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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 3, 1973 - Issue 1
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Original Articles

Titanium (III) Reduction of Sulfoxides

Tse-Lok Ho Department of Chemistry, University of Manitoba, WINNIPEG Manitoba, Canada, R3T 2N2
&
C. M. Wong Department of Chemistry, University of Manitoba, WINNIPEG Manitoba, Canada, R3T 2N2
Pages 37-38 | Received 03 Nov 1972, Published online: 06 Dec 2006

Citations (25)

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Sung-Kee Chung & Guangdian Han. (1982) A Convenient Deoxygenation of Sulfoxides with CO(II) and NaBH4 . Synthetic Communications 12:11, pages 903-906.
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Jozef Drabowicz, Tatsuo Numata & Shigeru Oae. (1977) DEXYGENATION OF SULFOXIDES. A REVIEW. Organic Preparations and Procedures International 9:2, pages 63-83.
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Tse-Lok Ho & Chiu Ming Wong. (1973) Titanium Trichloride Reactions: Dehalogenation. Synthetic Communications 3:3, pages 237-239.
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Articles from other publishers (22)

Anthony Bongso, Robby Roswanda & Yana Maolana Syah. (2022) Recent advances of carbonyl olefination via McMurry coupling reaction . RSC Advances 12:25, pages 15885-15909.
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Yusuke Takahashi, Takato Mitsudome, Tomoo Mizugaki, Koichiro Jitsukawa & Kiyotomi Kaneda. (2014) Highly Efficient Deoxygenation of Sulfoxides Using Hydroxyapatite-supported Ruthenium Nanoparticles. Chemistry Letters 43:4, pages 420-422.
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Lise-Lotte Gundersen, Frode Rise, Kjell Undheim, Enrique Aguilar & Patricia García-García. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
Gurpreet S. Bhatia & Piotr P. Graczyk. (2004) A mild protocol for the deoxygenation of α-hydrogen-containing sulfoxides to the corresponding sulfides. Tetrahedron Letters 45:27, pages 5193-5195.
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K. C. Nicolaou, Alexandros E. Koumbis, Scott A. Snyder & Klaus B. Simonsen. (2000) Novel Reactions Initiated by Titanocene Methylidenes: Deoxygenation of Sulfoxides,N-Oxides, and Selenoxides. Angewandte Chemie 112:14, pages 2629-2633.
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E. D. Savin & V. L. Nedel'kin. (1996) Interaction of diphenyl sulfide with sulfuryl chloride. Russian Chemical Bulletin 45:11, pages 2668-2669.
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Vadim Yu. Kukushkin. (1995) Metal-ion mediated deoxygenation of sulfoxides. Coordination Chemistry Reviews 139, pages 375-407.
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Claudio Mapelli & Katerina Leftheris. 1993. Peptides 1992. Peptides 1992 207 208 .
Yi Dang & Herman J. Geise. (1991) Low-valent organotitanium species and their applications to organic synthesis. Journal of Organometallic Chemistry 405:1, pages 1-39.
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Yoshitsugu Arai, Kazuya Hayashi, Makoto Matsui, Toru Koizumi, Motoo Shiro & Kaoru Kuriyama. (1991) Synthesis and asymmetric Diels–Alder reaction of dimethyl (‘d-isoborneol-10-sulphinyl’)maleate: novel route to key intermediates for synthesis of some carbocyclic nucleosides and terpenoids. J. Chem. Soc., Perkin Trans. 1:7, pages 1709-1716.
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Koichiro Nagasawa, Yuji Ikenishi & Yuzo Nakagawa. (1990) Oxidation products of cesium monomercaptoundecahydro-closo-dodecaborate(2 -). Journal of Organometallic Chemistry 391:2, pages 139-146.
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Michel Madesclaire. (1988) Reduction of sulfoxides to thioethers. Tetrahedron 44:21, pages 6537-6580.
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Jean-Marc Pons & Maurice Santelli. (1988) Reductions promoted by low valent transition metal complexes in organic synthesis. Tetrahedron 44:14, pages 4295-4312.
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Hitomi Suzuki, Hajime Manabe, Rika Enokiya & Yasuaki Hanazaki. (1986) Preparation and Reactions of Titanium(III) Chloride Solubilized in Inert Organic Solvents. Chemistry Letters 15:8, pages 1339-1340.
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Jin Soon Cha, Jin Euog Kim & Jong Dae Kim. (1985) Selective deoxygenation of sulfoxides with thexylchloroborane-methyl sulfide complex. Tetrahedron Letters 26:52, pages 6453-6456.
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N. Moszner & M. Hartmann. (2004) Vinylpolymerisation mit reduzierenden Übergangsmetallverbindungen. VII. Polymerisation von Methylmethacrylat in Gegenwart von Molybdän(III)‐chlorid‐Sulfoxid‐Systemen. Journal für Praktische Chemie 327:4, pages 595-603.
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J.A. Davies. 1981. 115 187 .
D. D. Mikhno & V. M. Berezovskii. (1980) Advances in the chemistry of biotin. Chemistry of Natural Compounds 16:4, pages 313-338.
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. 1978. Reactions of Organosulfur Compounds. Reactions of Organosulfur Compounds 1 35 .
John E. McMurry. (2002) Organic chemistry of low-valent titanium. Accounts of Chemical Research 7:9, pages 281-286.
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Teruaki Mukaiyama, Toshio Sato & Junichi Hanna. (1973) REDUCTIVE COUPLING OF CARBONYL COMPOUNDS TO PINACOLS AND OLEFINS BY USING TiCl 4 AND Zn . Chemistry Letters 2:10, pages 1041-1044.
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T.‐L. HO & C. M. WONG. (2016) ChemInform Abstract: TITAN(III)‐REDUKTION VON SULFOXIDEN. Chemischer Informationsdienst 4:28.
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