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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 39, 2009 - Issue 23
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Original Articles

Nucleophilic Substitution Reactions of 1-Methyl-2,4,5-trinitroimidazole (MTNI)

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Pages 4282-4288 | Received 26 Jan 2009, Published online: 29 Oct 2009

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M. Anniyappan, K. Vijay Varma, R.S. Amit & J.K Nair. (2020) 1-methyl-2,4,5-trinitroimidazole (MTNI), a melt-cast explosive: synthesis and studies on thermal behavior in presence of explosive ingredients. Journal of Energetic Materials 38:1, pages 111-125.
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Articles from other publishers (20)

Rui Yang, Zhen Dong, Yaxin Liu, Yifei Liu, Haiyan Li, Guofeng Zhang & Zhiwen Ye. (2022) Construction of new framework of 1,3,4-oxadiazole energetic compounds using 1,1-dichloro-2-nitroethylene: design of high-performance molten-cast explosives. Chemical Engineering Journal 429, pages 132503.
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Sergey Chuprun, Dmitry Dar’in, Elizaveta Rogacheva, Liudmila Kraeva, Oleg Levin, Olga Manicheva, Marine Dogonadze, Tatiana Vinogradova, Olga Bakulina & Mikhail Krasavin. (2020) Mutually Isomeric 2- and 4-(3-Nitro-1,2,4-triazol-1-yl)pyrimidines Inspired by an Antimycobacterial Screening Hit: Synthesis and Biological Activity against the ESKAPE Panel of Pathogens. Antibiotics 9:10, pages 666.
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Raja Duddu, Reddy Damavarapu & Damon Parrish. (2020) Synthesis of polynitro methyltetrazoles. Journal of Heterocyclic Chemistry 57:7, pages 2923-2927.
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Xin Yin, Jie Li, Guojie Zhang, Zhenqi Zhang, Qing Ma, Jun Wang & Shumin Wang. (2018) Design and Synthesis of Energetic Materials towards Versatile Applications by N-trinitromethyl and N-nitromethyl Functionalization of Nitroimidazoles. ChemPlusChem 83:8, pages 787-796.
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Raja Duddu, John Hoare, Peggy Sanchez, Reddy Damavarapu & Damon Parrish. (2017) Synthesis of Nitro, Dinitro, and Polynitroalkylamino Derivatives of Trifurazanoxide. Journal of Heterocyclic Chemistry 54:6, pages 3087-3092.
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Qing Ma, Zhipeng Lu, Longyu Liao, Jinglun Huang, Dabin Liu, Jinshan Li & Guijuan Fan. (2017) 5,6-Di(2-fluoro-2,2-dinitroethoxy)furazano[3,4-b]pyrazine: a high performance melt-cast energetic material and its polycrystalline properties. RSC Advances 7:62, pages 38844-38852.
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Qing Ma, Tao Jiang, Yu Chi, Ya Chen, Jun Wang, Jinglun Huang & Fude Nie. (2017) A novel multi-nitrogen 2,4,6,8,10,12-hexanitrohexaazaisowurtzitane-based energetic co-crystal with 1-methyl-3,4,5-trinitropyrazole as a donor: experimental and theoretical investigations of intermolecular interactions. New Journal of Chemistry 41:10, pages 4165-4172.
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John Hoare, Raja Duddu & Reddy Damavarapu. (2016) A Safe Scalable Process for Synthesis of 4,6-Bis(nitroimino)-1,3,5-triazinan-2-one (DNAM). Organic Process Research & Development 20:3, pages 683-686.
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M. Anniyappan, S.H. Sonawane, S.J. Pawar & A.K. Sikder. (2015) Thermal decomposition and kinetics of 2,4-dinitroimidazole: An insensitive high explosive. Thermochimica Acta 614, pages 93-99.
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A. V. Kormanov, T. K. Shkineva, I. A. Vatsadze, S. A. Shevelev & I. L. Dalinger. (2014) Nitropyrazoles 23. Synthesis of substituted N-amino-3-nitro-5-R-pyrazoles. Russian Chemical Bulletin 63:2, pages 435-442.
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Kehui Hou, Congming Ma & Zuliang Liu. (2013) Synthesis of 2‐Azido‐4‐nitroimidazole and Its Derivatives for High‐Energy Materials. Chinese Journal of Chemistry 31:12, pages 1539-1545.
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Congming Ma, Yongbin Wang, Kehui Hou, Zuliang Liu & Qizheng Yao. (2013) Synthesis of New Substituted 4‐Amino‐3,5‐dinitropyridine Derivatives. Chinese Journal of Chemistry 31:10, pages 1299-1304.
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Bao-Hui Li, Wen-jing Shi, Fu-de Ren & Yong Wang. (2012) A B3LYP and MP2(full) theoretical investigation into the strength of the C–NO2 bond upon the formation of the intermolecular hydrogen-bonding interaction between HF and the nitro group of nitrotriazole or its methyl derivatives. Journal of Molecular Modeling 19:2, pages 511-519.
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Kehui Hou & Zuliang Liu. (2013) Synthesis and Characterization of Some N ‐Aryl‐4‐nitroimidazoles as Potential Insensitive Energy Materials . Chinese Journal of Chemistry 31:2, pages 243-246.
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Kehui Hou, Congming Ma & Zuliang Liu. (2013) Synthesis, single crystal structure and performance of N-substituted derivatives of dinitroimidazole. New Journal of Chemistry 37:9, pages 2837.
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Qing-guo Wei, Wen-jing Shi, Fu-de Ren, Yong Wang & Jun Ren. (2012) A B3LYP and MP2(full) theoretical investigation into the strength of the C-NO2 bond upon the formation of the molecule-cation interaction between Na+ and the nitro group of nitrotriazole or its methyl derivatives. Journal of Molecular Modeling 19:1, pages 453-463.
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P. Ravi & Surya P. Tewari. (2012) Theoretical investigations on the structure, density, thermodynamic and performance properties of amino-, methyl-, and nitroimidazoles and their N-oxides. Structural Chemistry 23:6, pages 1953-1970.
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Larry Yet. 2011. 217 257 .
Raja Duddu, Paritosh R. Dave, Reddy Damavarapu, Rao Surapaneni & Damon Parrish. (2010) ChemInform Abstract: Nucleophilic Substitution Reactions of 1‐Methyl‐2,4,5‐trinitroimidazole (MTNI).. ChemInform 41:14.
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Raja Duddu, Paritosh R. Dave, Reddy Damavarapu, Nathaniel Gelber & Damon Parrish. (2010) Synthesis of N-amino- and N-nitramino-nitroimidazoles. Tetrahedron Letters 51:2, pages 399-401.
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