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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 33, 1977 - Issue 5
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Original Articles

The charge-transfer contribution to the intensity of hypersensitive trivalent lanthanide transitions

Robert D. Peacock Department of Chemistry, King's College, Strand, London, WC2R 2LS
Pages 1239-1246 | Received 17 Jan 1977, Published online: 22 Aug 2006

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Rashid Ilmi & K. Iftikhar. (2012) Luminescent nine-coordinate lanthanide complexes derived from fluorinated β-diketone and 2,4,6-tris(2-pyridyl)-1,3,5-triazine. Journal of Coordination Chemistry 65:3, pages 403-419.
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Mohammad Amin Abubaker, Katharine Harrington & Ray von Wandruszka. (1993) Fluorescence Sensitization of Aqueous Terbium and Europium Ions Without Aromatic Donors or Synergistic Agents. Analytical Letters 26:8, pages 1681-1692.
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MichaelF. Reid & Betty Ng. (1989) Complete second-order calculations of intensity parameters for one-photon and two-photon transitions of rare-earth ions in solids. Molecular Physics 67:2, pages 407-415.
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Lidia Smentek-Mielczarek. (1987) Electron correlation third-order contributions to the electric dipole transition amplitudes of rare earth ions in crystals. Molecular Physics 61:3, pages 767-774.
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Lidia Smentek-Mielczarek. (1985) Crystal field, ligand polarization and electron correlation third order contributions to the f↔f transition probabilities. Molecular Physics 54:4, pages 873-881.
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FrederickS. Richardson, JeffreyD. Saxe, ScottA. Davis & ThomasR. Faulkner. (1981) Intensity calculations on hypersensitive f-f transitions in nine-coordinate lanthanide systems of trigonal symmetry. Molecular Physics 42:6, pages 1401-1429.
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StephenF. Mason. (1979) Ligand-polarization models for the optical activity of chiral cobalt(III) complexes octahedrally-coordinated with monodentate ligands. Molecular Physics 37:3, pages 843-853.
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ThomasR. Faulkner & F.S. Richardson. (1978) Magnetic dipole and vibronically induced electric dipole intensities of the 5D4→7F transitions of Tb3+ in Cs2NaTbCl6 . Molecular Physics 36:1, pages 193-914.
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Articles from other publishers (32)

M.S. Sutrisno, N.N. Yusof, M.N. Azlan, M.H.M. Zaid, S.M. Iskandar & R. Hisam. (2023) Hypersensitivity and nephelauxetic effect of Er3+ in bismuth tellurite glass system. Results in Chemistry 6, pages 101085.
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Thiyam Samrat Singh, Ch. Sumitra & Thiyam David Singh. (2022) Comparative 4f-4f Spectral Analysis of Simultaneous Complexation of Pr(III) with L-Tryptophan in Presence and Absence of Ca2+ and Zn2+ Ions in Aqueous Medium: Energy, Intensity and Kinetic Studies. Asian Journal of Chemistry 34:12, pages 3183-3188.
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Rashid Ilmi, Aabid Bashir Ganaie & K. Iftikhar. (2018) 1H NMR of paramagnetic Lanthanide(III) complexes of trifluoroacetylacetone and 2,2′-Bipyridyl and 4f-4f absorption studies. Journal of Molecular Structure 1173, pages 990-999.
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Rashid Ilmi & K. Iftikhar. (2016) Structure elucidation by sparkle/RM1, effect of lanthanide contraction and photophysical properties of lanthanide(III) trifluoroacetylacetonate complexes with 1,10-phenanthroline. Journal of Photochemistry and Photobiology A: Chemistry 325, pages 68-82.
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Koen Binnemans. (2015) Interpretation of europium(III) spectra. Coordination Chemistry Reviews 295, pages 1-45.
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Lidia Smentek. 2015. Computational Methods in Lanthanide and Actinide Chemistry. Computational Methods in Lanthanide and Actinide Chemistry 241 268 .
Miho Hatanaka & Satoshi Yabushita. (2014) Mechanisms of f–f hypersensitive transition intensities of lanthanide trihalide molecules: a spin–orbit configuration interaction study. Theoretical Chemistry Accounts 133:8.
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Qi Liu, Su-Zhi Ge, Jie-Cen Zhong, Yan-Qiong Sun & Yi-Ping Chen. (2013) Two novel 2D lanthanide–cadmium heterometal–organic frameworks based on nanosized heart-like Ln6Cd6O12 wheel-clusters exhibiting luminescence sensing to the polarization and concentration of cations. Dalton Transactions 42:18, pages 6314.
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Cheng Yan, Kang Li, Shi-Chao Wei, Hai-Ping Wang, Lei Fu, Mei Pan & Cheng-Yong Su. (2012) Lanthanide homometallic and d–f heterometallic MOFs from the same tripodal ligand: structural comparison, one photon (OP) vs. two photon (TP) luminescence and selective guest adsorption behavior. Journal of Materials Chemistry 22:19, pages 9846.
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Miho Hatanaka & Satoshi Yabushita. (2011) An ab initio study on the f-f hypersensitive transition intensities of lanthanide tribromide molecules. Chemical Physics Letters 504:4-6, pages 193-198.
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Miho Hatanaka & Satoshi Yabushita. (2009) Theoretical Study on the f−f Transition Intensities of Lanthanide Trihalide Systems. The Journal of Physical Chemistry A 113:45, pages 12615-12625.
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A.A. Ansari, M. Irfanullah & K. Iftikhar. (2007) Optical absorption and NMR spectroscopic studies on paramagnetic neodymium(III) complexes with β-diketone and heterocyclic amines. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 67:5, pages 1178-1188.
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Brian Wybourne & Lidia Smentek. 2007. Optical Spectroscopy of Lanthanides. Optical Spectroscopy of Lanthanides 217 230 .
Azad A Khan, H.A Hussain & K Iftikhar. (2003) 4f–4f absorption spectra of nine-coordinate Pr (III) and Nd (III) complexes in different environments. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 59:5, pages 1051-1059.
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Lidia Smentek. (1998) Theoretical description of the spectroscopic properties of rare earth ions in crystals. Physics Reports 297:4, pages 155-237.
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Christiane Görller-Walrand & Koen Binnemans. 1998. 101 264 .
G. W. Burdick & M. C. Downer. 1993. Solid State Luminescence. Solid State Luminescence 97 131 .
D J Newman & B Ng. (1989) The superposition model of crystal fields. Reports on Progress in Physics 52:6, pages 699-762.
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Brian Stewart. 1989. Vibronic Processes in Inorganic Chemistry. Vibronic Processes in Inorganic Chemistry 327 345 .
Lidia Smentek-Mielczarek & B. Andes HessJr.Jr.. (1988) Third order a b   i n i t i o calculations of the f ↔ f transition amplitudes for ions across the lanthanide series . The Journal of Chemical Physics 89:2, pages 703-710.
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Shanker Ram. (2005) Electronic Raman and fluorescence spectroscopic studies of Eu 3+ ‐doped A 2 SO 4 · χH 2 O sulphates . Journal of Raman Spectroscopy 18:8, pages 537-548.
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Lidia Smentek-Mielczarek & B. Andes HessJr.Jr.. (1987) Third-order a b   i n i t i o calculations of the intensity parameters for the Pr+3 ion in LaAlO3, NdAlO3, and LaCl3 hosts . The Journal of Chemical Physics 87:6, pages 3509-3512.
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Y M Poon. (1984) Overlap and covalency contributions to lanthanide-ion spectral intensity parameters. Journal of Physics C: Solid State Physics 17:24, pages 4319-4325.
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S Ram, O P Lamba & H D Bist. (1984) Optical transitions of Eu3+ ions in EuCl3 solutions. Pramana 23:1, pages 59-68.
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Michael F. Reid & Frederick S. Richardson. (1983) Anisotropic ligand polarizability contributions to lanthanide 4f → 4f intensity parameters. Chemical Physics Letters 95:6, pages 501-506.
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Paolo Biscarini. (1983) Synthesis and characterisation of chiral lanthanide complexes: Tetraethylammonium tetrakis [(-)cyclic O,O′-1(R),2(R)-dimethylethylene dithiophosphato] lanthanide(III), {(C2H5)4N}{Ln[(-)S2PO2C4H8]4}, (Ln = Nd, Eu). Inorganica Chimica Acta 74, pages 65-75.
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B R Judd. (1980) Vibronic Contributions to Ligand-Induced Pseudo-Quadrupole Absorption of Rare-Earth Ions. Physica Scripta 21:3-4, pages 543-548.
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P. Porcher & P. Caro. (1980) Influence of J-mixing on the phenomenological interpretation of the Eu3+ ion spectroscopic properties. Journal of Luminescence 21:2, pages 207-216.
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Stephen F. Mason. 1980. Electrons and Transitions. Electrons and Transitions 43 81 .
B. R. Judd. (1979) Ionic transitions hypersensitive to environment. The Journal of Chemical Physics 70:11, pages 4830-4833.
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Stephen F. Mason. (2002) The ligand polarization model and the spectra of metal complexes. A complementation of the crystal field. Accounts of Chemical Research 12:2, pages 55-61.
Crossref
S. F. Mason. 1979. Optical Activity and Chiral Discrimination. Optical Activity and Chiral Discrimination 161 187 .

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