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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 15, 1985 - Issue 8
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Original Articles

Trimethylsulfonium Methylsulfate, A Simple and Efficient Epoxidizing Agent

Paul Mosset Groupe de Recherches de Physicochimie Structurale, U.A. n° 704, Avenue du Général Leclerc, 35042, Rennes Cédex, France
&
René Grée Groupe de Recherches de Physicochimie Structurale, U.A. n° 704, Avenue du Général Leclerc, 35042, Rennes Cédex, France
Pages 749-757 | Published online: 06 Dec 2006

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LaurenceM. Harwood, Guy Casy & Janet Sherlock. (1990) A Simple Laboratory Procedure for Preparation of (1-Methylethenyl)oxirane (3,4-Epoxyisoprene). Synthetic Communications 20:9, pages 1287-1292.
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H. Bouda, M.E. Borredon, M. Delmas & A. Gaset. (1987) Aldehydes and Ketones Epoxidation with Trimethylsulfonium Bromide in a Slightly Hydrated Solid-Liquid Medium. Synthetic Communications 17:5, pages 503-513.
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Giorgiana Denisa Bisag, Silvia Ruggieri, Mariafrancesca Fochi & Luca Bernardi. (2020) Sulfoxonium ylides: simple compounds with chameleonic reactivity. Organic & Biomolecular Chemistry 18:43, pages 8793-8809.
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Yu Xiang, Xing Fan, Pei‐Jun Cai & Zhi‐Xiang Yu. (2018) Understanding Regioselectivities of Corey–Chaykovsky Reactions of Dimethylsulfoxonium Methylide (DMSOM) and Dimethylsulfonium Methylide (DMSM) toward Enones: A DFT Study. European Journal of Organic Chemistry 2019:2-3, pages 582-590.
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Vittorio Pace, Laura Castoldi, Eugenia Mazzeo, Marta Rui, Thierry Langer & Wolfgang Holzer. (2017) Efficient Access to All‐Carbon Quaternary and Tertiary α‐Functionalized Homoallyl‐type Aldehydes from Ketones. Angewandte Chemie 129:41, pages 12851-12856.
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Yuya Daicho, Yuki Watanabe, Naokazu Kano, Mariko Yukimoto, Mao Minoura & Takayuki Kawashima. (2014) Aziridine Formation with Retention of Configuration from a Pentacoordinated 1,2-Thiazetidine Bearing Two Chiral Centers at the 3- and 4-Positions. Bulletin of the Chemical Society of Japan 87:9, pages 1005-1012.
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Guillermo A. Guerrero‐Vásquez, Carlos Kleber Z. Andrade, José M. G. Molinillo & Francisco A. Macías. (2013) Practical First Total Synthesis of the Potent Phytotoxic (±)‐Naphthotectone, Isolated from Tectona grandis . European Journal of Organic Chemistry 2013:27, pages 6175-6180.
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René Momha, Dieudonné Emmanuel Pegnyemb & Paul Mosset. (2012) Synthesis of (Z)-(2′R)-1-O-(2′-methoxynonadec-10′-enyl)-sn-glycerol, a new analog of bioactive ether lipids. Tetrahedron 68:14, pages 2973-2983.
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Peng Gao, Peng-Fei Xu & Hongbin Zhai. (2008) Borax-catalyzed thiolysis of 1,2-epoxides in aqueous medium. Tetrahedron Letters 49:46, pages 6536-6538.
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Sarah A. Kavanagh, Alessandro Piccinini, Eimear M. Fleming & Stephen J. Connon. (2008) Urea derivatives are highly active catalysts for the base-mediated generation of terminal epoxides from aldehydes and trimethylsulfonium iodide. Organic & Biomolecular Chemistry 6:8, pages 1339.
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Naokazu Kano, Yuya Daicho & Takayuki Kawashima. (2006) A Potential Intermediate for the Aza-Corey−Chaykovsky Reaction:  Synthesis, Structure, and Thermolysis of a Pentacoordinate 1,2-Thiazetidine 1-Oxide. Organic Letters 8:20, pages 4625-4627.
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Ellen Klegraf, Stephan Knauer & Horst Kunz. (2006) Stereoselective Synthesis of Benzomorphan Derivatives with Perpivaloylated Galactose as the Chiral Auxiliary. Angewandte Chemie International Edition 45:16, pages 2623-2626.
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