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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 45, 1982 - Issue 5
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Original Articles

Methyl group rotation in 2,4-hexadiyne

II. The transition from classical to quantum dynamics

J.R. Cockbain Physical Chemistry Laboratory, South Parks Road, Oxford, England
,
R. Lechner Physical Chemistry Laboratory, South Parks Road, Oxford, England; Hahn-Meitner Institut, West Berlin, Germany
,
M. Owen Physical Chemistry Laboratory, South Parks Road, Oxford, England
,
R.K. Thomas Physical Chemistry Laboratory, South Parks Road, Oxford, England
&
J.W. White Physical Chemistry Laboratory, South Parks Road, Oxford, England
Pages 1035-1051 | Received 30 Jun 1981, Accepted 02 Oct 1981, Published online: 22 Aug 2006

Citations (13)

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Read on this site (2)

Giorgio Moro & Pier Luigi Nordio. (1985) Diffusive and jump description of hindered motions. Molecular Physics 56:2, pages 255-269.
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Barbara Gabryś. (1984) Coupled relaxation of tunnelling methyl groups. Molecular Physics 51:3, pages 601-615.
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Articles from other publishers (11)

Juan Colmenero, Angel J. Moreno & Angel Alegría. (2005) Neutron scattering investigations on methyl group dynamics in polymers. Progress in Polymer Science 30:12, pages 1147-1184.
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A. J. Moreno, A. Alegría, J. Colmenero & B. Frick. (2001) Methyl Group Dynamics in Poly(methyl methacrylate):  From Quantum Tunneling to Classical Hopping. Macromolecules 34:14, pages 4886-4896.
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M. Prager & A. Heidemann. (1997) Rotational Tunneling and Neutron Spectroscopy:  A Compilation. Chemical Reviews 97:8, pages 2933-2966.
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Alois W�rger. (1991) High-temperature quantum effects in methyl rotation. Zeitschrift f�r Physik B Condensed Matter 84:2, pages 263-267.
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Colin Carlile, Ian McL. Jamie, John W. White, Michael J. Prager & William Stead. (1991) Rotational tunnelling of ammonia in two-dimensional metal–ammonia solutions. J. Chem. Soc., Faraday Trans. 87:1, pages 73-81.
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Alfred H�ller. (1990) Rotational tunnelling at finite temperatures: Substitution by an equivalent harmonic system. Zeitschrift f�r Physik B Condensed Matter 78:1, pages 125-129.
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A Wurger. (1989) The temperature dependence of inelastic rotational tunnelling transitions. Journal of Physics: Condensed Matter 1:38, pages 6901-6905.
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A. Heidemann, M. Prager & M. Monkenbusch. (1989) Methyl rotation in acetamide: the transition from quantum mechanical tunneling to classical reorientation studied by inelastic neutron scattering. Zeitschrift f�r Physik B Condensed Matter 76:1, pages 77-88.
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J. le G. Gilchrist. (1985) Anomalous temperature dependence of a dielectric relaxation rate. Chemical Physics Letters 121:6, pages 540-542.
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Giorgio Moro. (1985) Spectral densities from asymptotic solutions of the Fokker-Planck equation. Chemical Physics 96:2, pages 287-297.
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Barbara Gabryś, Julia S. Higgins & David A. Young. (1985) Rotation of methyl groups in molecular solids and polymers at low temperatures: recent developments. Polymer 26:3, pages 355-363.
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