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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 40, 2010 - Issue 12
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Original Articles

Mild and Efficient Deoxygenation of Sulfoxides to Sulfides Using HfCl4/KBH4 System

Jianghua Zhang State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China
,
Xinqin Gao State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, ChinaCorrespondence[email protected]
,
Chengyi Zhang State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China
,
Cheng Zhang State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China
,
Jiming Luan State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China
&
Defeng Zhao State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China
Pages 1794-1801 | Received 22 Apr 2009, Published online: 17 May 2010

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Anže Zupanc & Marjan Jereb. (2020) NaSH-HCl mediated reduction of sulfoxides into sulfides under organic solvent-free reaction conditions. Green Chemistry Letters and Reviews 13:4, pages 341-348.
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Byung Woo Yoo, Bo Ran Yu & Cheol Min Yoon. (2015) A facile and efficient procedure for the deoxygenation of sulfoxides to sulfides with the HfCl4/Zn system. Journal of Sulfur Chemistry 36:4, pages 358-363.
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Maasoumeh Jafarpour, Abdolreza Rezaeifard & Mahdieh Heidari. (2011) Efficient Organic Transformations Mediated by ZrOCl2·8H2O in Water. Phosphorus, Sulfur, and Silicon and the Related Elements 186:7, pages 1470-1482.
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Articles from other publishers (24)

Jixia Fan, Yifan Du, Rongrong Zhao, Qixing Liu & Haifeng Zhou. (2023) Catalyst- and additive-free chemoselective reduction of sulfoxides into sulfides using B2(OH)4 as a deoxygenative agent. Tetrahedron 140, pages 133411.
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Juan Tang, Jiayu Hu, Zhiqiang Zhu & Shouzhi Pu. (2023) Recent Advances in Visible-Light-Induced Organic Phosphine- Promoted Deoxygenative Functionalization Reactions. Chinese Journal of Organic Chemistry 43:12, pages 4036.
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Yanxin Wang, Kaiyue Yao, Duanjian Tao, Nian Xiang, Wei Wang & Zehui Zhang. (2021) Hydrodeoxygenation of sulfoxides into sulfides under mild conditions over a heterogeneous cobalt catalyst. Reaction Chemistry & Engineering 6:8, pages 1475-1482.
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Norio Sakai, Retsu Shimada & Yohei Ogiwara. (2021) Indium‐Catalyzed Deoxygenation of Sulfoxides with Hydrosilanes. Asian Journal of Organic Chemistry 10:4, pages 845-850.
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Shu Fujita, Sho Yamaguchi, Seiji Yamazoe, Jun Yamasaki, Tomoo Mizugaki & Takato Mitsudome. (2020) Nickel phosphide nanoalloy catalyst for the selective deoxygenation of sulfoxides to sulfides under ambient H 2 pressure . Organic & Biomolecular Chemistry 18:43, pages 8827-8833.
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Qiang Yang, Min Sheng, Xiaoyong Li, Craig Tucker, Suhelen Vásquez Céspedes, Nicola J. Webb, Gregory T. Whiteker & Jing Yu. (2020) Potential Explosion Hazards Associated with the Autocatalytic Thermal Decomposition of Dimethyl Sulfoxide and Its Mixtures. Organic Process Research & Development 24:6, pages 916-939.
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Aimee K. ClarkeAlison Parkin, Richard J. K. TaylorWilliam P. Unsworth & James A. Rossi-Ashton. (2020) Photocatalytic Deoxygenation of Sulfoxides Using Visible Light: Mechanistic Investigations and Synthetic Applications. ACS Catalysis 10:10, pages 5814-5820.
Crossref
R.W. Fischer. 2019. Catalysis from A to Z. Catalysis from A to Z.
W.R. Thiel. 2019. Catalysis from A to Z. Catalysis from A to Z.
Kaiyue Yao, Ziliang Yuan, Shiwei Jin, Quan Chi, Bing Liu, Renjie Huang & Zehui Zhang. (2020) Efficient hydrodeoxygenation of sulfoxides into sulfides under mild conditions using heterogeneous cobalt–molybdenum catalysts. Green Chemistry 22:1, pages 39-43.
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Jiaqi Li, Shengsi Liu, Tracy L. Lohr & Tobin J. Marks. (2019) Efficient Chemoselective Reduction of N ‐Oxides and Sulfoxides Using a Carbon‐Supported Molybdenum‐Dioxo Catalyst and Alcohol . ChemCatChem 11:16, pages 4139-4146.
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Lotfi Shiri & Mosstafa Kazemi. (2017) Deoxygenation of sulfoxides. Research on Chemical Intermediates 43:11, pages 6007-6041.
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Mohammad Abbasi, Mohammad Reza Mohammadizadeh & Zahra Moradi. (2015) Efficient reduction of sulfoxides with NaHSO 3 catalyzed by I 2. Tetrahedron Letters 56:47, pages 6610-6613.
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Hiroshi Kominami, Kousuke Nakanishi, Satoshi Yamamoto, Kazuya Imamura & Keiji Hashimoto. (2014) Photocatalytic deoxygenation of sulfoxides to sulfides over titanium(IV) oxide at room temperature without use of metal co-catalysts. Catalysis Communications 54, pages 100-103.
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Takato Mitsudome, Yusuke Takahashi, Tomoo Mizugaki, Koichiro Jitsukawa & Kiyotomi Kaneda. (2014) Hydrogenation of Sulfoxides to Sulfides under Mild Conditions Using Ruthenium Nanoparticle Catalysts. Angewandte Chemie International Edition 53:32, pages 8348-8351.
Crossref
Takato Mitsudome, Yusuke Takahashi, Tomoo Mizugaki, Koichiro Jitsukawa & Kiyotomi Kaneda. (2014) Hydrogenation of Sulfoxides to Sulfides under Mild Conditions Using Ruthenium Nanoparticle Catalysts. Angewandte Chemie 126:32, pages 8488-8491.
Crossref
Yusuke Takahashi, Takato Mitsudome, Tomoo Mizugaki, Koichiro Jitsukawa & Kiyotomi Kaneda. (2014) Highly Efficient Deoxygenation of Sulfoxides Using Hydroxyapatite-supported Ruthenium Nanoparticles. Chemistry Letters 43:4, pages 420-422.
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Sara C. A. Sousa, Joana R. Bernardo, Mariusz Wolff, Barbara Machura & Ana C. Fernandes. (2014) Oxo‐Rhenium(V) Complexes Containing Heterocyclic Ligands as Catalysts for the Reduction of Sulfoxides. European Journal of Organic Chemistry 2014:9, pages 1855-1859.
Crossref
A.-C. Gaumont, M. Gulea, S. Perrio & V. Reboul. 2014. Comprehensive Organic Synthesis II. Comprehensive Organic Synthesis II 535 563 .
Yujin Jang, Kyoung Tae Kim & Heung Bae Jeon. (2013) Deoxygenation of Sulfoxides to Sulfides with Thionyl Chloride and Triphenylphosphine: Competition with the Pummerer Reaction. The Journal of Organic Chemistry 78:12, pages 6328-6331.
Crossref
Sara C.A. Sousa, Joana R. Bernardo, Carlos C. Romão & Ana C. Fernandes. (2012) Highly efficient rhenium-catalyzed deoxygenation of sulfoxides without adding any reducing agent. Tetrahedron 68:39, pages 8194-8197.
Crossref
Zheng Ping Wu, Yuan Bing Sun & Ian S. Butler. (2011) Optimized Structures and Theoretical <sup>1</sup>H-NMR Spectral Analysis of the Methylene Protons in Dibenzyl Sulfoxide. Advanced Materials Research 391-392, pages 1368-1374.
Crossref
Jianghua Zhang, Xinqin Gao, Chengyi Zhang, Cheng Zhang, Jiming Luan & Defeng Zhao. (2010) ChemInform Abstract: Mild and Efficient Deoxygenation of Sulfoxides to Sulfides Using HfCl 4 /KBH 4 System. . ChemInform 41:44.
Crossref
Ivânia Cabrita, Sara C.A. Sousa & Ana C. Fernandes. (2010) Reduction of sulfoxides catalyzed by oxo-complexes. Tetrahedron Letters 51:47, pages 6132-6135.
Crossref

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