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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 4
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Original Articles

4-Aza-N-Benzyl Bicyclo [2,2,2] Octyl Ammonium Borohydride a Highly Chemoselective Reagent for the Reduction of Aldehydes in the Presence of Ketones

H. Firouzabadi Chemistry Department, Shiraz University, Shiraz, Iran
&
G. R. Afsharifar Chemistry Department, Shiraz University, Shiraz, Iran
Pages 497-507 | Received 02 Aug 1991, Published online: 24 Sep 2006

Citations (18)

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Read on this site (6)

Abdol Reza Hajipour & Shadpour E. Mallakpour. (2001) BUTYLTRIPHENYLPHOSPHONIUM TETRAHYDROBORATE (BTPPTB) AS A SELECTIVE REDUCING AGENT FOR REDUCTION OF ORGANIC COMPOUNDS. Synthetic Communications 31:8, pages 1177-1185.
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Habib Firouzabadi, Bahman Tamami & Ali Reza Kiasat. (2000) EFFICIENT REDUCTION OF ORGANIC COMPOUNDS WITH SULFURATED CALCIUM BOROHYDRIDE [Ca(S3BH2)2], A NEW AND STABLE MODIFIED BOROHYDRIDE REAGENT. Phosphorus, Sulfur, and Silicon and the Related Elements 159:1, pages 99-108.
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A.R. Hajipour, S.E. Mallakpour & A.R. Najafi. (2000) Benzyltriphenylphosphonium Tetraborate (Btpptb) As A Selective Reducing Agent For Reduction Of Aldehydes And Ketones To The Corresponding Alcohols. Phosphorus, Sulfur, and Silicon and the Related Elements 165:1, pages 165-170.
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Habib Firouzabadi & Mina Adibi. (1998) METHYLTRIPHENYLPHOSPHONIUM TETRAHYDROBORATE (MePh3PBH4). A STABLE, SELECTIVE AND VERSATILE REDUCING AGENT. Phosphorus, Sulfur, and Silicon and the Related Elements 142:1, pages 125-147.
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H. Firouazabadi & M. Adibi. (1996) Modified Borohydride Agents1a-d Methyltriphenylphosphonium Tetrahydroborate; MePh3P+BH4 − as a Selective and An Efficient Reducing Agent. Synthetic Communications 26:13, pages 2429-2441.
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H. Firouzabadi & G.R. Afsharifar. (1996) Facile Deprotection of Trimethylsilyl Ethers With Modified Borohydride Agents; 1-Benzyl-4-AZA-1-Azoniabicyclo[2.2.2]Octane Tetrahydroborate (Baaotb)1 Versus Tetrabutylammonium Tetrahydroborate(TBATB). Synthetic Communications 26:6, pages 1065-1073.
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Articles from other publishers (12)

Moslem M. Lakouraj, Mahmood Tajbakhsh & Majid S. Mahalli. (2007) Ionene-Bound Borohydrides: Efficient, Selective, and Versatile Polymer-Supported Reducing Agents. Monatshefte für Chemie - Chemical Monthly 139:2, pages 117-123.
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Behzad Zeynizadeh & Tarifeh Behyar. (2005) Wet THF as a Suitable Solvent for a Mild and Convenient Reduction of Carbonyl Compounds with NaBH 4 . Bulletin of the Chemical Society of Japan 78:2, pages 307-315.
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Heshmatollah Alinezhad, Mahmood Tajbakhsh & Fatemeh Salehian. (2019) Reduction of acid chlorides using dichloro bis[(1,4-diaza bicyclo [2.2.2] octane) bis(tetrahydroborato)] zirconium (IV). Journal of Chemical Research 2004:12, pages 814-815.
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. (2003) A Mild and Convenient Method for the Reduction of Carbonyl Compounds with NaBH 4 in the Presence of Catalytic Amounts of MoCl 5 . Bulletin of the Korean Chemical Society 24:11, pages 1664-1670.
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Behzad Zeynizadeh & Karam Zahmatkesh. (2019) Mild and Convenient Method for Reduction of Aliphatic and Aromatic Carboxylic Acids and Anhydrides with (Pyridine)(Tetrahydroborato)Zinc Complex as a New Stable Ligand-Metal Tetrahydroborate Agent. Journal of Chemical Research 2003:8, pages 522-525.
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. (2003) (Pyridine)(tetrahydroborato)zinc Complex, [Zn(BH 4 ) 2 (py)], as a New Stable, Efficient and Chemoselective Reducing Agent for Reduction of Carbonyl Compounds . Bulletin of the Korean Chemical Society 24:4, pages 453-459.
Crossref
Behzad Zeynizadeh & Karam Zahmatkesh. (2013) First and Efficient Method for Reduction of Aliphatic and Aromatic Nitro Compounds with Zinc Borohydride as Pyridine Zinc Tetrahydroborato Complex: A New Stable Ligand‐Metal Borohydride. Journal of the Chinese Chemical Society 50:2, pages 267-271.
Crossref
. (2003) Mild and Efficient Reduction of α,β-Unsaturated Carbonyl Compounds, α-Diketones and Acyloins with Sodium Borohydride/Dowex1-x8 System. Bulletin of the Korean Chemical Society 24:3, pages 295-298.
Crossref
Behzad Zeynizadeh. (2003) Modified Hydroborate Agent: (2,2′-Bipyridyl)(tetrahydroborato)zinc Complex, [Zn(BH 4 ) 2 (bpy)], as a New, Stable, Efficient Ligand-Metal Hydroborate and Chemoselective Reducing Agent . Bulletin of the Chemical Society of Japan 76:2, pages 317-326.
Crossref
Habib Firouzabadi & Behzad Zeynizadeh. (1997) Modified Borohydride Agents, (1,4-Diazabicyclo[2.2.2]octane)(tetrahydroborato)zinc Complex [Zn(BH 4 ) 2 (dabco)]. A New Ligand Metal Borohydride as a Stable, Efficient, and Versatile Reducing Agent . Bulletin of the Chemical Society of Japan 70:1, pages 155-167.
Crossref
Habib Firouzabadi & Gholam Reza Afsharifar. (1995) Modified Borohydride Agents, 1-Benzyl-4-aza-1-azoniabicyclo[2.2.2]octane Tetrahydroborate (BAAOTB) versus Tetrabutylammonium Tetrahydroborate (TBATB). Efficient, Selective, and Versatile Reducing Agents. Bulletin of the Chemical Society of Japan 68:9, pages 2595-2602.
Crossref
H. FIROUZABADI & G. R. AFSHARIFAR. (2010) ChemInform Abstract: 4-Aza-N-benzylbicyclo(2.2.2)octylammonium Borohydride - a Highly Chemoselective Reagent for the Reduction of Aldehydes in the Presence of Ketones.. ChemInform 23:30, pages no-no.
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