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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 17, 1987 - Issue 13
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Original Articles

Sodium Formaldehyde Sulphoxylate an Efficient Reagent For The Reduction of α-Haloketones

Alan R. Harris Chemical Process R & D Department, Fisons plc, Pharmaceutical Division, R & D Laboratories, Bakewell Road, Loughborough, Leics, England, LEII ORH
Pages 1587-1592 | Published online: 06 Dec 2006

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By André Loupy, Jean Sansoulet & AlanR. Harris. (1989) Organic Chemistry Without Solvent. Improvements to the One Step Preparation of Dibenzyl Sulphones. Synthetic Communications 19:17, pages 2939-2946.
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AlanR. Harris & TimothyJ. Mason. (1989) The Reduction of Aromatic Aldehydes and Benzils by Sodium Formaldehyde Sulphoxylate. Synthetic Communications 19:3-4, pages 529-535.
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Articles from other publishers (22)

Patrick S. Fier, Riley A. Roberts & Reed T. Larson. (2023) The Direct Conversion of Esters to Ketones Enabled by a Traceless Activating Group. Organic Letters 25:17, pages 3131-3135.
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Mei-Chun Wu, Ming-Zhi Li, Yi-Xuan Chen, Fang Liu, Jun-An Xiao, Kai Chen, Hao-Yue Xiang & Hua Yang. (2022) Photoredox-Catalyzed C–H Trideuteromethylation of Quinoxalin-2(1 H )-ones with CDCl 3 as the “CD 3 ” source . Organic Letters 24:35, pages 6412-6416.
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Rashid Ali. (2020) New Dimensions in Rongalite Chemistry: The Land of Opportunities in Organic Synthesis and Material Sciences. ChemistrySelect 5:34, pages 10795-10815.
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Sambasivarao Kotha & Priti Khedkar. (2011) Rongalite: A Useful Green Reagent in Organic Synthesis. Chemical Reviews 112:3, pages 1650-1680.
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Sambasivarao Kotha & Arjun S. Chavan. (2010) Design and Synthesis of Benzosultine-sulfone as a o -Xylylene Precursor via Cross-enyne Metathesis and Rongalite: Further Expansion to Polycyclics via Regioselective Diels−Alder Reaction . The Journal of Organic Chemistry 75:12, pages 4319-4322.
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Sambasivarao Kotha & Priti Khedkar. (2009) Differential Reactivity Pattern of Hybrid o -Quinodimethane Precursors: Strategic Expansion to Annulated Benzocycloalkanes via Rongalite . The Journal of Organic Chemistry 74:15, pages 5667-5670.
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Balaka Barkakaty, Yutaka Takaguchi & Sadao Tsuboi. (2007) New synthetic routes towards various α-fluorinated aryl ketones and their enantioselective reductions using baker's yeast. Tetrahedron 63:4, pages 970-976.
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Sambasivarao Kotha, Priti Khedkar & Arun Kumar Ghosh. (2005) Synthesis of Symmetrical Sulfones from Rongalite: Expansion to Cyclic Sulfones by Ring-Closing Metathesis. European Journal of Organic Chemistry 2005:16, pages 3581-3585.
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Gamal Giuglio-Tonolo, Thierry Terme, Maurice Médebielle & Patrice Vanelle. (2003) Original reaction of p-nitrobenzyl chloride with aldehydes using tetrakis(dimethylamino)ethylene (TDAE). Tetrahedron Letters 44:34, pages 6433-6435.
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William R DolbierJr.Jr., Maurice Médebielle & Samia Ait-Mohand. (2001) Single electron transfer approaches to the practical synthesis of aromatic and heterocyclic-CF2H derivatives. Tetrahedron Letters 42:29, pages 4811-4814.
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Donald C. Dittmer. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
Conrad Burkholder, William R DolbierJr.Jr., Maurice Médebielle & Samia Ait-Mohand. (2001) Synthesis and electron-transfer reactions of some 3-difluoroacetylated imidazo[1,2- a ]pyridine derivatives. Tetrahedron Letters 42:17, pages 3077-3080.
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Philippe Hapiot & Maurice Médebielle. (2001) Electrochemically induced free-radical tandem cyclisation of chlorodifluoromethylated ketones. Journal of Fluorine Chemistry 107:2, pages 285-300.
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R. Alan Jones. 2001. Quaternary Ammonium Salts. Quaternary Ammonium Salts 119 157 .
Cheng-Chien Wang, Jen-Feng Kuo & Chuh-Yung Chen. (2000) Polymerization of styrene initiated by a novel initiator sodium formaldehyde sulfoxylate and sodium lauryl sulfate. European Polymer Journal 36:5, pages 965-974.
Crossref
. 1995. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations 727 856 .
Kevin E.B. Parkes & Stewart K. Richardson. 1995. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations 111 204 .
Virendra Kumar, Patrick McCloskey & Malcolm R. Bell. (1994) Novel method for the preparation of monofluoroacetyl and difluoroacetylfuran derivatives. Tetrahedron Letters 35:6, pages 833-834.
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. 1992. Compendium of Organic Synthetic Methods. Compendium of Organic Synthetic Methods 219 229 .
B.J. Grady & D.C. Dittmer. (1990) Reaction of perfluoroaryl halides with reduced species of sulfur dioxide (HSO2− SO22−,S2O42−) [1]. Journal of Fluorine Chemistry 50:2, pages 151-172.
Crossref
A. R. HARRIS. (1988) ChemInform Abstract: Sodium Formaldehyde Sulfoxylate. An Efficient Reagent for the Reduction of α-Halo Ketones.. ChemInform 19:16.
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. 1988. Annual Reports in Organic Synthesis–1987. Annual Reports in Organic Synthesis–1987 259 290 .

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