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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 33, 1977 - Issue 5
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Original Articles

Neutron inelastic scattering study of exchange interactions in a chromium(III) dimer: μ-hydroxo-bis[pentaamminechromium-(III)] chloride monohydrate

H.U. Güdel Institut für Anorganische Chemie, Universität Bern, Freiestrasse 3, CH-3000, Bern, 9, Switzerland
&
A. Furrer Institut für Reaktortechnik, Eidgenössische Technische Hochschule, CH-5303, Würenlingen, Switzerland
Pages 1335-1344 | Received 04 Jan 1977, Published online: 22 Aug 2006

Citations (44)

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Read on this site (2)

HansU. Güdel. (1996) Magnetic excitations in transition metal and rare earth metal dimers. Neutron News 7:3, pages 24-28.
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G.F. Kventsel & J. Katriel. (1978) On the temperature dependence of the singlet-triplet energy gap in dimers. Molecular Physics 36:4, pages 1249-1253.
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Articles from other publishers (42)

Shadan Ghassemi Tabrizi. (2021) Symmetry-induced universal momentum-transfer dependencies for inelastic neutron scattering on anisotropic spin clusters. Physical Review B 104:1.
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Shadan Ghassemi Tabrizi. (2021) Point-group selection rules and universal momentum-transfer dependencies for inelastic neutron scattering on molecular spin clusters. Physical Review B 103:21.
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Jürgen Schnack & Coen de Graaf. 2017. Molecular Magnetic Materials. Molecular Magnetic Materials 447 471 .
Michael L. Baker, Takuya Tanaka, Rina Murakami, Seiko Ohira-Kawamura, Kenji Nakajima, Takayuki Ishida & Hiroyuki Nojiri. (2015) Relationship between Torsion and Anisotropic Exchange Coupling in a Tb III -Radical-Based Single-Molecule Magnet . Inorganic Chemistry 54:12, pages 5732-5738.
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Mariano Spivak, Celestino Angeli, Carmen J. Calzado & Coen de Graaf. (2014) Improving the calculation of magnetic coupling constants in MRPT methods. Journal of Computational Chemistry 35:23, pages 1665-1671.
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Michael L. Baker, Stephen J. Blundell, Neus Domingo & Stephen Hill. 2015. Molecular Nanomagnets and Related Phenomena. Molecular Nanomagnets and Related Phenomena 231 291 .
D. T. Adroja, A. D. Hillier, Y. Muro, J. Kajino, T. Takabatake, P. Peratheepan, A. M. Strydom, P. P. Deen, F. Demmel, J. R. Stewart, J. W. Taylor, R. I. Smith, S. Ramos & M. A. Adams. (2013) Competing -electron dynamics in Ce(Ru Fe ) Al ( ): Magnetic ordering emerging from the Kondo semiconducting state . Physical Review B 87:22.
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M.L. Baker & H. Mutka. (2012) Neutron spectroscopy of molecular nanomagnets. The European Physical Journal Special Topics 213:1, pages 53-68.
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G. Chaboussant. (2010) Diffusion inélastique des neutrons sur les aimants moléculaires. Diffusion inélastique des neutrons sur les aimants moléculaires.
Chengbao Ni, Gary J. Long, Fernande Grandjean & Philip P. Power. (2009) Synthesis, Characterization, and Magnetism of Divalent Aryl Transition-Metal Complexes of the Simplest Dialkylamide, NMe 2 : Rare T-Shaped Coordination at Chromium . Inorganic Chemistry 48:24, pages 11594-11600.
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Reto Basler, Colette Boskovic, Grégory Chaboussant, Hans U. Güdel, Mark Murrie, Stefan T. Ochsenbein & Andreas Sieber. (2003) Molecular Spin Clusters: New Synthetic Approaches and Neutron Scattering Studies. ChemPhysChem 4:9, pages 910-926.
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Reto Basler, Grégory Chaboussant, Andreas Sieber, Hanspeter Andres, Mark Murrie, Paul Kögerler, Hartmut Bögge, Debbie C. Crans, Erich Krickemeyer, Stefan Janssen, Hannu Mutka, Achim Müller & Hans-Ulrich Güdel. (2002) Inelastic Neutron Scattering on Three Mixed-Valence Dodecanuclear Polyoxovanadate Clusters † . Inorganic Chemistry 41:22, pages 5675-5685.
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Ralph Schenker, Stephan Heer, Hans U. Güdel & Høgni Weihe. (2001) Optical Dimer Excitations and Exchange Parameters in (Et 4 N) 3 Cr 2 F 9 : First Observation of the 4 A 2 → 2 A 1 Transition . Inorganic Chemistry 40:7, pages 1482-1488.
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Y. Shapira, M. T. Liu, S. Foner, R. J. Howard & W. H. Armstrong. (2001) Magnetization steps in the model magnetic dimer . Physical Review B 63:9.
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J. J. Borrás-Almenar, J. M. Clemente-Juan, E. Coronado & B. S. Tsukerblat. (1999) High-Nuclearity Magnetic Clusters: Generalized Spin Hamiltonian and Its Use for the Calculation of the Energy Levels, Bulk Magnetic Properties, and Inelastic Neutron Scattering Spectra. Inorganic Chemistry 38:26, pages 6081-6088.
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Hanspeter Andres, Juan M. Clemente-Juan, Michael Aebersold, Hans U. Güdel, Eugenio Coronado, Herma Büttner, Gordon Kearly, Julio Melero & Ramón Burriel. (1999) Magnetic Excitations in Polyoxometalate Clusters Observed by Inelastic Neutron Scattering:  Evidence for Anisotropic Ferromagnetic Exchange Interactions in the Tetrameric Cobalt(II) Cluster [Co 4 (H 2 O) 2 (PW 9 O 34 ) 2 ] 10- . Comparison with the Magnetic and Specific Heat Properties . Journal of the American Chemical Society 121:43, pages 10028-10034.
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Juan M. Clemente-Juan, Hanspeter Andres, Juan J. Borrás-Almenar, Eugenio Coronado, Hans U. Güdel, Michael Aebersold, Gordon Kearly, Herma Büttner & Markus Zolliker. (1999) Magnetic Excitations in Polyoxometalate Clusters Observed by Inelastic Neutron Scattering:  Evidence for Ferromagnetic Exchange Interactions and Spin Anisotropy in the Tetrameric Nickel(II) Cluster [Ni 4 (H 2 O) 2 (PW 9 O 34 ) 2 ] 10 - and Comparison with the Magnetic Properties . Journal of the American Chemical Society 121:43, pages 10021-10027.
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Juan M. Clemente-Juan & Eugenio Coronado. (1999) Magnetic clusters from polyoxometalate complexes. Coordination Chemistry Reviews 193-195, pages 361-394.
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Y. Shapira, M. T. Liu, S. Foner, C. E. Dubé & P. J. Bonitatebus. (1999) Magnetization steps in . Physical Review B 59:2, pages 1046-1054.
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Hanspeter Andres, Michael Aebersold, Hans U. Güdel, Juan M. Clemente, Eugenio Coronado, Herma Büttner, Gordon Kearly & Markus Zolliker. (1998) Anisotropic exchange coupling in the Keggin derivative K8[Co2(D2O)(W11O39)] · n D2O. Chemical Physics Letters 289:3-4, pages 224-230.
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J.J. Borrás-Almenar, J.M. Clemente, E. Coronado & B.S. Tsukerblat. (1997) A general approach for the calculation of the energy levels and the inelastic neutron scattering cross-section of highly nuclear magnetic clusters. Physica B: Condensed Matter 234-236, pages 746-748.
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C. E. AnsonJ. P. BourkeR. D. CannonU. A. JayasooriyaM. MolinierA. K. Powell. (1997) Crystal Structures of the Isomorphous Prototypic Oxo-Centered Trinuclear Complexes [Cr 3 O(OOCCH 3 ) 6 (H 2 O) 3 ]Cl·6H 2 O and [Fe 3 O(OOCCH 3 ) 6 (H 2 O) 3 ]Cl·6H 2 O . Inorganic Chemistry 36:6, pages 1265-1267.
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J. M. Clemente, A. V. Palii, B. S. Tsukerblat & R. Georges. 1996. Molecular Magnetism: From Molecular Assemblies to the Devices. Molecular Magnetism: From Molecular Assemblies to the Devices 85 104 .
N. Fanjat, M. Barj, B. Briat, O. Schaerpf & G. Lucazeau. (1993) Study of inelastic magnetic excitations in Na3Cr2(PO4)3 by neutron scattering. Journal of Physics and Chemistry of Solids 54:11, pages 1515-1526.
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C.J. Gómez-García, E. Coronado, J.J. Borrás-Almenar, M. Aebersold, H.U. Güdel & H. Mutka. (1992) Magnetic excitations in an exchange-coupled tetramer cluster of cobalt (II): a study by inelastic neutron scattering. Physica B: Condensed Matter 180-181, pages 238-240.
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S.K. Hoffmann, A. Waśkowska & W. Hilczer. (1990) Thermal expansion and interdimer exchange coupling in [Co(ethylenediamine)3]2[Cu2Cl8]Cl2 ∗ 2H2O single crystals. Solid State Communications 74:12, pages 1359-1361.
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T. M. Giebultowicz, P. Klosowski, J. J. Rhyne, T. J. Udovic, J. K. Furdyna & W. Giriat. (1990) Magnetic exchange interactions in Co-based II-VI diluted magnetic semiconductors: S . Physical Review B 41:1, pages 504-513.
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R.P. White, J.O. Al-Basseet, R.D. Cannon, G.J. Kearley & U.A. Jayasooriya. (1989) Temperature dependent magnetic exchange interactions in a mixed-valence complex: A neutron scattering study. Physica B: Condensed Matter 156-157, pages 367-369.
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A. V. Palii, M. I. Belinskii, V. E. Fainzil'berg & B. S. Tsukerblat. (1989) Inelastic scattering of unpolarized neutrons on dimer clusters. Theoretical and Experimental Chemistry 24:4, pages 382-387.
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Johan Springborg. 1988. 55 169 .
Roderick D. Cannon & Ross P. White. 1988. Progress in Inorganic Chemistry. Progress in Inorganic Chemistry 195 298 .
H. Astheimer, H. Weitzel & W. Haase. (1985) Inelastic neutron scattering on the tetrameric alkoxo-bridged copper(II) complex [CuCl (OCD2CD2N(C2D5)2)]4. The Journal of Chemical Physics 83:3, pages 1234-1236.
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Hans U. Güdel. 1984. Magneto-Structural Correlations in Exchange Coupled Systems. Magneto-Structural Correlations in Exchange Coupled Systems 329 354 .
S.K. Hoffmanne. (1983) Temperature dependence of a superexchange interaction determined from merging effect of copper(II) EPR lines. Chemical Physics Letters 98:4, pages 329-332.
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J. Darriet, J.L. Soubeyroux & A.P. Murani. (1983) Neutron inelastic scattering study of exchange interactions in a ruthenium V dimer a3CaRu2O9. Journal of Physics and Chemistry of Solids 44:3, pages 269-272.
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Raymond P. Scaringe, Derek J. Hodgson & William E. Hatfield. (2013) Exchange coupling in di-μ-hydroxo-bridged chromium(III) dimers. Transition Metal Chemistry 6:6, pages 340-344.
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Hans U. Güdel, Albert Furrer, Willi Bührer & Beat Hälg. (1981) Exchange interactions in clusters of paramagnetic transition metal ions; inelastic neutron scattering studies. Surface Science 106:1-3, pages 432-437.
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W. Bührer, R. Bührer, A. Isacson, M. Koch & R. Thut. (1981) Monochromator- and analyser-crystal with variable curvature for triple-axis spectrometers. Nuclear Instruments and Methods 179:2, pages 259-263.
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Hans U. Güdel & Urs Hauser. (1980) Magnetochemical properties of tetranuclear rhodoso and Pfeiffer chromium(III) complexes in a series of compounds. Journal of Solid State Chemistry 35:2, pages 230-239.
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H U Gudel, A Stebler & A Furrer. (1980) Inelastic neutron scattering from single crystals of dimeric copper acetate. Journal of Physics C: Solid State Physics 13:20, pages 3817-3822.
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Albert Furrer & Hans U. Güdel. (1979) Neutron inelastic scattering from isolated clusters of magnetic ions. Journal of Magnetism and Magnetic Materials 14:2-3, pages 256-264.
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A. Furrer & H. U. Güdel. (1977) Interference Effects in Neutron Scattering from Magnetic Clusters. Physical Review Letters 39:10, pages 657-660.
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