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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 13, 1983 - Issue 2
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Original Articles

Polymer-Supported “Multi-Site” Phase Transfer Catalysts

John P. Idoux Department of Chemistry, University of Central Florida, Orlando, Florida, 32816, USA
,
Ronald Wysocki Department of Chemistry, University of Central Florida, Orlando, Florida, 32816, USA
,
Sherre Young Department of Chemistry, University of Central Florida, Orlando, Florida, 32816, USA
,
Jeffrey Turcot Department of Chemistry, University of Central Florida, Orlando, Florida, 32816, USA
,
Charlene Ohlman Department of Chemistry, University of Central Florida, Orlando, Florida, 32816, USA
&
Russell Leonard Department of Chemistry, University of Central Florida, Orlando, Florida, 32816, USA
Pages 139-144 | Published online: 05 Dec 2006

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Murugesan Vajjiravel & M. J. Umapathy. (2008) Kinetics and Mechanism of Multi-site Phase Transfer Catalyzed Radical Polymerization of Ethyl Methacrylate. International Journal of Polymeric Materials and Polymeric Biomaterials 58:1, pages 61-76.
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Hung-Ming Yang & Ho-Shing Wu. (2003) Interfacial Mechanism and Kinetics of Phase-Transfer Catalysis. Catalysis Reviews 45:3-4, pages 463-540.
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Joseph Paul Jayachandran & Maw‐Ling Wang. (2000) Hydroxide‐ion initiated dichlorocyclopropanation of 5‐vinyl norbornene using a new active phase transfer reagent. Journal of the Chinese Institute of Engineers 23:5, pages 557-565.
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J. Paul Jayachandran & Maw-Ling Wang. (1999) A New Phase Transfer Reagent for the Addition of Dichlorocarbene to Olefins Under Mild PTC Conditions. Synthetic Communications 29:23, pages 4101-4112.
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T. Balakrishnan & J. Paul Jayachandran. (1995) Synthesis And Utility Of α,α'-bis (Triethyl Ammonium Methylene Chloride) β-Phenyl Ethene in Hydroxide Ion Initiated Reactions—A New Multi-Site Phase Transfer Catalyst. Synthetic Communications 25:23, pages 3821-3830.
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Articles from other publishers (53)

P.A. Vivekanand, T.K. Fayaz, S. Harikumar, P. Kamaraj, V. Thiruvengadam & V. Shanmugam. (2021) Enhanced catalytic activity of new di-site onium salt in the kinetics of α-Tolunitrile monoalkylation. Materials Today: Proceedings 36, pages 848-852.
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Manickam Sathiyaraj & Perumal Venkatesh. (2020) A Kinetic Study on the Synthesis of N-arylation of Indole Under Synergetic Effect of Multi-Site Phase Transfer Catalysis System. Current Organocatalysis 7:2, pages 89-95.
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O. Crosby. 2019. Catalysis from A to Z. Catalysis from A to Z.
Vajjiravel Murugesan, Elumalai Marimuthu, K. S. Yoganand & M. J. Umapathy. (2017) Multi-site phase transfer catalyzed radical polymerization of methyl methacrylate in mixed aqueous–organic medium: a kinetic study. International Journal of Industrial Chemistry 8:3, pages 241-251.
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Kottala Vijaya Ponmuthu, Duraimurugan Kumaraguru, Jesin Beneto Arockiam, Sadhasivam Velu, Murugesan Sepperumal & Siva Ayyanar. (2016) New quaternary phosphonium salt as multi-site phase-transfer catalyst for various alkylation reactions. Research on Chemical Intermediates 42:12, pages 8345-8358.
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Duraimurugan Kumaraguru, Dhanamoorthy Vaithialingam, Jesin Beneto Arockiam, Ashokkumar Veeramanoharan & Siva Ayyanar. (2016) Synthesis and characterization of new multi-site phase transfer catalyst and its catalytic efficiency in dichlorocarbene addition to (R)-Carvone. Journal of the Taiwan Institute of Chemical Engineers 62, pages 31-38.
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Ragini Gupta, Deepti Sharma, P. S. Verma & Anshu Jain. (2016) Insecticidal Evaluation and [4+2] Aza-Diels-Alder Synthesis of 3,7-Diaryl-6,7-dihydro-5 H -6-substituted Thiazolo[3,2-a]pyrimidin-5-ones Under Coupled Ultrasonic Irradiation and PTC . Journal of Heterocyclic Chemistry 53:1, pages 38-45.
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Arockiam Jesin Beneto, Jayaraman Sivamani, Veeramanoharan Ashokkumar, Rajendiran Balasaravanan, Kumaraguru Duraimurugan & Ayyanar Siva. (2015) Highly enantioselective Michael addition reactions with new trimeric chiral phase transfer catalysts. New Journal of Chemistry 39:4, pages 3098-3104.
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Varathan Selvaraj, Perumal Sakthivel & Venugopal Rajendran. (2015) Effect of ultrasound in the free radical polymerization of acrylonitrile under a new multi-site phase-transfer catalyst – A kinetic study. Ultrasonics Sonochemistry 22, pages 265-271.
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Eagambaram Murugan, Gurusamy Tamizharasu & Paramasivam Shanmugam. (2014) Synthesis of new polymer-supported multi-site phase transfer catalysts and their catalysis for the C-alkylation of 1-indanone in association with ultrasound: A kinetic study. Reaction Kinetics, Mechanisms and Catalysis 113:1, pages 39-59.
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Hossein Mahdavi & Mehdi Amirsadeghi. (2013) Synthesis and applications of quaternized highly branched polyacrylamide as a novel multi-site polymeric phase transfer catalyst. Journal of the Iranian Chemical Society 10:4, pages 791-797.
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Perumberkandgai Vivekanand, Maw-Ling Wang & Yu-Ming Hsieh. (2013) Sonolytic and Silent Polymerization of Methacrlyic Acid Butyl Ester Catalyzed by a New Onium Salt with bis-Active Sites in a Biphasic System — A Comparative Investigation. Molecules 18:2, pages 2419-2437.
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Kavitha Sankar & Venugopal Rajendran. (2013) Polymerization of ethyl methacrylate under the influence of ultrasound assisted a new multi-site phase-transfer catalyst system – A kinetic study. Ultrasonics Sonochemistry 20:1, pages 329-337.
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Subramanian Loganathan & Venugopal Rajendran. (2013) Ultrasound assisted polymerization of N-vinyl imidazole under phase-transfer catalysis condition – A kinetic study. Ultrasonics Sonochemistry 20:1, pages 308-313.
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Kavitha Sankar & Venugopal Rajendran. (2012) Ultrasound assisted free radical polymerization of glycidyl methacrylate by a new disite phase-transfer catalyst system: A kinetic study. Ultrasonics Sonochemistry 19:6, pages 1205-1212.
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Eagambaram Murugan & Gurusamy Tamizharasu. (2012) New soluble multi-site phase transfer catalysts and their catalysis for dichlorocarbene addition to citronellal assisted by ultrasound—A kinetic study. Journal of Molecular Catalysis A: Chemical 363-364, pages 81-89.
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Hossein Mahdavi & Mehdi Amirsadeghi. (2012) Kinetic study of dichlorocarbene addition to olefins via a quaternized highly branched polyacrylamide as a new multi-site phase transfer catalyst. Iranian Polymer Journal 21:9, pages 641-649.
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Eagambaram Murugan & Gurusamy Tamizharasu. (2011) Synthesis and characterization of new soluble multisite phase transfer catalysts and their catalysis in free radical polymerization of methyl methacrylate aided by ultrasound—A kinetic study. Journal of Applied Polymer Science 125:1, pages 263-273.
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P.A. Vivekanand & Maw-Ling Wang. (2012) An efficient recyclable polymer-supported bis-quaternary onium phase-transfer catalyst for the synthesis of dihalocyclopropyl derivatives at low alkaline concentration-comparative kinetic aspects. Catalysis Communications 22, pages 6-12.
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Murugesan Vajjiravel & M. J. Umapathy. (2010) Kinetics of radical polymerization of glycidyl methacrylate initiated by multi‐site phase transfer catalyst–potassium peroxydisulfate in two‐phase system. Journal of Applied Polymer Science 120:3, pages 1794-1799.
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P.A. Vivekanand & T. Balakrishnan. (2009) Evaluation of catalytic efficiency of a triple-site phase transfer catalyst and the kinetics of dichlorocarbene addition to 5-vinyl-2-norbornene. Catalysis Communications 10:15, pages 1962-1966.
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P. A. Vivekanand & T. Balakrishnan. (2009) Catalytic Potential of a New Polymer-Anchored Multisite Phase Transfer Catalyst in the Dichlorocarbene Addition to Indene. Catalysis Letters 131:3-4, pages 587-596.
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Eagambaram Murugan & Prakash Gopinath. (2009) Triphase catalytic activity of a new insoluble multi-site phase transfer catalyst in C-alkylation of dihydrocarvone—A kinetic study. Journal of Molecular Catalysis A: Chemical 309:1-2, pages 12-20.
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P.A. Vivekanand & T. Balakrishnan. (2009) Synthesis and characterization of a novel multi-site phase transfer catalyst and a kinetic study of the intramolecular cyclopentanation of indene. Applied Catalysis A: General 364:1-2, pages 27-34.
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P.A. Vivekanand & T. Balakrishnan. (2009) Superior catalytic efficiency of a new multi-site phase transfer catalyst in the C-alkylation of dimedone – A kinetic study. Catalysis Communications 10:10, pages 1371-1375.
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Eagambaram Murugan & Prakash Gopinath. (2008) Heterogeneous catalysis by new bead‐shaped polymer‐supported multisite phase transfer catalysts. Journal of Polymer Science Part A: Polymer Chemistry 47:3, pages 771-785.
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P.A. Vivekanand & T. Balakrishnan. (2009) Kinetics of dichlorocyclopropanation of vinylcyclohexane catalyzed by a new multi-site phase transfer catalyst. Catalysis Communications 10:5, pages 687-692.
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Eagambaram Murugan & Prakash Gopinath. (2008) Catalytic activity of novel soluble multi-site phase transfer catalyst in dichlorocarbene addition to α-pinene. Journal of Molecular Catalysis A: Chemical 294:1-2, pages 68-73.
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Murugesan Vajjiravel & M. J. Umapathy. (2008) Free radical polymerisation of methyl methacrylate initiated by multi-site phase transfer catalyst—a kinetic study. Colloid and Polymer Science 286:6-7, pages 729-738.
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Murugesan Vajjiravel & M. J. Umapathy. (2007) Synthesis and characterization of multi-site phase transfer catalyst: application in radical polymerisation of acrylonitrile – a kinetic study. Journal of Polymer Research 15:1, pages 27-36.
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Eagambaram Murugan & Ayyanar Siva. (2007) Effective Darzen's condensation of 4-nonanolide with 1,6-dibromohexan-2-one using new bead-shaped insoluble multi-site (six-site) phase transfer catalyst and low concentration of aqueous NaOH. Journal of Molecular Catalysis A: Chemical 277:1-2, pages 81-92.
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Hanan El-Sharkawy Ali. (2007) Cycloalkylation reactions of fatty amines with α,ω-dihaloalkanes: Role of bis-quaternary ammonium salts as phase-transfer catalysts. Catalysis Communications 8:6, pages 855-860.
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Eagambaram Murugan & Prakash Gopinath. (2007) Synthesis and characterization of novel bead-shaped insoluble polymer-supported tri-site phase transfer catalyst and its efficiency in N-alkylation of pyrrole. Applied Catalysis A: General 319, pages 72-80.
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Maw-Ling Wang & Venugopal Rajendran. (2006) A kinetic study of thioether synthesis under influence of ultrasound assisted phase-transfer catalysis conditions. Journal of Molecular Catalysis A: Chemical 244:1-2, pages 237-243.
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Ayyanar Siva & Eagambaram Murugan. (2005) Synthesis and characterization of novel multi-site phase transfer catalyst and its catalytic efficiency for dichlorocarbene addition to citral. Journal of Molecular Catalysis A: Chemical 241:1-2, pages 101-110.
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E. Murugan & A. Siva. (2005) Preparation of a novel soluble multi-site phase transfer catalyst and the kinetic study for the C-alkylation of α-pinene. Journal of Molecular Catalysis A: Chemical 235:1-2, pages 220-229.
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Maw-Ling Wang, Ze-Fa Lee & Feng-Sheng Wang. (2005) Synthesis of novel multi-site phase-transfer catalyst and its application in the reaction of 4,4′-bis(chloromethyl)-1,1′-biphenyl with 1-butanol. Journal of Molecular Catalysis A: Chemical 229:1-2, pages 259-269.
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T. Balakrishnan, E. Murugan & A. Siva. (2004) Synthesis and characterization of novel soluble multi-site phase transfer catalyst; its efficiency compared with single-site phase transfer catalyst in the alkylation of phenylacetonitrile as a model reaction. Applied Catalysis A: General 273:1-2, pages 89-97.
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Ho-Shing Wu & Hung-Ming Yang. 2002. Interfacial Catalysis. Interfacial Catalysis.
Ho-Shing Wu & Chun-Shen Lee. (2001) Catalytic Activity of Quaternary Ammonium Poly(methylstyrene-co-styrene) Resin in an Organic Solvent/Alkaline Solution. Journal of Catalysis 199:2, pages 217-223.
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Joseph Paul Jayachandran & Maw-Ling Wang. (2001) Selective dichlorocyclopropanation of dicyclopentadiene under controlled phase transfer catalysis conditions. Applied Catalysis A: General 206:1, pages 19-28.
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Joseph Paul Jayachandran & Maw-Ling Wang. (2000) Cycloalkylation of phenylacetonitrile with 1,4-dibromobutane catalyzed by aqueous sodium hydroxide and a new phase transfer reagent, Dq-Br. Applied Catalysis A: General 198:1-2, pages 127-137.
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Joseph Paul Jayachandran, Thayikkannu Balakrishnan & Maw-Ling Wang. (2000) Phase-transfer-catalyzed Darzen's condensation of chloroacetonitrile with cyclohexanone using aqueous sodium hydroxide and a new phase transfer catalyst. Journal of Molecular Catalysis A: Chemical 152:1-2, pages 91-98.
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E. A. Bekturov & S. E. Kudaibergenov. 1997. Catalysis by Polymers. Catalysis by Polymers 50 66 .
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S.V. Luis, M.I. Burguete & B. Altava. (1995) A novel method for the functionalization of polystyrene resins through long aliphatic spacers. Reactive and Functional Polymers 26:1-3, pages 75-83.
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Thayilekannu Balakrishnan & J. Paul Jayachandran. (1995) New ‘multi-site’ phase transfer catalyst for the addition of dichlorocarbene to styrene. J. Chem. Soc., Perkin Trans. 2:11, pages 2081-2085.
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Charles M. Starks, Charles L. Liotta & Marc E. HalpernCharles M. Starks, Charles L. Liotta & Marc E. Halpern. 1994. Phase-Transfer Catalysis. Phase-Transfer Catalysis 207 265 .
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Julio Alvarez-Builla, Juan J. Vaquero, Jose L. Garcia Navio, Juan F. Cabello, Carlos Sunkel, Miguel Fau de Casa-Juana, Fernando Dorrego & Luis Santos. (1990) 1,5-Bis- (N-benzyl-N,N-diethylammoninm) diethylether, dichloride (BBDE C1). A novel bis-ammonium salt as phase transfer catalyst. Tetrahedron 46:3, pages 967-978.
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F. E. Friedli, T. L. Vetter & M. J. Bursik. (1985) Comparison of commercially available quaternary ammonium structures for phase transfer catalysis. Journal of the American Oil Chemists' Society 62:6, pages 1058-1061.
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J.M.J. Frechet, J. Kelly & D.C. Sherrington. (1984) Some novel polymer-supported optically active phase transfer catalysts: 1. Synthesis. Polymer 25:10, pages 1491-1498.
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J. P. IDOUX, R. WYSOCKI, S. YOUNG, J. TURCOT, C. OHLMAN & R. LEONARD. (2016) ChemInform Abstract: POLYMER‐SUPPORTED MULTI‐SITE PHASE TRANSFER CATALYSTS. Chemischer Informationsdienst 14:36.
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