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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 20
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Original Articles

Cerium-Catalyzed Selective Oxidation of Alkylbenzenes with Bromate Salts

Eyal Ganin Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel
&
Ibrahim Amer Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel
Pages 3149-3154 | Received 28 Mar 1995, Published online: 23 Sep 2006

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PraveenK. Tandon, PriyB. Dwivedi & Satpal Singh. (2009) Liquid-Phase Oxidation of Some Aromatic Aldehydes, Hydrocarbons, and Alcohols by Cerium(IV) Catalyzed by Iridium(III) in Acidic Medium. Synthetic Communications 39:11, pages 1920-1928.
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PraveenK. Tandon, Manish Srivastava, SantoshB. Singh & Nidhi Srivastava. (2008) Liquid-Phase and Solventless Oxidation of Cyclohexane, Benzene, and Other Hydrocarbons by Cerium(IV) Catalyzed by Iridium(III) in Acidic Medium. Synthetic Communications 38:18, pages 3183-3192.
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PraveenK. Tandon, Manish Srivastava, SantoshB. Singh & Satpal Singh. (2008) Liquid Phase and Microwave Assisted Oxidation of Some Hydrocarbons, Aromatic Aldehydes, and Phenols by Cerium(IV) Catalyzed by Iridium(III) in Acidic Medium. Synthetic Communications 38:13, pages 2125-2137.
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Ahmad Shaabani & Donald G. Lee. (2003) Cerium(III) Bromate as a New Reagent in Oxidation of Organic Compounds. Synthetic Communications 33:11, pages 1845-1854.
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William J. Crooks$suffix/text()$suffix/text(), Edward A. Kyser$suffix/text()$suffix/text() & Steven R. Walter. (2002) LOW TEMPERATURE EXOTHERMIC REACTION OF REILLEXTM HPQ IN NITRIC ACID. Solvent Extraction and Ion Exchange 20:4-5, pages 543-559.
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Rashid Badri & Mousa Soleymani. (2002) 3,6-BIS(TRIPHENYLPHOSPHONIUM) CYCLOHEXENE PEROXODISULFATE AS AN EFFICIENT AND MILD OXIDIZING AGENT FOR CONVERSION OF ALKYLBENZENES TO CORRESPONDING CARBONYL COMPOUNDS. Synthetic Communications 32:15, pages 2385-2389.
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Qi-Zeng Shi, Jian-Ge Wang & Kun Cai. (1999) Cerium Dioxide Catalyzed Oxidation of Alkylbenzenes with Sodium Bromate. Synthetic Communications 29:7, pages 1177-1181.
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Articles from other publishers (26)

Elavarasan Pavithra, Sathananthan Kannadasan & Ponnusamy Shanmugam. (2022) Synthesis of 5-aryl-3,3′-bis-indolyl and bis-7-aza-indolyl methanone derivatives from 5-bromo-7-azaindoles via sequential methylenation using microwave irradiation, CAN oxidation, and Suzuki coupling reactions . RSC Advances 12:47, pages 30712-30721.
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Meghdad Karimi, Haleh Mohebali, Samira Sadeghi, Vahid Safarifard, Alireza Mahjoub & Akbar Heydari. (2021) Additive-free aerobic C-H oxidation through a defect-engineered Ce-MOF catalytic system. Microporous and Mesoporous Materials 322, pages 111054.
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Kelvin Chen, Pei-Chun Liu, Tsun-Ren Chen & Jhy-Der Chen. (2018) Cyclometalated Iridium(III) Complexes Containing Benzoxazole Derivatives and Different Ancillary Ligands for Catalytic Oxidation of Toluene. Inorganics 6:4, pages 118.
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Tsun‐Ren Chen, Pei‐Chun Liu, Hsiu‐Pen Lee, Fang‐Siou Wu & Kelvin H. ‐C. Chen. (2017) Cyclometalated Iridium(III) Complexes with Ligand Effects on the Catalytic C–H Bond Activation of Toluene. European Journal of Inorganic Chemistry 2017:13, pages 2023-2031.
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Manish Srivastava, Ashu Goyal, Anamika Srivastava, Aakanksha Mishra & Preeti Tomar. (2016) AU(III) AND CU(II) CATALYST FOR OXIDATION OF AROMATIC AND CYCLIC HYDROCARBON BY CERIUM (IV) IN ACIDIC MEDIUM UNDER MICROWAVE IRRADIATION. Green Chemistry & Technology Letters 2:4, pages 199-205.
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Xiao‐Yi Yi, Guo‐Cang Wang, Ho‐Fai Ip, Wai‐Yeung Wong, Lizhuang Chen, Herman H. ‐Y. Sung, Ian D. Williams & Wa‐Hung Leung. (2014) Oxidation of Alkylbenzenes with Cerium Complexes Containing a Tripodal Oxygen Ligand. European Journal of Inorganic Chemistry 2014:35, pages 6097-6103.
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Aniruddha Ghosh, Rumpa Saha, Kakali Mukherjee, Pintu Sar, Sumanta K. Ghosh, Susanta Malik, Subhendu Sekhar Bhattacharyya & Bidyut Saha. (2014) Rate enhancement via micelle encapsulation for room temperature metal catalyzed Ce(IV) oxidation of p-chlorobenzaldehyde to p-chlorobenzoic acid in aqueous medium at atmospheric pressure. Journal of Molecular Liquids 190, pages 81-93.
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K. Ramesh, S. Shylaja, K. C. Rajanna, P. Giridhar Reddy & P. K. Saiprakash. (2013) Polyethylene Glycols as Efficient Media for Decarboxylative Nitration of α , β -Unsaturated Aromatic Carboxylic Acids by Ceric Ammonium Nitrate in Acetonitrile Medium: A Kinetic and Mechanistic Study . Advances in Physical Chemistry 2013, pages 1-12.
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Batool Akhlaghinia, Hossein Ebrahimabadi, Elaheh K. Goharshadi, Sara Samiee & Soodabeh Rezazadeh. (2012) Ceria nanoparticles as an efficient catalyst for oxidation of benzylic CH bonds. Journal of Molecular Catalysis A: Chemical 357, pages 67-72.
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Liang Wu Bi, Qiu Ge Zhang, Zhen Dong Zhao & Da Wei Li. (2011) Exploration of Chemical Oxidation of <i>p</i>-Cymene. Advanced Materials Research 396-398, pages 1132-1137.
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Peter Schmitt, Nadine Brem, Stephan Schunk & Claus Feldmann. (2011) Polyol-Mediated Synthesis and Properties of Nanoscale Molybdates/Tungstates: Color, Luminescence, Catalysis. Advanced Functional Materials 21:16, pages 3037-3046.
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Vellaisamy Sridharan & J. Carlos Menéndez. (2010) Cerium(IV) Ammonium Nitrate as a Catalyst in Organic Synthesis. Chemical Reviews 110:6, pages 3805-3849.
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Norihiro Tada, Kazunori Ban, Shin-ichi Hirashima, Tsuyoshi Miura & Akichika Itoh. (2010) Direct synthesis of α-bromoketones from alkylarenes by aerobic visible light photooxidation. Organic & Biomolecular Chemistry 8:20, pages 4701.
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Vijay Nair & Ani Deepthi. (2009) Recent advances in CAN mediated reactions in organic synthesis. Tetrahedron 65:52, pages 10745-10755.
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Karen Deleersnyder, Stijn Schaltin, Jan Fransaer, Koen Binnemans & Tatjana N. Parac-Vogt. (2009) Ceric ammonium nitrate (CAN) as oxidizing or nitrating reagent for organic reactions in ionic liquids. Tetrahedron Letters 50:32, pages 4582-4586.
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Mohammad Ghaffarzadeh, Mohammad Bolourtchian, Kourosh Tabar-Heydar, Iman Daryaei & Farshid Mohsenzadeh. (2009) H2O2-HBr: A metal-free and organic solvent-free reagent system for the synthesis of arylaldehydes from methylarenes. Journal of Chemical Sciences 121:2, pages 177-182.
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Ponnusamy Shanmugam, Vadivel Vaithiyanathan & Kodirajan Selvakumar. (2008) A mild and efficient CAN mediated oxidation of Morita–Baylis–Hillman adducts of 5-methyl-N-alkylisatin to 5-formyl-N-alkylisatin. Tetrahedron Letters 49:13, pages 2119-2123.
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Gopa Barman, Mahuya Roy & Jayanta. K. Ray. (2008) A novel synthetic approach towards N-phenylsuccinimides from γ-lactam-2-carboxylic acid derivatives by reaction with CAN–NaBrO3. Tetrahedron Letters 49:8, pages 1405-1407.
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Mohammad Ghaffarzadeh, Mohammad Bolourtchian, Maral Gholamhosseni & Farshid Mohsenzadeh. (2007) Synthesis of arylaldehydes: Br2/DMSO catalytic system for the chemoselective oxidation of methylarenes. Applied Catalysis A: General 333:1, pages 131-135.
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Vijay Nair & Ani Deepthi. (2007) Cerium(IV) Ammonium NitrateA Versatile Single-Electron Oxidant. Chemical Reviews 107:5, pages 1862-1891.
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Koen Binnemans. 2006. Handbook on the Physics and Chemistry of Rare Earths Volume 36. Handbook on the Physics and Chemistry of Rare Earths Volume 36 281 392 .
Monika Gupta, Satya Paul, Rajive Gupta & André Loupy. (2005) ZnO: a versatile agent for benzylic oxidations. Tetrahedron Letters 46:30, pages 4957-4960.
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André Lubineau & Jacques Augé. 1999. Modern Solvents in Organic Synthesis. Modern Solvents in Organic Synthesis 1 39 .
Paul A. GriecoF. Fringuelli, O. Piermatti & F. Pizzo. 1998. Organic Synthesis in Water. Organic Synthesis in Water 223 249 .
Kevin Auty, Bruce C. Gilbert, C.Barry Thomas, Scott W. Brown, Craig W. Jones & William R. Sanderson. (1997) The selective oxidation of toluenes to benzaldehydes by cerium(III), hydrogen peroxide and bromide ion. Journal of Molecular Catalysis A: Chemical 117:1-3, pages 279-287.
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E. GANIN & I. AMER. (2010) ChemInform Abstract: Cerium‐Catalyzed Selective Oxidation of Alkylbenzenes with Bromate Salts.. ChemInform 26:51.
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