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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 38, 2008 - Issue 23
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Original Articles

Water-Accelerated Selective Synthesis of 1,2-Disubstituted Benzimidazoles at Room Temperature Catalyzed by Br⊘nsted Acidic Ionic Liquid

Minoo Dabiri Department of Chemistry, Faculty of Science, Shahid Beheshti University, G. C., Evin, Tehran, IranCorrespondence[email protected]
,
Peyman Salehi Department of Phytochemistry, Medicinal Plants and Drugs Research Institute, Shahid Beheshti University, Tehran, Iran
,
Mostafa Baghbanzadeh Department of Chemistry, Faculty of Science, Shahid Beheshti University, G. C., Evin, Tehran, Iran
&
Maryam Shakouri Nikcheh Department of Chemistry, Faculty of Science, Shahid Beheshti University, G. C., Evin, Tehran, Iran
Pages 4272-4281 | Received 03 May 2008, Published online: 31 Oct 2008

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Fatemeh Pakpour Roudsari, Mohadeseh Seddighi, Farhad Shirini & Hassan Tajik. (2020) Application of [PVP-SO3H] HSO4 as an Efficient Polymeric-Based Solid Acid Catalyst in the Synthesis of Some Benzimidazole Derivatives. Organic Preparations and Procedures International 52:4, pages 340-353.
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Articles from other publishers (27)

Abdulhamid Dehghani, Yousef Delshad, Moslem Ahmadpour & Milad Ghezelsofloo. (2024) Synthesis of 1, 2-Disubstituted Benzimidazoles at Ambient Temperature Catalyzed by 1-Methylimidazolium Tetraflouroborate ([Hmim] BF_4) and Investigating Their Anti-ovarian Cancer Properties Through Molecular Docking Studies and Calculations. Qeios.
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Susheel Gulati, Rajvir Singh & Suman Sangwan. (2023) A Review on Green Synthesis and Biological Activities of Medicinally Important Nitrogen and Oxygen Containing Heterocycles. Current Organic Chemistry 26:20, pages 1848-1894.
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G. Varvounis, V. Gkalpinos, P. Theodorakopoulou & E. Tsemperlidou. 2022. Comprehensive Heterocyclic Chemistry IV. Comprehensive Heterocyclic Chemistry IV 113 307 .
B. Anjaneyulu, G.B. Dharma Rao, Nancy & S. Nagakalyan. (2021) Synthesis and DFT studies of 1,2-disubstituted benzimidazoles using expeditious and magnetically recoverable CoFe2O4/Cu(OH)2 nanocomposite under solvent-free condition. Journal of Saudi Chemical Society 25:12, pages 101394.
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Rajani Kanta Mahato, Prafullya Kumar Mudi, Mayukh Deb & Bhaskar Biswas. (2021) A Direct Metal‐Free Synthetic Approach for the Efficient Production of Privileged Benzimidazoles in Water Medium under Aerobic Condition. Asian Journal of Organic Chemistry 10:11, pages 2954-2963.
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Arup DattaSamiran Halder. (2020) Dowex 50W: Mild Efficient Reusable Heterogeneous Catalyst for Synthesis of Quinoxaline Derivatives in Aqueous Medium. Oriental Journal Of Chemistry 36:6, pages 1218-1224.
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Samiran HalderArup Datta. (2020) Highly Efficient Chemoselective Synthesis of 2-Aryl-1-arylmethyl-1H-Benzimidazoles by Using TiCp2Cl2 Catalyst. Oriental Journal Of Chemistry 36:6, pages 1173-1178.
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Kalicharan Das, Avijit Mondal & Dipankar Srimani. (2018) Selective Synthesis of 2-Substituted and 1,2-Disubstituted Benzimidazoles Directly from Aromatic Diamines and Alcohols Catalyzed by Molecularly Defined Nonphosphine Manganese(I) Complex. The Journal of Organic Chemistry 83:16, pages 9553-9560.
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Shuang Hao, Yuchuan Liu, Chuning Shang, Zhiqiang Liang & Jihong Yu. (2017) CO 2 adsorption and catalytic application of imidazole ionic liquid functionalized porous organic polymers . Polymer Chemistry 8:11, pages 1833-1839.
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Ahmad Shaabani, Heshmatollah Sepahvand, Seyyed Emad Hooshmand & Mahmoud Borjian Boroujeni. (2016) Design, preparation and characterization of Cu/GA/Fe 3 O 4 @SiO 2 nanoparticles as a catalyst for the synthesis of benzodiazepines and imidazoles . Applied Organometallic Chemistry 30:6, pages 414-421.
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Sudipta Ponra & K. C. Majumdar. (2016) Brønsted acid-promoted synthesis of common heterocycles and related bio-active and functional molecules. RSC Adv. 6:44, pages 37784-37922.
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Tamar L. Greaves & Calum J. Drummond. (2015) Protic Ionic Liquids: Evolving Structure–Property Relationships and Expanding Applications. Chemical Reviews 115:20, pages 11379-11448.
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Farhad Shirini, Masoumeh Abedini, Mohadeseh Seddighi & Fatemeh Shaabani Arbosara. (2014) Preparation, characterization, and application of 1,1′-disulfo-[2,2′-bipyridine]-1,1′-diium chloride ionic liquid as an efficient catalyst for the synthesis of benzimidazole derivatives. Research on Chemical Intermediates 41:10, pages 7683-7693.
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Ghodsi Mohammadi Ziarani, Negar Lashgari & Alireza Badiei. (2015) Sulfonic acid-functionalized mesoporous silica (SBA-Pr-SO3H) as solid acid catalyst in organic reactions. Journal of Molecular Catalysis A: Chemical 397, pages 166-191.
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Pedavenkatagari Narayana Reddy, Pannala Padmaja, Basireddy V. Subba Reddy & Gundla Rambabu. (2015) Ionic liquid/water mixture promoted organic transformations. RSC Advances 5:63, pages 51035-51054.
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BRAJESH KUMAR, KUMARI SMITA, BRAJENDRA KUMAR & LUIS CUMBAL. (2015) Ultrasound promoted and SiO2/CCl3COOH mediated synthesis of 2-aryl-1-arylmethyl-1H-benzimidazole derivatives in aqueous media: An eco-friendly approach. Journal of Chemical Sciences 126:6, pages 1831-1840.
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Meihong Jin, Guowei Song, Zhenjiang Li, Feng Zhou, Bo Fan & Pingkai Ouyang. (2014) Efficient Synthesis of 2‐Aryl‐1‐arylmethyl‐1 H ‐benzimidazoles in Ball Mill without Solvent . Journal of Heterocyclic Chemistry 51:6, pages 1838-1843.
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Dinesh Kumar, Damodara N. Kommi, Rajesh Chebolu, Sanjeev K. Garg, Raj Kumar & Asit K. Chakraborti. (2013) Selectivity control during the solid supported protic acids catalysed synthesis of 1,2-disubstituted benzimidazoles and mechanistic insight to rationalize selectivity. RSC Adv. 3:1, pages 91-98.
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Rajesh Chebolu, Damodara N. Kommi, Dinesh Kumar, Narendra Bollineni & Asit K. Chakraborti. (2012) Hydrogen-Bond-Driven Electrophilic Activation for Selectivity Control: Scope and Limitations of Fluorous Alcohol-Promoted Selective Formation of 1,2-Disubstituted Benzimidazoles and Mechanistic Insight for Rationale of Selectivity. The Journal of Organic Chemistry 77:22, pages 10158-10167.
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Luísa C. R. Carvalho, Eduarda Fernandes & M. Manuel B. Marques. (2011) Developments Towards Regioselective Synthesis of 1,2‐Disubstituted Benzimidazoles. Chemistry – A European Journal 17:45, pages 12544-12555.
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Catia S. Radatz, Rodrigo B. Silva, Gelson Perin, Eder J. Lenardão, Raquel G. Jacob & Diego Alves. (2011) Catalyst-free synthesis of benzodiazepines and benzimidazoles using glycerol as recyclable solvent. Tetrahedron Letters 52:32, pages 4132-4136.
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Minoo Dabiri, Peyman Salehi, Mahboobeh Bahramnejad & Fatemeh Sherafat. (2010) Synthesis of Diheterocyclic Compounds Based on Triazolyl Methoxy Phenylquinazolines via a One-Pot Four-Component-Click Reaction. Journal of Combinatorial Chemistry 12:5, pages 638-642.
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R. Arundhathi, B. Sreedhar & G. Parthasarathy. (2018) Chamosite, a naturally occurring clay as a versatile catalyst for various organic transformations. Clay Minerals 45:3, pages 281-299.
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Minoo Dabiri, Mahboobeh Bahramnejad & Sahareh Bashiribod. (2010) [Hmim]TFA catalyzed multicomponent reaction: direct, mild, and efficient procedure for the synthesis of 1,2-dihydroquinazoline derivatives. Molecular Diversity 14:3, pages 507-512.
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Minoo Dabiri, Peyman Salehi, Mostafa Baghbanzadeh & Maryam Shakouri Nikcheh. (2009) ChemInform Abstract: Water‐Accelerated Selective Synthesis of 1,2‐Disubstituted Benzimidazoles at Room Temperature Catalyzed by Broensted Acidic Ionic Liquid.. ChemInform 40:16.
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Raquel G. Jacob, Luiz G. Dutra, Cátia S. Radatz, Samuel R. Mendes, Gelson Perin & Eder J. Lenardão. (2009) Synthesis of 1,2-disubstitued benzimidazoles using SiO2/ZnCl2. Tetrahedron Letters 50:13, pages 1495-1497.
Crossref
Larry Yet. 2009. 224 260 .

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