Advanced search
Publication Cover
Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 29, 1975 - Issue 4
Submit an article Journal homepage
23
Views
61
CrossRef citations to date
0
Altmetric
Original Articles

E.S.R. study of copper and silver N,N-dialkyldiselenocarbamates

Part II. Interpretation of spectra measured in host lattices with monomeric structures

C.P. Keijzers Department of Physical Chemistry, University of Nijmegen, Toernooiveld, Nijmegen, The Netherlands
&
E. de Boer Department of Physical Chemistry, University of Nijmegen, Toernooiveld, Nijmegen, The Netherlands
Pages 1007-1020 | Received 19 Jul 1974, Published online: 22 Aug 2006

Citations (61)

Keep up to date with the latest research on this topic with citation updates for this article.

Subscribe to citation updates

Read on this site (11)

M.C.M. Gribnau & E. De Boer. (1991) The magnetic structure of sodium biphenyl bistriglyme. Molecular Physics 73:4, pages 819-829.
Read now
R. Kirmse, W. Dietzsch, J. Stach, L. Golič, R. Böttcher, W. Brunner, M.C.M. Gribnau & C.P. Keijzers. (1986) Ligand exchange reactions between copper(II)- and nickel(II)-chelates of different sulphur- and selenium-containing ligands. Molecular Physics 57:6, pages 1139-1152.
Read now
R. Böttcher, R. Kirmse, J. Stach & C.P. Keijzers. (1985) Single-crystal ENDOR-TRIPLE resonance studies on copper(II) complexes with unsaturated dichalcogeno ligands. Molecular Physics 55:6, pages 1431-1445.
Read now
A. Bencini & D. Gatteschi. (1985) Calculating EPR Spin Hamiltonian Parameters of Transition Metal Complexes. Comments on Inorganic Chemistry 4:2, pages 99-111.
Read now
C.P. Keijzers, G. van Kalkeren, E. de Boer & J.S. Wood. (1983) Tetragonal distortions in the jahn-teller active copper pyridine-N-oxide complexes. Molecular Physics 49:5, pages 1187-1197.
Read now
WilliamE. Hatfield. (1981) Effect of Bridge Geometry on Exchange Coupling in Ligand-Bridged Copper(II) Dimers and Chains. Comments on Inorganic Chemistry 1:2, pages 105-121.
Read now
D. Snaathorst, C.P. Keijzers, A.A.K. Klaassen, E. De Boer, V.P. Chacko & R. Gomperts. (1980) Proton ENDOR study of copper(II) bis(dithiocarbamate). Molecular Physics 40:3, pages 585-596.
Read now
B.S. Prabhananda. (1979) Anisotropic g and hyperfine tensors from E.S.R. linewidth studies of liquid solutions: Cu{(i-C3H7O)2PSe2}2 . Molecular Physics 38:1, pages 209-217.
Read now
D. Attanasio, C.P. Keijzers, J.P. van de Berg & E. de Boer. (1976) E.S.R. study of copper dithio- and diselenophosphate. Molecular Physics 31:2, pages 501-514.
Read now
C.P. Keijzers & E. de Boer. (1975) E.S.R. study of copper and silver N,N-dialkyldiselenocarbamates. Molecular Physics 29:6, pages 1743-1748.
Read now
C.P. Keijzers, P.L.A. Chr.M. van der Meer & E. de Boer. (1975) E.S.R. study of copper and silver N,N-dialkyldiselenocarbamates. Molecular Physics 29:6, pages 1733-1742.
Read now

Articles from other publishers (50)

Saurabh Kumar Singh, Mihail Atanasov & Frank Neese. (2018) Challenges in Multireference Perturbation Theory for the Calculations of the g -Tensor of First-Row Transition-Metal Complexes . Journal of Chemical Theory and Computation 14:9, pages 4662-4677.
Crossref
Sushil K. Misra. 2011. Multifrequency Electron Paramagnetic Resonance. Multifrequency Electron Paramagnetic Resonance 57 113 .
Piotr Pietrzyk & Zbigniew Sojka. (2005) Relativistic Density Functional Calculations of EPR g Tensor for η{CuNO} 11 Species in Discrete and Zeolite-Embedded States . The Journal of Physical Chemistry A 109:46, pages 10571-10581.
Crossref
Ram Kripal & Sanjay Misra. (2005) ESR of copper-doped sodium citrate. Journal of Magnetism and Magnetic Materials 294:1, pages 72-82.
Crossref
Frank Neese & Edward I. Solomon. 2004. Magnetism: Molecules to Materials. Magnetism: Molecules to Materials 345 466 .
Michael Kampf, Jan Griebel & Reinhard Kirmse. (2004) EPR‐spektroskopische Charakterisierung (X‐, Q‐Band) monomerer Ag II ‐ und Au II ‐Komplexe der Thiakronenether [12]anS 4 , [16]anS 4 , [18]anS 6 und [27]anS 9 . Zeitschrift für anorganische und allgemeine Chemie 630:15, pages 2669-2676.
Crossref
Reinhard Felsberg, Steffen Blaurock, Peter C. Junk, Reinhard Kirmse, Andreas Voigt & Evamarie Hey‐Hawkins. (2004) Organometallic Molybdenum(V) Complexes with Primary Phosphine Ligands. Syntheses, Spectroscopic Properties and Molecular Structures of [Cp°MoCl 4 (PH 2 R)] (R = Bu t , 1‐Ad, Cy, Ph, 2, 4, 6‐Me 3 C 6 H 2 , 2, 4, 6‐Pr i 3 C 6 H 2 , Cp° = C 5 EtMe 4 ) . Zeitschrift für anorganische und allgemeine Chemie 630:6, pages 806-816.
Crossref
Frank Neese. (2001) Theoretical Study of Ligand Superhyperfine Structure. Application to Cu(II) Complexes. The Journal of Physical Chemistry A 105:17, pages 4290-4299.
Crossref
Frank Neese. (2001) Configuration interaction calculation of electronic g tensors in transition metal complexes* . International Journal of Quantum Chemistry 83:3-4, pages 104-114.
Crossref
Guillaume Morin & Dominique Bonnin. (1999) Modeling EPR Powder Spectra Using Numerical Diagonalization of the Spin Hamiltonian. Journal of Magnetic Resonance 136:2, pages 176-199.
Crossref
L. Ihlo, R. Böttcher, R.-M. Olk & R. Kirmse. (1998) A single-crystal electron paramagnetic resonance, 13C and 1H electron nuclear double resonance study of tetra-n-butylammonium-bis(1,2-dicyanoethylene-1,2-dithiolato)aurate(II), [(n-C4H9)4N]2[AuII(mnt)2]. Inorganica Chimica Acta 281:2, pages 160-164.
Crossref
A. Voigt, U. Abram, P. Strauch & R. Kirmse. (1998) An electron paramagnetic resonance study of tetra-n-butylammoniumtetrabromo-nitridorhenate(VI), [(n-C4H9)4N][ReNBr4]. Inorganica Chimica Acta 271:1-2, pages 199-202.
Crossref
Oliver Sorgenfrei, Evert C. Duin, Albrecht Klein & Simon P. J. Albracht. (2004) Changes in the Electronic Structure Around Ni in Oxidized and Reduced Selenium‐Containing Hydrogenases from Methanococcus Voltae . European Journal of Biochemistry 247:2, pages 681-687.
Crossref
Reinhard Felsberg, Steffen Blsurock, Svea Jelonek, Thomas Gelbrich, Reinhard Kirmse, Andreas Voigt & Evamarie Hey‐Hawkins. (2006) Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl 4 (PH 2 R)] (R=2,4,6‐Pr i 3 C 6 H 2 , Cyclohexyl, Cp′=C 5 H 4 Me) . Chemische Berichte 130:6, pages 807-812.
Crossref
Reinhard Kirmse, E. Möller, Chr. Seitz & J. Reinhold. (2004) Zum Redoxverhalten von Dithiolenkomplexen des Typs [M IV (S 2 C 2 R 2 ) 2 ] 0 der Nickel‐Triade . Zeitschrift für anorganische und allgemeine Chemie 623:1-6, pages 159-168.
Crossref
Frank Neese, Walter G. Zumft, William E. Antholine & Peter M. H. Kroneck. (1996) The Purple Mixed-Valence Cu A Center in Nitrous-oxide Reductase:  EPR of the Copper-63-, Copper-65-, and Both Copper-65- and [ 15 N]Histidine-Enriched Enzyme and a Molecular Orbital Interpretation . Journal of the American Chemical Society 118:36, pages 8692-8699.
Crossref
A. Buttafava, A. Faucitano, F. Martinotti, N. Iazzi & E. Rotondo. (1995) Matrix isolation and ESR study of platinum(I) diolefin complexes—norbornadiene and (1,5-cyclooctadiene) platinum dichloride radical anions. Radiation Physics and Chemistry 45:1, pages 37-43.
Crossref
Simone Saluschke, Maren Pink, W. Dietzsch, R. Kirmse & N. Law. (2004) EPR‐Einkristalluntersuchungen System Fe(NO)(Et 2 dsc) 2 /In(Et 2 dsc) 3 (Et 2 dsc = Diethyldiselenocarbamat). Kristall‐ und Molekülstruktur von Tris(diethyldiselenocarbamato)indium(III), In(Et 2 dsc) 3 . Zeitschrift für anorganische und allgemeine Chemie 619:11, pages 1862-1868.
Crossref
Ruth‐Maria Olk, B. Olk, J. Rohloff, J. Reinhold, J. Sieler, Kirsten Trübenbach, R. Kirmse & E. Hoyer. (2004) Zur Koordinationschemie des 1,3‐Dithiol‐2‐selon‐4,5‐diselenolats (dsise) und des 1,3‐Dithiol‐2‐selon‐4,5‐dithiolats (dmise). Kristall‐ und Molekülstruktur des Tetrabutylammonium‐bis‐(1,3‐dithiol‐2‐selon‐4,5‐diselenolato)nickelat(II) und ‐(III), [(n‐C 4 H 9 ) 4 N] 2 [Ni(dsise) 2 ] und (n‐C 4 H 9 ) 4 N[Ni(dsise) 2 ] . Zeitschrift für anorganische und allgemeine Chemie 609:3, pages 103-116.
Crossref
R. Kirmse & P. Strauch. (2004) EPR‐Untersuchungen an Kupfer(II)‐Bis‐Komplexen mit Thiooxalaten. Zeitschrift für anorganische und allgemeine Chemie 600:1, pages 61-66.
Crossref
A. Buttafava, A. Faucitano & F. Martinotti. (1991) Matrix isolation and ESR study of unstable intermediate generated by radiation techniques from metal carbonyl complexes. International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry 37:4, pages 567-571.
Crossref
K. Köhler, R. Kirmse, R. Böttcher, U. Abram, M.C.M. Gribnau, C.P. Keijzers & E. De Boer. (1990) Single-crystal EPR, 35,37Cl and 14,15N ENDOR and ESEEM studies on (Ph4As)[TcVINCl4/TcVOCl4]. II. Determination of the 35,37Cl and 14,15N hyperfine and quadrupole tensors by ENDOR and ESEEM. Chemical Physics 143:1, pages 83-95.
Crossref
M Cook & C T White. (1989) Molecular electronic structure theory in the study of localised defects. Semiconductor Science and Technology 4:12, pages 1012-1035.
Crossref
Michael Cook & C. T. White. (1988) Hyperfine interactions in cluster models of the defect center . Physical Review B 38:14, pages 9674-9685.
Crossref
Friedrich Ritschl & Helmut Haberlandt. (1988) MO theoretical calculations of EPR parameters of vanadium compounds. Journal of Molecular Structure: THEOCHEM 180, pages 45-63.
Crossref
E. G. Musaev, E. G. Ismailov & A. A. Medzhidov. (1987) ESR studies of Mo−Mg oxide catalysts. Reaction Kinetics and Catalysis Letters 33:2, pages 253-258.
Crossref
William Levason & Mark D. Spicer. (1987) The chemistry of copper and silver in their higher oxidation states. Coordination Chemistry Reviews 76, pages 45-120.
Crossref
Ivan Leban, Ljubo Golič, Reinhard Kirmse, Joachim Stach, Ulrich Abram, Hans-joachim Sieler, Wolfgang Dietzsch, Huub Vergoossen & Kees P. Keijzers. (1986) Ligand exchange reactions between copper(II) and nickel(II) chelates of different sulphur and selenium containing ligands. VII. Single-crystal ESR study on the mixed ligand chelate system Ph4As[Cu/Zn(mnt)(Et2dtc)] and crystal and molecular structure of Ph4As[Zn(mnt)(Et2dtc)]. Inorganica Chimica Acta 112:2, pages 107-112.
Crossref
R. Kirmse, J. Stach & U. Abram. (1985) EPR on tetrabutylammonium tetraiodo-nitrosyltechnetate(II), (Bu4N)[Tc(NO)I4]. Polyhedron 4:7, pages 1275-1277.
Crossref
J. Stach, R. Kirmse, C. Nieke, J. Reinhold & R. Böttcher. (1984) Endor and triple resonance on covalent copper(II) complexes, comparison of experimental results with semi-empirical quantum-chemical calculations. Chemical Physics Letters 112:4, pages 371-375.
Crossref
R. Kirmse, J. Stach, U. Abram & I. N. Marov. (2004) Zu Struktur, Bindung und Ligandenaustauschverhalten von Nitrosyltechnetium(II)‐Verbindungen Eine. EPR‐Untersuchung. Zeitschrift für anorganische und allgemeine Chemie 518:11, pages 210-226.
Crossref
Joachim Stach, Reinhard Kirmse, Ulrich Abram, Wolfgang Dietzsch, Jan H. Noordik, Karel Spee & Kees P. Keijzers. (1984) Ligand exchange reactions between copper(II)- and nickel(II)- chelates of different sulphur- and selenium-containing ligandsIII. Polyhedron 3:4, pages 433-442.
Crossref
Reinhard Kirmse, Bernd Lorenz & Klaus Schmidt. (1983) EPR on trichloro-nitrosyl-bis(dimethylphenylphosphine)technetium(II) TcCl3(NO)(PMe2Ph)2. Polyhedron 2:9, pages 935-939.
Crossref
R. Kirmse, J. Stach & D. Walther. (2004) Wechselwirkungen von Hetero‐π‐Systemen mit Zentralmetallatomen in niedrigen Oxydationsstufen. ESR‐Untersuchungen zur Struktur und Bindung an Niedrig‐spin‐d 5 ‐(S = 1/2)‐Tris(benzil‐bis‐N‐phenylimin)vanadium(0) und Bis(benzil‐bis‐N‐phenylimin)cobalt(0) . Zeitschrift für anorganische und allgemeine Chemie 496:1, pages 147-158.
Crossref
R. Kirmse, U. Abram & R. Bötther. (1982) A 13C endor study on Copper(II)/Zinc(II) bis-(diethyl-dithiocarbamate) Cu/Zn(et2dtc)2. Chemical Physics Letters 88:1, pages 98-102.
Crossref
K. K. Sunil, J. F. Harrison & Max T. Rogers. (1982) An SCF–MS– X α study of a series of d 1 transition metal oxohalo complexes . The Journal of Chemical Physics 76:6, pages 3087-3097.
Crossref
K. K. Sunil, J. F. Harrison & Max T. Rogers. (1982) Electronic structure and ESR parameters of (CrOCl4)−. The Journal of Chemical Physics 76:6, pages 3078-3086.
Crossref
R. Kirmse, J. Stach & G. Kreisel. (1981) A single-crystal esr study on a tetrahedrally coordinated vanadium(IV) compound: tetramesitylvanadium(IV). Journal of Organometallic Chemistry 210:1, pages 73-82.
Crossref
Reinhard Kirmse, Joachim Stach & Günter Kreisel. (2010) ESR‐Untersuchungen an einem tetraedrisch koordinierten Vanadium (IV)‐Komplex: Tetramesitylvanadium (IV). Zeitschrift für Chemie 20:10, pages 385-386.
Crossref
P. J. M. Geurts, P. C. P. Bouten & A. van der Avoird. (1980) Hartree–Fock–Slater–LCAO calculations on the Cu(II) bis(dithiocarbamate) complex; magnetic coupling parameters and optical spectrum. The Journal of Chemical Physics 73:3, pages 1306-1312.
Crossref
J. Stach, R. Kirmse, W. Dietzsch, I. N. Marov & V. K. Belyaeva. (2004) EPR‐Untersuchungen am Tris(maleonitrildithiolato)niobat(IV)‐Anion. Zeitschrift für anorganische und allgemeine Chemie 466:1, pages 36-40.
Crossref
J R Pilbrow & M R Lowrey. (1980) Low-symmetry effects in electron paramagnetic resonance. Reports on Progress in Physics 43:4, pages 433-495.
Crossref
C.P. Keijzers & D. Snaathorst. (1980) Multi-centre contributions to the anisotropic hyperfine interactions in the cu(ii) bis(dithiocarbamate) complex. Proton hyperfine couplings. Chemical Physics Letters 69:2, pages 348-353.
Crossref
Joachim Stach, Reinhard Kirmse, Siegfried Wartewig & Rolf Böttcher. (2010) EHT‐SCCC‐ Berechnungen zur Interpretation der Tensorparameter des Spin‐Hamilton‐operators von Kupfer (II)‐Chelaten. Zeitschrift für Chemie 19:6, pages 205-210.
Crossref
Dimitri Coucouvanis. 1979. Progress in Inorganic Chemistry. Progress in Inorganic Chemistry 301 469 .
J. Stach, R. Kirmse, E. Hoyer & S. Wartewig. (1978) EPR study of bis-(N,N-diethylthioselenogarbamato)-copper(II). Journal of Molecular Structure 46, pages 245-250.
Crossref
J. Stach, R. Kirmse, E. Hoyer & S. Wartewig. (1978) A single-crystal and powder ESR study of copper(II)-bis(diethyl-thioselenocarbamate). Noncoinciding principal axes of g and A. Journal of Inorganic and Nuclear Chemistry 40:8, pages 1529-1532.
Crossref
John F. Boas, John R. Pilbrow & Thomas D. Smith. 1978. Biological Magnetic Resonance. Biological Magnetic Resonance 277 342 .
R. Kirmse, L. Beyer & E. Hoyer. (1977) A single-crystal ESR study of bis(1,1-diisobutyl-3-benzoyl-selenoureato)-copper(II). Chemical Physics Letters 49:3, pages 544-546.
Crossref
J. Willemse, J. A. Cras, J. J. Steggerda & C. P. Keijzers. 1976. Electrons in Oxygen- and Sulphur-Containing Ligands. Electrons in Oxygen- and Sulphur-Containing Ligands 83 126 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.