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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 33, 1977 - Issue 5
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Original Articles

The role of local fields and interparticle pair correlations in light scattering by dense fluids

IV. Removal of the point-polarizability approximation

Thomas Keyes Department of Chemistry, Yale University, New Haven, Connecticut, 06520, U.S.A.View further author information
&
Branka M. Ladanyi Department of Chemistry, Yale University, New Haven, Connecticut, 06520, U.S.A.
Pages 1271-1285 | Received 28 Jul 1976, Published online: 22 Aug 2006

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A. De Santis & M. Sampoli. (1984) A light scattering study of rotational bands in fluid CO2 . Molecular Physics 53:3, pages 717-729.
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G. Breuer. (1982) Contributions to the time independent theory of Rayleigh scattering in liquids. Molecular Physics 45:2, pages 349-371.
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K.L. Clarke, P.A. Madden & A.D. Buckingham. (1978) Collision-induced polarizabilities of inert gas atoms. Molecular Physics 36:2, pages 301-316.
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BrankaM. Ladanyi & T. Keyes. (1977) Theory of the static Kerr effect in dense fluids. Molecular Physics 34:6, pages 1643-1659.
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Articles from other publishers (45)

F. F. Summa, J. H. Andersen, P. Lazzeretti, S. P. A. Sauer, G. Monaco, S. Coriani & R. Zanasi. (2023) Origin-Independent Dynamic Polarizability Density from Coupled Cluster Response Theory. Journal of Chemical Theory and Computation 19:20, pages 7242-7259.
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Gungor Ozer & Tom Keyes. (2015) Classical Description of the Vibrational Spectroscopy, Structure, and Electrostatics of the Halide Solvation Shell with the POLIR Potential. The Journal of Physical Chemistry B 119:29, pages 9312-9318.
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Francesca Ingrosso & Branka M. Ladanyi. (2013) Intermolecular Structure and Collective Dynamics of Supercritical Fluoroform Studied by Molecular Dynamics Simulations. The Journal of Physical Chemistry B 117:2, pages 654-667.
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A. Mandal & K. L. C. Hunt. (2009) A single molecule as a dielectric medium. The Journal of Chemical Physics 131:23.
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M. Dolores Elola & Branka M. Ladanyi. (2006) Molecular Dynamics Study of Polarizability Anisotropy Relaxation in Aromatic Liquids and Its Connection with Local Structure. The Journal of Physical Chemistry B 110:31, pages 15525-15541.
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M. Dolores Elola & Branka M. Ladanyi. (2005) Polarizability response in polar solvents: Molecular-dynamics simulations of acetonitrile and chloroform. The Journal of Chemical Physics 122:22.
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Olga Spirina Jenkins & Katharine L. C. Hunt. (2003) Nonlocal dielectric functions on the nanoscale: Screened forces from unscreened potentials. The Journal of Chemical Physics 119:16, pages 8250-8256.
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Olga Spirina Jenkins & Katharine L.C. Hunt. (2003) Non-local dielectric functions on the nanoscale: electronic polarization and fluctuations. Journal of Molecular Structure: THEOCHEM 633:2-3, pages 145-155.
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M. H. Champagne, X. Li & K. L. C. Hunt. (2000) Nonadditive three-body polarizabilities of molecules interacting at long range: Theory and numerical results for the inert gases, H2, N2, CO2, and CH4. The Journal of Chemical Physics 112:4, pages 1893-1906.
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X. Li & K. L. C. Hunt. (1997) Nonadditive three-body dipoles of inert gas trimers and H2⋯H2⋯H2: Long-range effects in far infrared absorption and triple vibrational transitions. The Journal of Chemical Physics 107:11, pages 4133-4153.
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X. Li & K. L. C. Hunt. (1996) Nonadditive, three-body dipoles and forces on nuclei: New interrelations and an electrostatic interpretation. The Journal of Chemical Physics 105:10, pages 4076-4093.
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P.-H. Liu & K. L. C. Hunt. (1995) Molecular softness, hypersoftness, infrared absorption, and vibrational Raman scattering: New relations derived from nonlocal polarizability densities. The Journal of Chemical Physics 103:24, pages 10597-10604.
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E. L. Tisko, X. Li & K. L. C. Hunt. (1995) Relation of vibrational hyper-Raman intensities to γ-hyperpolarizability densities. The Journal of Chemical Physics 103:16, pages 6873-6879.
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K. L. C. Hunt. (1995) Vibrational force constants and anharmonicities: Relation to polarizability and hyperpolarizability densities. The Journal of Chemical Physics 103:9, pages 3552-3560.
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P.-H. Liu & K. L. C. Hunt. (1994) Force balance and force relay in molecular interactions: An analysis based on nonlocal polarizability densities. The Journal of Chemical Physics 100:4, pages 2800-2807.
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Ying Q. Liang & K. L. C. Hunt. (1993) Intramolecular screening of intermolecular forces. The Journal of Chemical Physics 98:6, pages 4626-4635.
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R. Nimalakirthi & K. L. C. Hunt. (1993) Nonlocal polarizability density of a model system: A homogeneous electron gas at T =0 . The Journal of Chemical Physics 98:4, pages 3066-3075.
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K. L. C. Hunt & Y. Q. Liang. (1991) Forces on nuclei in interacting molecules: New analytical results obtained with nonlocal polarizability densities. The Journal of Chemical Physics 95:4, pages 2549-2559.
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Katharine L. C. Hunt & Robert A. Harris. (1991) Vibrational circular dichroism and electric-field shielding tensors: A new physical interpretation based on nonlocal susceptibility densities. The Journal of Chemical Physics 94:11, pages 6995-7002.
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Shi-aki Hyodo. (1991) Fluctuation of Local Field and Depolarization Ratio of the ν 1 Raman Line of Carbon Tetrachloride in Carbon Disulfide Solution . Bulletin of the Chemical Society of Japan 64:2, pages 498-504.
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Lynn C. Geiger, Branka M. Ladanyi & Mark E. Chapin. (1990) A comparison of models for depolarized light scattering in supercritical CO2. The Journal of Chemical Physics 93:7, pages 4533-4542.
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K. L. C. Hunt. (1990) Dispersion dipoles and dispersion forces: Proof of Feynman’s ‘‘conjecture’’ and generalization to interacting molecules of arbitrary symmetry. The Journal of Chemical Physics 92:2, pages 1180-1187.
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K. L. C. Hunt, Y. Q. Liang, R. Nimalakirthi & R. A. Harris. (1989) Changes in electronic polarizability densities due to shifts in nuclear positions, and a new interpretation for integrated intensities of vibrational Raman bands. The Journal of Chemical Physics 91:9, pages 5251-5254.
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Romana Frattini, Marco Sampoli & Renzo Vallauri. (1989) Collision induced contributions on Rayleigh and Raman allowed spectra from fluids composed of linear molecules : A comparison between experimental and computer simulation results.. Journal of Molecular Liquids 43, pages 293-313.
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K. L. C. Hunt. (1989) Relationships between electric field shielding tensors and infrared or Raman intensities: An explanation based on nonlocal polarizability densities. The Journal of Chemical Physics 90:9, pages 4909-4915.
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Aleksandra Borysow & Lothar Frommhold. 1989. Advances in Chemical Physics. Advances in Chemical Physics 439 505 .
A. de Santis, R Frattini, M Sampoli & R Vallauri. (1986) Raman Scattering from CO 2 : A Computer Simulation Investigation of the Effects of Polarizability and Potential Models . Europhysics Letters (EPL) 2:1, pages 17-22.
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Alessandra De Lorenzi, Alberto De Santis, Romana Frattini & Marco Sampoli. (1986) Induced contributions in the Rayleigh band of gaseous S . Physical Review A 33:6, pages 3900-3912.
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A. De Santis & M. Sampoli. 1985. Phenomena Induced by Intermolecular Interactions. Phenomena Induced by Intermolecular Interactions 627 642 .
Renzo Vallauri. 1985. Phenomena Induced by Intermolecular Interactions. Phenomena Induced by Intermolecular Interactions 457 474 .
Katharine L. C. Hunt. 1985. Phenomena Induced by Intermolecular Interactions. Phenomena Induced by Intermolecular Interactions 1 28 .
C. S. Murthy, R. Vallauri, H. Versmold, U. Zimmermann & K. Singer. (2010) Depolarized Rayleigh Scattering from CO 2 : An Experimental and Molecular Dynamics Investigation . Berichte der Bunsengesellschaft für physikalische Chemie 89:1, pages 18-20.
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Branka M. Ladanyi & Nancy E. Levinger. (1984) Computer simulation of Raman scattering from molecular fluids. The Journal of Chemical Physics 81:6, pages 2620-2633.
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A De Santis & M Sampoli. (1984) Induced interactions on the depolarized rayleigh bands of fluid CO2. Physics Letters A 101:3, pages 131-133.
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K. L. C. Hunt. (1984) Nonlocal polarizability densities and the effects of short-range interactions on molecular dipoles, quadrupoles, and polarizabilities. The Journal of Chemical Physics 80:1, pages 393-407.
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P. A. Madden. 1984. Molecular Liquids. Molecular Liquids 431 474 .
Thomas Keyes & Branka M. Ladanyi. 1984. Advances in Chemical Physics. Advances in Chemical Physics 411 465 .
K. L. C. Hunt. (1983) Nonlocal polarizability densities and van der Waals interactions. The Journal of Chemical Physics 78:10, pages 6149-6155.
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Branka M. Ladanyi. (1983) Molecular dynamics study of Rayleigh light scattering from molecular fluids. The Journal of Chemical Physics 78:5, pages 2189-2203.
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Branka M. Ladanyi. (1982) Light scattering from dilute solutions of flexible molecules: A molecular theory of the solute–solvent interactions. The Journal of Chemical Physics 76:9, pages 4303-4310.
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Walter Danninger & Georg Zundel. (1981) Intense depolarized Rayleigh scattering in Raman spectra of acids caused by large proton polarizabilities of hydrogen bonds. The Journal of Chemical Physics 74:5, pages 2769-2777.
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T. Keyes. (1981) Light scattering from nonequilibrium steady states. Physical Review A 23:1, pages 277-284.
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A. K. Burnham & T. D. Gierke. (1980) A comparison of effective polarizabilities from electro-optical experiments using microscopic and macroscopic theories of the local electric field. The Journal of Chemical Physics 73:10, pages 4822-4831.
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T. Keyes, Branka M. Ladanyi & Paul A. Madden. (1979) Is depolarized light scattered from simple liquids mainly double-scattered?. Chemical Physics Letters 64:3, pages 479-484.
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Branka M. Ladanyi & T. Keyes. (1978) The intensity of light scattered by liquid CS2 . The Journal of Chemical Physics 68:7, pages 3217-3221.
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