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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 30, 1975 - Issue 1
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Original Articles

What is the influence of a ‘heavy atom’ on the decay mechanisms of the lowest triplet state of aromatic hydrocarbons?

J. Friedrich Institut für Physikalische Chemie und Elektrochemie der Technischen Universität München, Munich, Germany
,
F. Metz Institut für Physikalische Chemie und Elektrochemie der Technischen Universität München, Munich, Germany
&
F. Dörr Institut für Physikalische Chemie und Elektrochemie der Technischen Universität München, Munich, Germany
Pages 289-312 | Received 26 Apr 1974, Published online: 23 Aug 2006

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ThomasG. Gray. (2007) GILDED ORGANOMETALLICS. Comments on Inorganic Chemistry 28:5-6, pages 181-212.
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Shigeya Niizuma, Lawrence Kwan & Noboru Hirota. (1978) E.P.R. and zero-field odmr studies of the T 1 states of halogen-containing benzonitriles, anisoles and anilines. Molecular Physics 35:4, pages 1029-1046.
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Articles from other publishers (39)

E. A. Gastilovich, L. V. Volkova & V. G. Klimenko. (2010) Model and calculation of rate constants of nonradiative T-S intersystem conversion: Test by example of naphthalene and its chlorine derivatives. Optics and Spectroscopy 109:4, pages 543-552.
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E. A. Gastilovich, N. V. Korol’kova & V. G. Klimenko. (2010) Rate constants of nonradiative intersystem crossing transition S 1(ππ*) ⇝ T 1(ππ*) in molecules of aromatic compounds with heteroatoms. Optics and Spectroscopy 109:1, pages 72-84.
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R. Aaron Vogt, Miya A. Peay, Thomas G. Gray & Carlos E. Crespo-Hernández. (2010) Excited-State Dynamics of (Organophosphine)gold(I) Pyrenyl Isomers. The Journal of Physical Chemistry Letters 1:8, pages 1205-1211.
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E. A. Gastilovich, V. G. Klimenko, N. V. Korol’kova & R. N. Nurmukhametov. (2010) Role of structural elements of chloronaphthalene molecules in spin-orbit coupling: Phosphorescence. Optics and Spectroscopy 108:3, pages 486-494.
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Lei Gao, Miya A. Peay, David V. Partyka, James B. UpdegraffIIIIII, Thomas S. Teets, Arthur J. Esswein, Matthias Zeller, Allen D. Hunter & Thomas G. Gray. (2009) Mono- and Di-Gold(I) Naphthalenes and Pyrenes: Syntheses, Crystal Structures, and Photophysics. Organometallics 28:19, pages 5669-5681.
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E. A. Gastilovich, V. G. Klimenko, S. A. Serov & R. N. Nurmukhametov. (2009) Nonradiative S-T intersystem crossing in α and β chlorine derivatives of naphthalene. Optics and Spectroscopy 106:6, pages 799-807.
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Lei Gao, David V. Partyka, James B. UpdegraffIIIIII, Nihal Deligonul & Thomas G. Gray. (2009) Synthesis, Structures, and Excited‐State Geometries of Alkynylgold(I) Complexes. European Journal of Inorganic Chemistry 2009:18, pages 2711-2719.
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J. Catalán. (2005) Polarization of the T1→S0 phosphorescence and S0→Sn phosphorescence excitation of aromatic hydrocarbons prototype for π,π* states. A reappraisal. Chemical Physics 316:1-3, pages 253-259.
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Mohammad A. Omary, Ahmed A. Mohamed, Manal A. Rawashdeh-Omary & John P. FacklerJr.Jr.. (2005) Photophysics of supramolecular binary stacks consisting of electron-rich trinuclear Au(I) complexes and organic electrophiles. Coordination Chemistry Reviews 249:13-14, pages 1372-1381.
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Konstantin N. Solov'ev & Elena A. Borisevich. (2005) Intramolecular heavy-atom effect in the photophysics of organic molecules. Uspekhi Fizicheskih Nauk 175:3, pages 247.
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Ahmed A. Mohamed, Manal A. Rawashdeh-Omary, Mohammad A. Omary & John P. Fackler, Jr.. (2005) External heavy-atom effect of gold in a supramolecular acid–base π stack. Dalton Transactions:15, pages 2597.
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David F. Plusquellic, Scott R. Davis & Farid Jahanmir. (2001) Probing nuclear quadrupole interactions in the rotationally resolved S1←S electronic spectrum of 2-chloronaphthalene. The Journal of Chemical Physics 115:1, pages 225-235.
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Max Glasbeek. 2001. Transition Metal and Rare Earth Compounds. Transition Metal and Rare Earth Compounds 95 142 .
K. Gustav, M. Leonhardt & H. Port. (1997) Theoretical investigations on absorption and fluorescence of perylene and its tetracarboxylic derivativesTheoretische Untersuchungen der Absorption und Fluoreszenz von Perylen und seinen Tetracarbons�ure-Derivaten. Monatshefte f�r Chemie Chemical Monthly 128:2, pages 105-112.
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Jaco Westra & Max Glasbeek. (1991) Spin dynamics in the photo-excited triplet state of Rh3+-trisbipyridyl perchlorate. Chemical Physics Letters 180:1-2, pages 41-44.
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Sanjib Ghosh, Michael Petrin, August H. Maki & Lynn R. Sousa. (1987) Dependence of the triplet state properties on the orientation of metal ion perturbers in naphthalene-crown ether metal ion complexes. I. External heavy atom effect. The Journal of Chemical Physics 87:8, pages 4315-4323.
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N.J. Tro, J.J. Tro, D.F. Marten & A.M. Nishimura. (1987) External spin-orbit coupling on the 3n,π* state of several cycloalkanones. Journal of Photochemistry 36:2, pages 141-148.
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G. Gradl & J. Friedrich. (1985) Investigation of inhomogeneous line broadening of ODMR transitions in doped organic glasses. Chemical Physics Letters 114:5-6, pages 543-546.
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R. D. Coombe & M. H. Van Benthem. (1984) Radiative rates of singlet–triplet transitions in nitrogen halide diatomics. The Journal of Chemical Physics 81:7, pages 2984-2990.
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J. Najbar, W. Jarzeba & Z.H. Urbanek. (1983) Internal heavy-atom effect on the T1 states of monochloroquinolines and monochloronaphthalenes. Chemical Physics 79:2, pages 245-253.
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F.W. Deeg, Chr. Bräuchle & J. Voitländer. (1982) Distribution and conjugation of the π-electrons in the T1 state of some BNC-heterocycles. Chemical Physics 64:3, pages 427-436.
Crossref
FRANK H. QUINA. 1982. Chemical and Biological Generation of Excited States. Chemical and Biological Generation of Excited States 1 36 .
G. Weinzierl & J. Friedrich. (1981) Selective external heavy atom effect on the dynamics of the isolated triplet sublevels of naphthalene X-traps. Chemical Physics Letters 80:1, pages 55-59.
Crossref
Ulrich Steiner. (2010) A triplet mechanism for magnetic field modulation of photochemical quantum yields. Berichte der Bunsengesellschaft für physikalische Chemie 85:3, pages 228-233.
Crossref
G. Weinzierl & J. Friedrich. (1981) Heavy-atom effect in the electron-phonon coupling of naphthalene X-traps. Chemical Physics Letters 77:1, pages 139-142.
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R. Griebel. (2010) Abnormal Influences of Temperature and Fluidity on Fluorescence Depolarization of Solute Molecular Rotors. Berichte der Bunsengesellschaft für physikalische Chemie 84:9, pages 919-925.
Crossref
G. Flatscher & J. Friedrich. (1980) Position-dependent heavy atom effect in the subrates of the lowest triplet state of dichloronaphthalenes. Chemical Physics 49:3, pages 311-319.
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Barbara Zickendraht‐Wendelstadt, Josef Friedrich & Wolfhart Rüdiger. (2008) SPECTRAL CHARACTERIZATION OF MONOMERIC C‐PHYCOERYTHRIN FROM PSEUDANABAENA W 1173 AND ITS α AND β SUBUNITS: ENERGY TRANSFER IN ISOLATED SUBUNITS AND C‐PHYCOERYTHRIN. Photochemistry and Photobiology 31:4, pages 367-376.
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Hiroyuki Saigusa, Tohru Azumi, Minoru Sumitani & Keitaro Yoshihara. (1980) Internal heavy atom effect on the triplet spin sublevels of the lowest triplet state of naphthalene. II. Intersystem crossing processes from the singlet excited state to the individual spin sublevels of the lowest triplet state. The Journal of Chemical Physics 72:3, pages 1713-1715.
Crossref
J.J. Dekkers, G.Ph. Hoornweg, W.P. Cofino, C. MaClean & N.H. Velthorst. (1979) Orientation and phosphorescence polarization of planar hetero-aromatic molecules in stretched polyethylene films. Chemical Physics Letters 67:1, pages 24-29.
Crossref
Hiroyuki Saigusa & Tohru Azumi. (1979) Internal heavy atom effect on the triplet spin sublevels of the lowest triplet state of naphthalene. I. Radiative and nonradiative decays of the spin sublevels of 1-halonaphthalenes. The Journal of Chemical Physics 71:3, pages 1408-1413.
Crossref
J.J. Dekkers, G.Ph. Hoornweg, K.J. Terpstra, C. Maclean & N.H. Velthorst. (1978) Phosphorescence polarisation of aromatic compounds oriented in stretched polyethylene films. Chemical Physics 34:2, pages 253-260.
Crossref
Ulrich Steiner & Gerhard Winter. (1978) Position dependent heavy atom effect in physical triplet quenching by electron donors. Chemical Physics Letters 55:2, pages 364-368.
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Kh. I. Mamedov & �. N. Niyazova. (1978) Phosphorescence of the radical derived from 6-chloroquinoline at 20?K. Journal of Applied Spectroscopy 28:4, pages 459-462.
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H. Singh & J.D. Laposa. (1978) Intramolecular heavy atom effect on the polarization of phosphorescence of phenylacetylene. Journal of Luminescence 16:3, pages 257-278.
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V. A. Kuz'min, A. P. Darmanyan, V. I. Shirokova, M. A. Al'perovich & I. I. Levkoev. (1978) External heavy-atom effects in thiacarbocyanine dyes. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 27:3, pages 501-506.
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G. Eber, S. Schneider & F. Doerr. (1977) On the electronic relaxation processes of carbonyl compounds of azulene in solution. Journal of Photochemistry 7:2, pages 91-99.
Crossref
L.O. Ruzo, G. Sundström, O. Hutzinger & S. Safe. (2010) Heavy‐atom effects in the photoreactions of halogenated aromatic compounds. Recueil des Travaux Chimiques des Pays-Bas 96:10, pages 249-251.
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Willem Siebrand. 1976. Dynamics of Molecular Collisions. Dynamics of Molecular Collisions 249 302 .

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