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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 27, 1974 - Issue 3
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Original Articles

High-resolution MCD spectroscopy of transition metal ions in fluoride crystals

I. The 6A1g→4A1g, 4Ega (4G) no-phonon transitions of Mn2+ in KMgF3 and KZnF3

J. Ferguson Research School of Chemistry, Australian National University, P.O. Box 4, Canberra, 2600, Australia
,
E.R. Krausz Research School of Chemistry, Australian National University, P.O. Box 4, Canberra, 2600, Australia
&
H.J. Guggenheim Bell Laboratories Inc., Murray Hill, New Jersey, 07974, U.S.A.
Pages 577-591 | Received 19 Jun 1973, Published online: 22 Aug 2006

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B. C. Venkata Reddy, J. Lakshmana Rao, K. Sudhakar & B. Munibhadraiah. (1984) Electronic absorption spectruf: Of Mn2+ ions doped in lithium ammonium sulphate sikgle crystal. Ferroelectrics Letters Section 2:4, pages 147-156.
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S.V. J. Lakshman & A. Sundar Jacob. (1983) Absorption Spectrum of Mn2+ in LiKSO4 . Spectroscopy Letters 16:5, pages 379-391.
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V.L.R. Murthy, J.L. Rao & S.V.J. Lakshman. (1982) Absorption Spectrum of Manganese Formate Dihydrate at Liquid Nitrogen Temperature. Spectroscopy Letters 15:4, pages 313-323.
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K. Purandar, C.V. R. Dhaveji, J. Lakshmana Rao & S.V. J. Lakshman. (1981) Low Temperature Absorption Spectrum of Mn2+ Ions Doped in Diglycine Barium Chloride Monohydrate. Spectroscopy Letters 14:7, pages 465-479.
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James Ferguson, Hiromitsu Masui & Yukito Tanabe. (1979) Optical spectra of nearest neighbour nickel pairs in KMgF3 and KZnF3 crystals. Molecular Physics 37:3, pages 737-748.
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Lucjan Dubicki, James Ferguson & BarryV. Harrowfield. (1977) Exchange interactions in a trigonal chromium(III) pair. Molecular Physics 34:6, pages 1545-1561.
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M. Vala, J.C. Rivoal & J. Badoz. (1975) Magnetic circular and linear dichroism in cubic high spin d5 complex. Molecular Physics 30:5, pages 1325-1344.
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James Ferguson, ElmarsR. Krausz & HowardJ. Guggenheim. (1975) MCD spectroscopy of transition metal ions in fluoride crystals. Molecular Physics 29:6, pages 1785-1796.
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James Ferguson, E.R. Krausz & H.J. Guggenheim. (1975) High resolution MCD spectroscopy of transition metal ions in fluoride crystals. Molecular Physics 29:4, pages 1021-1033.
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J. Ferguson, H.U. Güdel, E.R. Krausz & H.J. Guggenheim. (1974) High resolution phosphorescence excitation spectroscopy of exchange coupled Mn2+ pairs in KMgF3 and KZnF3 . Molecular Physics 28:4, pages 893-904.
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J. Ferguson, H.U. Güdel, E.R. Krausz & H.J. Guggenheim. (1974) High resolution MCD and phosphorescence excitation spectroscopy of Mn2+ in KMgF3 and KZnF3 . Molecular Physics 28:4, pages 879-891.
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Ram Kripal, Har Govind, S.K. Gupta & Manju Arora. (2007) EPR and optical absorption study of Mn2+-doped zinc ammonium phosphate hexahydrate single crystals. Physica B: Condensed Matter 392:1-2, pages 92-98.
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Ram Kripal, Har Govind & Manju Maurya. (2007) EPR and optical study of Mn2+-doped lithium hydrogen oxalate monohydrate single crystals. Journal of Magnetism and Magnetic Materials 308:2, pages 243-249.
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Ram Kripal & Vishal Mishra. (2005) EMR and optical study of Mn2+ doped potassium trihydrogen selenite. Journal of Magnetic Resonance 172:2, pages 201-208.
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Ram Kripal & Vishal Mishra. (2005) ESR and optical study of Mn2+ doped potassium hydrogen sulphate. Solid State Communications 133:1, pages 23-28.
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Ch Linga Raju, K.V Narasimhulu, N.O Gopal, J.L Rao & B.C.V Reddy. (2002) Electron paramagnetic resonance, optical and infrared spectral studies on the marine mussel Arca burnesi shells. Journal of Molecular Structure 608:2-3, pages 201-211.
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Frank Neese & Edward I. Solomon. (1999) MCD C -Term Signs, Saturation Behavior, and Determination of Band Polarizations in Randomly Oriented Systems with Spin S ≥ 1 / 2 . Applications to S = 1 / 2 and S = 5 / 2 . Inorganic Chemistry 38:8, pages 1847-1865.
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R. Rama Kumar, A. Srinivasa Rao & B. C. Venkata Reddy. (1996) E.p.r. and optical absorption of Mn2+ ions in ternary K2SO4 − Na2SO4-ZnSO4 glasses. Transition Metal Chemistry 21:5, pages 390-392.
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R. Parrot, D. Boulanger, B. Litzenburger, U. W. Pohl, H. E. Gumlich & M. N. Diarra. (1995) High-resolution study of the magnetic-field effect on the E state of in cubic ZnS by laser spectroscopy . Physical Review B 52:19, pages 13983-13991.
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A. C. Lewandowski & T. M. Wilson. (1994) Ab initio multiconfiguration self-consistent-field calculations of the excited states of a Mn impurity in . Physical Review B 50:5, pages 2780-2791.
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F. Rodríguez, H. Riesen & H.U. Güdel. (1991) Luminescence properties of Mn2+ in KMgF3 and KZnF3 perovskite crystals. Journal of Luminescence 50:2, pages 101-110.
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J.R.G. Thorne, R.G. Denning & I.D. Morrison. (1988) Two-photon excitation spectroscopy of Mn2+. Journal of Luminescence 40-41, pages 519-520.
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J.S. Cook, J.S. Dryden, P.B. Gwan & J. Ferguson. (1987) Photochemical production of F centers in KBr crystals doped with Se2−. Chemical Physics Letters 138:5, pages 415-418.
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K. Ramesh & Y.P. Reddy. (1987) Optical absorption of manganese-doped LiRbSO4. Materials Letters 5:5-6, pages 189-192.
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B.C.Venkata Reddy, B. Munibhadraiah & I.Aruna Kumari. (1987) Electronic absorption spectrum of Mn2+ ions doped in ammonium perchlorate single crystal. Materials Letters 5:4, pages 156-158.
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James Ferguson, Elmars Krausz & Julian Vrbancich. (1986) Magnetic circular dichroism and the assignments of metal-ligand charge transfer states in Ru(bpy)32+ and related systems. Chemical Physics Letters 131:6, pages 463-467.
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A. V. Malakhovskii, G. G. Vasilev & T. P. Morozova. (1986) Temperature Dependences of6A1g →4A1g,4Eg(4G) and6A1g →4Eg(4D) Absorption Bands in RbMnF3 in Paramagnetic State. physica status solidi (b) 138:1, pages 285-293.
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J.S. Cook, J.S. Dryden & J. Ferguson. (1986) Electronic spectroscopy of Se2- in KBr. Journal of Luminescence 36:1, pages 1-9.
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J S Cook, J S Dyrden, J Ferguson & P B Gwan. (1986) Magnetic circular dichroism, electric conductivity and mobility of anion vacancies in KBr:Se 2- . Journal of Physics C: Solid State Physics 19:25, pages 4999-5004.
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Betty Ng & D. J. Newman. (1986) A linear model of crystal field correlation effects in Mn2+. The Journal of Chemical Physics 84:6, pages 3291-3296.
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N. Satyanarayana & S. Radhakrishna. (1986) Electronic absorption spectra of Mn2+ ion in Cd(NH4)2(SO4)2 · 6H2O and CdK2(SO4)2 · 6H2O single crystals. Physica B+C 138:1-2, pages 97-102.
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D. K. Sardar, M. D. Shinn & W. A. Sibley. (1982) Radiation-defect-perturbed and optical transitions in RbMg . Physical Review B 26:5, pages 2382-2389.
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James Ferguson, Fritz Herren & George M. McLaughlin. (1982) The circular dichroism of the charge-transfer bands of M(bpy)2+3 (M = Re, Ru, Os). Chemical Physics Letters 89:5, pages 376-380.
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B. Ghosh & R. K. Mukherjee. (2006) Electronic Absorption Spectrum of Rb 2 MnCl 4 Single Crystals . physica status solidi (b) 106:2, pages 699-706.
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J. Lakshmana Rao & K. Purandar. (1981) Electronic absorption spectrum of Mn2+ ions doped in diglycine barium chloride monohydrate. Solid State Communications 37:12, pages 983-986.
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B. Ghosh & R. K. Mukherjee. (2006) Reinvestigation of the Luminescence Spectra of CdCl 2 :Mn 2+ Single Crystals . physica status solidi (b) 102:2.
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Lucjan Dubicki, James Ferguson, Rodney J. Geue & Alan M. Sargeson. (1980) Circular dichroism of cobalt(III) complexes: dependence on the outer sphere configuration. Chemical Physics Letters 74:3, pages 393-397.
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L Dubicki, J Ferguson & B van Oosterhout. (1980) A magneto-optical study of the 2 T 1g , 4 T 2g , 2 E g from 4 A 2g transitions in K 2 NaGaF 6 :Cr 3+ . Journal of Physics C: Solid State Physics 13:14, pages 2791-2798.
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V.Ya. Mitrofanov, V.A. Sapozhnikov, A.E. Nikiforov & A.N. Men. (1980) Exchange interactions of transition-metal ions in in orbitally degenerated excited states. Journal of Magnetism and Magnetic Materials 20:2, pages 141-147.
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Maria Cieślak-Golonka, Adam Bartecki & Shyama P. Sinha. (1980) Vibrational fine structure in the electronic spectra of transition metal compounds. an experimental survey. Coordination Chemistry Reviews 31:3, pages 251-288.
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J. Ferré, J. Pommier, I.R. Jahn & Y. Tanabe. (1980) Exchange dipole optical transition in the manganese aluminosilicate glass: An insulating spin glass. Solid State Communications 33:1, pages 27-30.
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Lucjan Dubicki & James Ferguson. (1979) Interference transition electric dipole mechanism in MCD spectroscopy. Chemical Physics Letters 68:2-3, pages 507-510.
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Richard Alan Palmer, Mark Chin-Lan Yang & Judith C. Hempel. (2002) Electronic structure of the tris(ethylenediamine)manganese(II) ion. Circular and linear dichroism and electron paramagnetic resonance spectra of tris(ethylenediamine)manganese(II) nitrate. Inorganic Chemistry 17:5, pages 1200-1203.
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W. A. Sibley & N. Koumvakalis. (1976) Perturbed transitions in irradiated RbMg :Mn . Physical Review B 14:1, pages 35-40.
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Judith C. Hempel. (1976) Trigonal ligand field and zero field splitting diagrams for the d 5 configuration . The Journal of Chemical Physics 64:11, pages 4307-4313.
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P Rudra & M K Sikdar. (1976) Tables of Clebsch-Gordan coefficients of magnetic point groups. Journal of Physics C: Solid State Physics 9:1, pages 1-4.
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K. H. Lee & W. A. Sibley. (1975) Exchange enhancement of and transitions due to radiation defects . Physical Review B 12:8, pages 3392-3399.
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G. B. Scott, D. E. Lacklison, H. I. Ralph & J. L. Page. (1975) Magnetic circular dichroism and Faraday rotation spectra of . Physical Review B 12:7, pages 2562-2571.
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Dante Gatteschi & Elmars Krausz. (1975) Single crystal MCD of five coordinate Co(II) and Ni(II) complexes. Chemical Physics Letters 34:2, pages 348-351.
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Ath. Trut̨ia, V. Ghiordǎnescu & M. Voda. (2006) On the Optical Spectrum of CdCl 2 :Mn Single Crystals . physica status solidi (b) 70:1.
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Tekeo Fujiwara & Yukito Tanabe. (1974) 4 E g (G) Exciton of RbMnF 3 . Journal of the Physical Society of Japan 37:6, pages 1512-1520.
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