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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 34, 1977 - Issue 4
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Original Articles

4Ag↔2Eg Transition of Mn4+ in Cs2TiF6: MnF62-

N.B. Manson Department of Solid State Physics, Research School of Physical Sciences, Australian National University, Canberra, A.C.T., 2600, Australia
,
G.A. Shah Department of Solid State Physics, Research School of Physical Sciences, Australian National University, Canberra, A.C.T., 2600, Australia; Department of Vascular Surgery, Woden Valley Hospital, Yamba Drive, Garran, A.C.T., Australia, 2605
,
B. Howes Department of Solid State Physics, Research School of Physical Sciences, Australian National University, Canberra, A.C.T., 2600, Australia
&
C.D. Flint Department of Chemistry, Birkbeck College, University of London, London, WC1E 7HY, England
Pages 1157-1174 | Received 04 Mar 1977, Published online: 22 Aug 2006

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R. Acevedo, S.O. Vasquez & C.D. Flint. (1991) Vibronic intensities in the electronic spectra of transition metal complex ions. Part IX. Experimental study of the relative vibronic intensities in the 2Eg → 4A2g transition of the MnF2- 6 ion in Cs2SiF6 . Molecular Physics 74:4, pages 843-851.
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R. Acevedo & C.D. Flint. (1983) Vibronic intensities in the electronic spectra of transition metal ions. Molecular Physics 49:5, pages 1065-1076.
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Articles from other publishers (25)

Zien Cheng, Guangxiang Lu, Yuxuan Qi, Jinmei Huang, Gonggui Yan, Leiming Fang, Maxim Avdeev, Tao Yang & Pengfei Jiang. (2024) Structure and photoluminescence of Mn 2+/4+ -activated doubly ordered spinel Mg 4 (Ga/Al)SbO 8 : site-selective Al 3+ -to-Ga 3+ substitution enabling Mn 4+ accumulation, excellent anti-thermal quenching of Mn 2+ green emission, and optical thermometry . Inorganic Chemistry Frontiers 11:6, pages 1923-1936.
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Debao Zhang, Wanggui Ye, Xuguang Cao, Ji Zhou, Fei Tang, Changcheng Zheng, Jiqiang Ning & Shijie Xu. (2024) High-excited-state splitting and multimode vibrational coupling in Mn4+-activated fluoride phosphor. Science China Physics, Mechanics & Astronomy 67:3.
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Jiayue Wu, Ziqing Yin, Shikao Shi & Lianshe Fu. (2023) An Al 3+ -incorporated Ca 2 LuNbO 6 :Mn 4+ oxide phosphor with dramatic deep-red and far-red emission bands . Journal of Materials Chemistry C 11:44, pages 15731-15741.
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Jinmei Huang, Pengfei Jiang, Zien Cheng, Rong Wang, Rihong Cong & Tao Yang. (2023) Structural confinement-induced highly efficient deep-red emission and negative thermal quenching performance in Mn 4+ -activated Ca 7 Mg 2 Ga 6− y Al y O 18 :Mn 4+ phosphors . Inorganic Chemistry Frontiers 10:9, pages 2776-2787.
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Jinmei Huang, Pengfei Jiang, Zien Cheng, Jie Qin, Rihong Cong & Tao Yang. (2023) Equivalent chemical substitution in double–double perovskite-type ALaLiTeO 6 :Mn 4+ (A = Ba 2+ , Sr 2+ , Ca 2+ ) phosphors enabling wide range crystal field strength regulation and efficient far-red emission . Dalton Transactions 52:11, pages 3458-3471.
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Shirun Yan. (2021) Comment on “Investigation on Anomalous Thermal Quenching of Mn4 + Luminescence in A2XF6:Mn4+” [ ECS J. Solid State Sci. Technol., 10, 076007 (2021)]. ECS Journal of Solid State Science and Technology 10:12, pages 120001.
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Zhiguo Zhang, Hua Huo, Liguang Wang, Shuaifeng Lou, Lizhi Xiang, Bingxing Xie, Qun Wang, Chunyu Du, Jiajun Wang & Geping Yin. (2021) Stacking fault disorder induced by Mn doping in Ni(OH)2 for supercapacitor electrodes. Chemical Engineering Journal 412, pages 128617.
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Peiqing Cai, Song Wang, Tianmou Xu, Ying Tang, Xiaolin Yuan, Mingjie Wan, Qi Ai, Junjie Si, Xin Yao, Yonggang Cao, Maxim K. Rabchinskii, Pavel N. Brunkov & Zugang Liu. (2020) Mn4+ doped zero-dimensional organic-inorganic hybrid material with narrow-red emission. Journal of Luminescence 228, pages 117661.
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Decai Huang, Haomiao Zhu, Zhonghua Deng, Qilin Zou, Hongyu Lu, Xiaodong Yi, Wang Guo, Canzhong Lu & Xueyuan Chen. (2019) Moisture‐Resistant Mn 4+ ‐Doped Core–Shell‐Structured Fluoride Red Phosphor Exhibiting High Luminous Efficacy for Warm White Light‐Emitting Diodes . Angewandte Chemie International Edition 58:12, pages 3843-3847.
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Decai Huang, Haomiao Zhu, Zhonghua Deng, Qilin Zou, Hongyu Lu, Xiaodong Yi, Wang Guo, Canzhong Lu & Xueyuan Chen. (2019) Moisture‐Resistant Mn 4+ ‐Doped Core–Shell‐Structured Fluoride Red Phosphor Exhibiting High Luminous Efficacy for Warm White Light‐Emitting Diodes . Angewandte Chemie 131:12, pages 3883-3887.
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Chunyan Jiang, Mingying Peng, Alok M. Srivastava, Lihua Li & Mikhail G. Brik. (2018) Mn 4+ -Doped Heterodialkaline Fluorogermanate Red Phosphor with High Quantum Yield and Spectral Luminous Efficacy for Warm-White-Light-Emitting Device Application . Inorganic Chemistry 57:23, pages 14705-14714.
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Peiqing Cai, Lin Qin, Cuili Chen, Jing Wang, Shala Bi, Sun Il Kim, Yanlin Huang & Hyo Jin Seo. (2018) Optical Thermometry Based on Vibration Sidebands in Y 2 MgTiO 6 :Mn 4+ Double Perovskite . Inorganic Chemistry 57:6, pages 3073-3081.
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Peiqing Cai, Xiangfu Wang & Hyo Jin Seo. (2018) Excitation power dependent optical temperature behaviors in Mn 4+ doped oxyfluoride Na 2 WO 2 F 4 . Physical Chemistry Chemical Physics 20:3, pages 2028-2035.
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Tadeusz Lesniewski, Sebastian Mahlik, Marek Grinberg & Ru-Shi Liu. (2017) Temperature effect on the emission spectra of narrow band Mn 4+ phosphors for application in LEDs . Physical Chemistry Chemical Physics 19:48, pages 32505-32513.
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Thomas F. Hughes & Richard A. Friesner. (2010) Correcting Systematic Errors in DFT Spin-Splitting Energetics for Transition Metal Complexes. Journal of Chemical Theory and Computation 7:1, pages 19-32.
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Sadao Adachi, Hiroki Abe, Ryota Kasa & Takahiro Arai. (2011) Synthesis and Properties of Hetero-Dialkaline Hexafluorosilicate Red Phosphor KNaSiF 6 :Mn 4+ . Journal of The Electrochemical Society 159:2, pages J34-J37.
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Yan Kai Xu & Sadao Adachi. (2011) Properties of Mn[sup 4+]-Activated Hexafluorotitanate Phosphors. Journal of The Electrochemical Society 158:3, pages J58.
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Christian Aagaard Thuesen, Anne-Laure Barra & Jørgen Glerup. (2009) Single Crystal Electron Paramagnetic Resonance Spectra of Cs 2 MnF 6 and K 2 MnF 6 Diluted in the Isomorphous Germanium Salts . Inorganic Chemistry 48:7, pages 3198-3204.
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Clyde Arthur MorrisonClyde Arthur Morrison. 1992. Crystal Fields for Transition-Metal Ions in Laser Host Materials. Crystal Fields for Transition-Metal Ions in Laser Host Materials 36 38 .
Z Hasan & N B Manson. (1980) Jahn-Teller effect in the 4 T 2g state of Mn 4+ trigonal Cs 2 TiF 6 . Journal of Physics C: Solid State Physics 13:12, pages 2325-2329.
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Maria Cieślak-Golonka, Adam Bartecki & Shyama P. Sinha. (1980) Vibrational fine structure in the electronic spectra of transition metal compounds. an experimental survey. Coordination Chemistry Reviews 31:3, pages 251-288.
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Rainer Wernicke & Hans-Herbert Schmidtke. (1980) Low symmetry splittings due to phase transitions in the vibronic spectrum of ReCl62− and ReBr62− doped in K2PtCl6-type crystals. The Journal of Chemical Physics 72:3, pages 1938-1944.
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H. H. Patterson & J. W. Lynn. (1979) Lattice-dynamics study of Si with application to the vibronic optical spectra of Mn in Si . Physical Review B 19:2, pages 1213-1224.
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N B Manson & G Ali Shah. (1978) Splitting of vibronic levels in Cs 2 SiF 6 :Mn 4+ . Journal of Physics C: Solid State Physics 11:11, pages 2229-2238.
Crossref
A.M Black & C.D Flint. (1978) Splitting of the ground state in Cs2ReF6. Journal of Molecular Spectroscopy 70:3, pages 481-483.
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