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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 13, 1983 - Issue 12
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Original Articles

2-Phenylbenzimidazoline as a Reducing Agent in the Preparation of Malononitriles from α,β-Unsaturated Dinitriles

Hidenori Chikashita Department of Applied Chemistry, Faculty of Engineering, Kansai University, Suita, Osaka, 564, Japan
,
Shuichi Nishida Department of Applied Chemistry, Faculty of Engineering, Kansai University, Suita, Osaka, 564, Japan
,
Makoto Miyazaki Department of Applied Chemistry, Faculty of Engineering, Kansai University, Suita, Osaka, 564, Japan
&
Kazuyoshi Itoh Department of Applied Chemistry, Faculty of Engineering, Kansai University, Suita, Osaka, 564, Japan
Pages 1033-1039 | Published online: 06 Feb 2007

Citations (21)

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Hidenori Chikashita, Yasuhiro Morita & Kazuyoshi Itoh. (1985) An Efficient Method for the Selective Reduction of 2-Aryl-1-Nitroalkenes to 2-Aryl-1-Nitroalkanes by 2-Phenylbenzimidazoline. Synthetic Communications 15:6, pages 527-533.
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Articles from other publishers (20)

Adrián Luguera Ruiz, Elena Mariani, Stefano Protti & Maurizio Fagnoni. (2024) Photoredox catalyzed release of carbon-based radicals from 2-substituted-1,3-imidazolidines. Organic Chemistry Frontiers 11:3, pages 661-667.
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Shiqi Zhang, Dong Yi, Guangxun Li, Ling Li, Gang Zhao & Zhuo Tang. (2021) Biomimetic alloxan-catalyzed intramolecular redox reaction with O2: One-pot atom-economic synthesis of sulfinyl-functionalized benzimidazoles. Tetrahedron Letters 62, pages 152688.
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L. Reginald Mills & Sophie A.L. Rousseaux. (2019) A one-pot electrophilic cyanation–functionalization strategy for the synthesis of disubstituted malononitriles. Tetrahedron 75:32, pages 4298-4306.
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Valerii F. Traven, Dmitrii A. Cheptsov, Natalya P. Solovjova, Tatjana A. Chibisova, Ilya I. Voronov, Sergei M. Dolotov & Ivan V. Ivanov. (2017) Photoinduced formation of the laser dye coumarin 6 from its dihydro derivatives. Dyes and Pigments 146, pages 159-168.
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Atul K. Singh, Ruchi Chawla & Lal Dhar S. Yadav. (2015) Eosin Y catalyzed visible light mediated aerobic photo-oxidative cleavage of the C–C double bond of styrenes. Tetrahedron Letters 56:5, pages 653-656.
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Takahiko Akiyama & George Nikonov. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis 1 3 .
G. K. Surya Prakash, Thomas Mathew, Chiradeep Panja, Aditya Kulkarni, George A. Olah & Mark A. Harmer. (2012) Tetraflic Acid (1,1,2,2‐Tetrafluoroethanesulfonic Acid, HC 2 F 4 SO 3 H) and Gallium Tetraflate as Effective Catalysts in Organic Synthesis . Advanced Synthesis & Catalysis 354:11-12, pages 2163-2171.
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Takahiko Akiyama. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
Wei Guo, Yongbin Zhang & Guofu Zhou. (2009) Tetrahydropyrimidine Derivatives as Efficient Organic Reductants for Transfer Hydrogenation. HETEROCYCLES 78:6, pages 1541.
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G. K. Surya Prakash, Thomas Mathew, Chiradeep Panja, Habiba Vaghoo, Karthik Venkataraman & George A. Olah. (2006) Efficient One-Pot Synthesis of Fluorinated Benzimidazolines, Benzothiazolines, Benzoxazolines, and Dihydrobenzoxazinones Using Gallium(III) Triflate as a Catalyst. Organic Letters 9:2, pages 179-182.
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Dhevalapally B. Ramachary & G. Babul Reddy. (2006) Towards organo-click reactions: development of pharmaceutical ingredients by using direct organocatalytic bio-mimetic reductions. Organic & Biomolecular Chemistry 4:24, pages 4463.
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Yunlai Ren, Xianlun Xu, Kunpeng Sun & Jian Xu. (2005) A new and effective method for providing optically active monosubstituted malononitriles: selective reduction of ?,?-unsaturated dinitriles catalyzed by copper hydride complexes. Tetrahedron: Asymmetry 16:24, pages 4010-4014.
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Amanda J. Gallant, Brian O. Patrick & Mark J. MacLachlan. (2004) Mild and Selective Reduction of Imines:  Formation of an Unsymmetrical Macrocycle. The Journal of Organic Chemistry 69:25, pages 8739-8744.
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Francesco Risitano, Giovanni Grassi, Francesco Foti & Cristina Bilardo. (2001) Efficient Chemoselective Reduction of 3-Substituted Coumarins Utilizing ortho-Phenylenediamine and Benzaldehyde. HETEROCYCLES 55:7, pages 1311.
Crossref
K. N. Zelenin, I. V. Ukraintsev & V. V. Alekseev. (1998) Intermediates in the reaction ofo-phenylenediamine with carbonyl compounds and their subsequent conversions. Chemistry of Heterocyclic Compounds 34:3, pages 329-333.
Crossref
Abdel-Zaher A. Elassar, Yehya M. Elkholy & Mohammed H. Elnagdi. (1998) Chemistry of Crotononitrile. Journal f�r Praktische Chemie/Chemiker-Zeitung 340:6, pages 491-505.
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Francesco Risitano, Giovanni Grassi, Francesco Caruso & Francesco Foti. (1996) C,C- and C,N-linked dimers and 4-arylmethyl derivatives from 4-arylmethylene pyrazol-5-ones and isoxazol-5-ones with 2-arylbenzim idazolines.. Tetrahedron 52:4, pages 1443-1450.
Crossref
Hidenori Chikashita, Shuichi Nishida, Makoto Miyazaki, Yasuhiro Morita & Kazuyoshi Itoh. (1987) In Situ Generation and Synthetic Application of 2-Phenylbenzimidazoline to the Selective Reduction of Carbon–Carbon Double Bonds of Electron-Deficient Olefins. Bulletin of the Chemical Society of Japan 60:2, pages 737-746.
Crossref
Hidenori Chikashita & Kazuyoshi Itoh. (1986) AlCl3-Promoted Conjugate Reduction of α,β Unsaturated Carbonyl Compounds with 1,3-Dimethyl-2-phenylbenzimidazoline. Bulletin of the Chemical Society of Japan 59:6, pages 1747-1752.
Crossref
H. CHIKASHITA, S. NISHIDA, M. MIYAZAKI & K. ITOH. (2016) ChemInform Abstract: 2‐PHENYLBENZIMIDAZOLINE AS A REDUCING AGENT IN THE PREPARATION OF MALONONITRILES FROM α,β‐UNSATURATED DINITRILES. Chemischer Informationsdienst 15:17.
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