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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 3, 1973 - Issue 3
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Original Articles

Stable Difluoromethylene Olefination Solutions

Douglas G. Naae Department of Chemistry, University of Iowa, Iowa City, Iowa, 52242
&
Donald J. Burton Department of Chemistry, University of Iowa, Iowa City, Iowa, 52242
Pages 197-200 | Received 03 Apr 1973, Published online: 06 Dec 2006

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Yasuyuki Sasada, Teru Shimada, Makoto Ushioda & SHuichi Matsui. (2007) Synthesis and properties of novel 1,1‐difluoropropoxy‐linked liquid crystalline compounds of negative dielectric anisotropy. Liquid Crystals 34:5, pages 569-576.
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Articles from other publishers (65)

Ren-Yin Yang, Hui Wang & Bo Xu. (2021) Base promoted gem -difluoroolefination of alkyl triflones . Chemical Communications 57:39, pages 4831-4834.
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Kohei Fuchibe, Takeshi Fujita & Junji Ichikawa. (2018) Pinpoint-Fluorinated Polycyclic Aromatic Hydrocarbons (F-PAHs): Their Synthesis via Electrophilic Activation of Fluoroalkenes and Propertiesピンポイントフッ素化多環式芳香族炭化水素（F-PAH）：フルオロアルケンの求電子的活性化による合成と性質. Journal of Synthetic Organic Chemistry, Japan 76:9, pages 938-953.
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Xuxue Zhang & Song Cao. (2017) Recent advances in the synthesis and CF functionalization of gem-difluoroalkenes. Tetrahedron Letters 58:5, pages 375-392.
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Go Hirai, Eri Nishizawa, Daiki Kakumoto, Masaki Morita, Mitsuaki Okada, Daisuke Hashizume, Sayoko Nagashima & Mikiko Sodeoka. (2015) Reactions of Carbonyl Compounds with Phosphorus Ylide Generated from Tribromofluoromethane and Tris(dimethylamino)phosphine. Chemistry Letters 44:10, pages 1389-1391.
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Kohei Fuchibe, Toshiyuki Morikawa, Kento Shigeno, Takeshi Fujita & Junji Ichikawa. (2015) Pinpoint-Fluorinated Phenacenes: New Synthesis and Solubility Enhancement Strategies. Organic Letters 17:5, pages 1126-1129.
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Yupu Qiao, Tuda Si, Ming-Hsiu Yang & Ryan A. Altman. (2014) Metal-Free Trifluoromethylation of Aromatic and Heteroaromatic Aldehydes and Ketones. The Journal of Organic Chemistry 79:15, pages 7122-7131.
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Fei Wang, Lingchun Li, Chuanfa Ni & Jinbo Hu. (2014) Deoxygenative gem -difluoroolefination of carbonyl compounds with (chlorodifluoromethyl)trimethylsilane and triphenylphosphine . Beilstein Journal of Organic Chemistry 10, pages 344-351.
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Mingyou Hu, Zhengbiao He, Bing Gao, Lingchun Li, Chuanfa Ni & Jinbo Hu. (2013) Copper-Catalyzed gem -Difluoroolefination of Diazo Compounds with TMSCF 3 via C–F Bond Cleavage . Journal of the American Chemical Society 135:46, pages 17302-17305.
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Theresa Liang, Constanze N. Neumann & Tobias Ritter. (2013) Introduction of Fluorine and Fluorine‐Containing Functional Groups. Angewandte Chemie International Edition 52:32, pages 8214-8264.
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Charles S. Thomoson, Henry Martinez & William R. DolbierJr.Jr.. (2013) The use of methyl 2,2-difluoro-2-(fluorosulfonyl)acetate as the difluorocarbene source to generate an in situ source of difluoromethylene triphenylphosphonium ylide. Journal of Fluorine Chemistry 150, pages 53-59.
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Jian Zheng, Ji Cai, Jin-Hong Lin, Yong Guo & Ji-Chang Xiao. (2013) Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine. Chemical Communications 49:68, pages 7513.
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Lingui Zhu, Ya Li, Yanchuan Zhao & Jinbo Hu. (2010) Nucleophilic (phenylsulfonyl)difluoromethylation of alkyl halides using PhSO2CF2SiMe3: preparation of gem-difluoroalkenes and trifluoromethyl compounds. Tetrahedron Letters 51:47, pages 6150-6152.
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Yanchuan Zhao, Weizhou Huang, Lingui Zhu & Jinbo Hu. (2010) Difluoromethyl 2-Pyridyl Sulfone: A New gem- Difluoroolefination Reagent for Aldehydes and Ketones . Organic Letters 12:7, pages 1444-1447.
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Donald J. Burton, Weiming Qui, Richard J. K. Taylor & Graeme D. McAllister. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
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G. K. Surya Prakash, Jinbo Hu, Ying Wang & George A. Olah. (2004) Difluoromethyl Phenyl Sulfone, a Difluoromethylidene Equivalent: Use in the Synthesis of 1,1‐Difluoro‐1‐alkenes. Angewandte Chemie 116:39, pages 5315-5318.
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Hisanori Ueki, Takashi Chiba, Takashi Yamazaki & Tomoya Kitazume. (2004) Preparation and Regioselective S N 2‘ Reaction of Novel g em -Difluorinated Vinyloxiranes with RLi . The Journal of Organic Chemistry 69:22, pages 7616-7627.
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Donald J. Burton & Weiming Qiu. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
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Ba V. Nguyen & Donald J. Burton. (1997) A New Route for the Preparation of Substituted 2,2-Difluorostyrenes and a Convenient Route to Substituted (2,2,2-Trifluoroethyl)benzenes. The Journal of Organic Chemistry 62:22, pages 7758-7764.
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Makoto Fujita & Tamejiro Hiyama. (1987) Efficient Carbonyl Addition of Polyfluorochloroethyl, -ethylidene, and -ethenyl Units by Means of 1,1,1-Trichloro-2,2,2-trifluoroethane and Zinc. Bulletin of the Chemical Society of Japan 60:12, pages 4377-4384.
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Takeo Taguchi, Tsutomu Morikawa, Osamu Kitagawa, Takashi Mishima & Yoshiro Kobayashi. (1985) SYNTHESES OF β, β-DIFLUOROCARBOXYLIC ACID DERIVATIVES THROUGH THE CLAISEN REARRANGEMENT OF 1, 1-DIFLUORO-1-ALKEN-3-OLS. CHEMICAL & PHARMACEUTICAL BULLETIN Chemical and Pharmaceutical Bulletin 33:11, pages 5137-5140.
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Takashi Ishihara, Masayuki Yamana & Teiichi Ando. (1983) Organocuprate-induced substitution of the enol oxygen moiety in 2,2-difluoro enol phosphates with allyl halides: a novel route to -diffluoroolefins from chlorodifluoromethyl ketones. Tetrahedron Letters 24:50, pages 5657-5660.
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