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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 20
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Original Articles

Catalytic Transfer Hydrogenation of Aromatic Nitro Compounds by Employing Ammonium Formate and 5% Platinum on Carbon

D. Channe Gowda Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore, 570 006, India
&
B. Mahesh Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore, 570 006, India
Pages 3639-3644 | Received 01 Jun 1999, Published online: 04 Dec 2007

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Ehab Abdel-Latif, Heba M. Metwally, Eman M. Keshk, Abdel-Galil M. Khalil & Ali Saeed. (2019) An overview on the synthesis and chemical properties ofp-aminoacetanilide and its derivatives. Synthetic Communications 49:16, pages 1957-1986.
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Suresh Iyer & Girish M. Kulkarni. (2004) Mo(CO)6 Mediated Selective Reduction of Azides and Nitro Compounds to Amines Under Neutral Conditions. Synthetic Communications 34:4, pages 721-725.
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Shankare Gowda, B. K. Kempe Gowda & D. Channe Gowda. (2003) Hydrazinium Monoformate: A New Hydrogen Donor. Selective Reduction of Nitrocompounds Catalyzed by Commercial Zinc Dust. Synthetic Communications 33:2, pages 281-289.
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K. Abiraj, Shankare Gowda & D. Channe Gowda. (2002) MAGNESIUM/HYDRAZINIUM MONOFORMATE: A NEW HYDROGENATION SYSTEM FOR THE SELECTIVE REDUCTION OF NITRO COMPOUNDS. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 32:8, pages 1409-1417.
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Mahdi Shahmiri, Saadi Bayat & Sharmin Kharrazi. (2023) Catalytic performance of PVP-coated CuO nanosheets under environmentally friendly conditions. RSC Advances 13:19, pages 13213-13223.
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Gurmeet Singh, Jyoti Gahtori, Mukesh Kumar Poddar, Chanchal Samanta, Sumantra Bhattacharya, Ankush V. Biradar & Ankur Bordoloi. (2022) Studies on Synthesis of Sub‐Nanometre Size Pt Particles Stabilized on ZrO 2 Matrix for Formic Acid Mediated Synthesis of γ‐Valerolactone . ChemistrySelect 7:20.
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Hongbin Shi, Xiaofeng Dai, Qing Liu, Teng Zhang, Yabing Zhang, Yuling Shi & Tao Wang. (2021) Magnetic CuNi Alloy Nanoparticles for Catalytic Transfer Hydrogenation of Nitroarene. Industrial & Engineering Chemistry Research 60:44, pages 16011-16022.
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Renfeng Nie, Yuewen Tao, Yunqing Nie, Tianliang Lu, Jianshe Wang, Yongsheng Zhang, Xiuyang Lu & Chunbao Charles Xu. (2021) Recent Advances in Catalytic Transfer Hydrogenation with Formic Acid over Heterogeneous Transition Metal Catalysts. ACS Catalysis 11:3, pages 1071-1095.
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Angel H. Romero. (2020) Reduction of Nitroarenes via Catalytic Transfer Hydrogenation Using Formic Acid as Hydrogen Source: A Comprehensive Review. ChemistrySelect 5:42, pages 13054-13075.
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Richard C. LarockRichard C. Larock & Alexandre A. Pletnev. 2018. Comprehensive Organic Transformations. Comprehensive Organic Transformations 1 11 .
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Anthony O. King, Ichiro Shinkai, K. Abiraj, D. Channe Gowda & Jitendra D. Belani. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis 1 12 .
S. Letort, M. Lejeune, N. Kardos, E. Métay, F. Popowycz, M. Lemaire & M. Draye. (2017) New insights into the catalytic reduction of aliphatic nitro compounds with hypophosphites under ultrasonic irradiation. Green Chemistry 19:19, pages 4583-4590.
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Matthew J. Gilkey & Bingjun Xu. (2016) Heterogeneous Catalytic Transfer Hydrogenation as an Effective Pathway in Biomass Upgrading. ACS Catalysis 6:3, pages 1420-1436.
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Thomas Nesakumar Jebakumar Immanuel Edison, Mathur Gopalakrishnan Sethuraman & Yong Rok Lee. (2015) NaBH4 reduction of ortho and para-nitroaniline catalyzed by silver nanoparticles synthesized using Tamarindus indica seed coat extract. Research on Chemical Intermediates 42:2, pages 713-724.
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Önder Metin, Adriana Mendoza-Garcia, Diğdem Dalmızrak, Mehmet Serdar Gültekin & Shouheng Sun. (2016) FePd alloy nanoparticles assembled on reduced graphene oxide as a catalyst for selective transfer hydrogenation of nitroarenes to anilines using ammonia borane as a hydrogen source. Catalysis Science & Technology 6:15, pages 6137-6143.
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Dandu Damodara, Racha Arundhathi, T. Venkata Ramesh Babu, Margaret K. Legan, Hephzibah J. Kumpaty & Pravin R. Likhar. (2014) Polymethylhydrosiloxane derived palladium nanoparticles for chemo- and regioselective hydrogenation of aliphatic and aromatic nitro compounds in water. RSC Adv. 4:43, pages 22567-22574.
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Rahat Javaid, Shin-ichiro Kawasaki, Akira Suzuki & Toshishige M Suzuki. (2013) Simple and rapid hydrogenation of p -nitrophenol with aqueous formic acid in catalytic flow reactors . Beilstein Journal of Organic Chemistry 9, pages 1156-1163.
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Saravanan Mohanarangam, Bollikonda Satyanarayana, Chandrashekar R. Elati, Bolugoddu Vijayabhaskar & Padi Pratap Reddy. (2011) A Novel and Efficient Synthesis of Dronedarone Hydrochloride, an Antiarrhythmic Drug Substance. Journal of the Chinese Chemical Society 58:7, pages 841-845.
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Saeid Farhadi & Firouzeh Siadatnasab. (2011) Perovskite-type LaFeO3 nanoparticles prepared by thermal decomposition of the La[Fe(CN)6]·5H2O complex: A new reusable catalyst for rapid and efficient reduction of aromatic nitro compounds to arylamines with propan-2-ol under microwave irradiation. Journal of Molecular Catalysis A: Chemical 339:1-2, pages 108-116.
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Saeid Farhadi, Maryam Kazem & Firouzeh Siadatnasab. (2011) NiO nanoparticles prepared via thermal decomposition of the bis(dimethylglyoximato)nickel(II) complex: A novel reusable heterogeneous catalyst for fast and efficient microwave-assisted reduction of nitroarenes with ethanol. Polyhedron 30:4, pages 606-613.
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A. Ufer, D. Sudhoff, A. Mescher & D.W. Agar. (2011) Suspension catalysis in a liquid–liquid capillary microreactor. Chemical Engineering Journal 167:2-3, pages 468-474.
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Xia‐Bing Lou, Lin He, Yue Qian, Yong‐Mei Liu, Yong Cao & Kang‐Nian Fan. (2011) Highly Chemo‐ and Regioselective Transfer Reduction of Aromatic Nitro Compounds using Ammonium Formate Catalyzed by Supported Gold Nanoparticles. Advanced Synthesis & Catalysis 353:2-3, pages 281-286.
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Saeid Farhadi, Firouzeh Siadatnasab & Maryam Kazem. (2011) Microwave-Assisted Rapid and efficient Reduction of Aromatic Nitro Compounds to Amines with Propan-2-ol over Nanosized Perovskite-type SmFeO 3 powder as a New Recyclable Heterogeneous Catalyst . Journal of Chemical Research 35:2, pages 104-108.
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Li Zhou, Huizi Gu & Xinhuan Yan. (2009) A Novel Transfer Hydrogenation with High Hydrogen Utilization for the Hydrogenation of Halogenated Nitrobenzene without Hydrodehalogenation. Catalysis Letters 132:1-2, pages 16-21.
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N. M. Ivanova, E. A. Soboleva, E. V. Kulakova, V. P. Malyshev & I. V. Kirilyus. (2009) Reduction of nitrophenols in an electrocatalytic system. Russian Journal of Applied Chemistry 82:3, pages 421-428.
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Francisco Alonso, Paola Riente, Francisco Rodríguez-Reinoso, Javier Ruiz-Martínez, Antonio Sepúlveda-Escribano & Miguel Yus. (2008) Platinum nanoparticles supported on titania as an efficient hydrogen-transfer catalyst. Journal of Catalysis 260:1, pages 113-118.
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Ulrich Scholz. 2007. Amino Group Chemistry. Amino Group Chemistry 333 375 .
R Sabnis. 2007. Handbook of Acid-Base Indicators. Handbook of Acid-Base Indicators 295 328 .
Anthony O. King, Ichiro Shinkai, K. Abiraj & D. Channe Gowda. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
Koen Van Aken, Lucjan Strekowski & Luc Patiny. (2006) EcoScale, a semi-quantitative tool to select an organic preparation based on economical and ecological parameters. Beilstein Journal of Organic Chemistry 2.
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Kapa Prasad, Xinglong Jiang, Joel S. Slade, Jennifer Clemens, Oljan Repič & Thomas J. Blacklock. (2005) New Trends in Palladium‐Catalyzed Transfer Hydrogenations Using Formic Acid. Advanced Synthesis & Catalysis 347:14, pages 1769-1773.
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Yugang Liu, Yansong Lu, Mahavir Prashad, Oljan Repič & Thomas J. Blacklock. (2005) A Practical and Chemoselective Reduction of Nitroarenes to Anilines Using Activated Iron. Advanced Synthesis & Catalysis 347:2-3, pages 217-219.
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Jan Dalmolen, Marcel van der Sluis, José W. Nieuwenhuijzen, Auke Meetsma, Ben de Lange, Bernard Kaptein, Richard M. Kellogg & Quirinus B. Broxterman. (2004) Synthesis of Enantiopure 1‐Aryl‐1‐butylamines and 1‐Aryl‐3‐butenylamines by Diastereoselective Addition of Allylzinc Bromide to Imines Derived from ( R )‐Phenylglycine Amide . European Journal of Organic Chemistry 2004:7, pages 1544-1557.
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Michael B. Smith. 2003. Compendium of Organic Synthetic Methods. Compendium of Organic Synthetic Methods 264 309 .
Shankare Gowda & D.Channe Gowda. (2002) Application of hydrazinium monoformate as new hydrogen donor with Raney nickel: a facile reduction of nitro and nitrile moieties. Tetrahedron 58:11, pages 2211-2213.
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D. Channe Gowda & B. Mahesh. (2010) ChemInform Abstract: Catalytic Transfer Hydrogenation of Aromatic Nitro Compounds by Employing Ammonium Formate and 5% Platinum on Carbon.. ChemInform 32:1.
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