. Baraban, G. Barratt Park, Michelle L. Clark & Robert W. Field. (2013) Laser-Induced Fluorescence Study of the S 1 State of Doubly-Substituted 13 C Acetylene and Harmonic Force Field Determination . The Journal of Physical Chemistry A 117:50, pages 13696-13703.
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Kyle L. Bittinger, Wilton L. Virgo & Robert W. Field. (2011) Spectral Signatures of Inter-System Crossing Mediated by Energetically Distant Doorway Levels: Examples from the Acetylene S 1 State . The Journal of Physical Chemistry A 115:43, pages 11921-11943.
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Anthony J. Merer, Adam H. Steeves, Joshua H. Baraban, Hans A. Bechtel & Robert W. Field. (2011) Cis-trans isomerization in the S1 state of acetylene: Identification of cis-well vibrational levels. The Journal of Chemical Physics 134:24.
Crossref
J. H. Baraban, A. R. Beck, A. H. Steeves, J. F. Stanton & R. W. Field. (2011) Reduced dimension discrete variable representation study of cis–trans isomerization in the S1 state of C2H2 . The Journal of Chemical Physics 134:24.
Crossref
Adam H. Steeves, Hans A. Bechtel, Anthony J. Merer, Nami Yamakita, Soji Tsuchiya & Robert W. Field. (2009) Stretch-bend combination polyads in the Ã1Au state of acetylene, C2H2. Journal of Molecular Spectroscopy 256:2, pages 256-278.
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