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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 2
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Original Articles

Facile Synthesis of Steroidal Δ4-3,6-Diones from Δ5-3-Ols using Pyridinium Chlorochromate

A. Nangia School of Chemistry, University of Hyderabad Central University PO, Hyderabad, 500 046, India
&
A. Anthony School of Chemistry, University of Hyderabad Central University PO, Hyderabad, 500 046, India
Pages 225-230 | Received 15 May 1995, Published online: 21 Aug 2006

Citations (14)

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Jin Liu, Hong-You Zhu & Xiao-Hong Cheng. (2009) CrO3/NHPI Adsorbed on Activated Clay: A New Supported Reagent for Allylic Selective Oxidation of Δ5-Sterols. Synthetic Communications 39:6, pages 1076-1083.
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Articles from other publishers (13)

S. Priyadarshini, P. S. Guru, R. DS & S. Dash. (2019) Cr(VI) Oxidation of Cholesterol—A Kinetic Study Using N-Cetylpicolinium Dichromates, A Class of Novel Phase Transfer Oxidants. Kinetics and Catalysis 60:2, pages 147-154.
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Jianguo Cui, Lei Fan, Yanmin Huang, Yi Xin & Aimin Zhou. (2009) Synthesis and evaluation of some steroidal oximes as cytotoxic agents: Structure/activity studies (II). Steroids 74:12, pages 989-995.
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Thomas C. Wilde, Grzegorz Blotny & Ralph M. Pollack. (2008) Experimental Evidence for Enzyme-Enhanced Coupled Motion/Quantum Mechanical Hydrogen Tunneling by Ketosteroid Isomerase. Journal of the American Chemical Society 130:20, pages 6577-6585.
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Jun Dong, Wenxiang Chen, Shu Wang, Jiangtao Zhang, Hongxia Li, Hanbang Guo, Yong Man & Baosheng Chen. (2007) Jones oxidation and high performance liquid chromatographic analysis of cholesterol in biological samples. Journal of Chromatography B 858:1-2, pages 239-246.
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Iwona Skiera & Zdzisław Paryzek. (2007) Methyl Steroids. Studies on the Synthesis of 4-Methyl- and 4,4-Dimethyl-25-hydroxycholestan-3-one Derivatives. Collection of Czechoslovak Chemical Communications 72:10, pages 1319-1330.
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A. Christy Hunter & Shelley-Marie Priest. (2006) An efficient one-pot synthesis generating 4-ene-3,6-dione functionalised steroids from steroidal 5-en-3β-ols using a modified Jones oxidation methodology. Steroids 71:1, pages 30-33.
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Jun-Long Zhang & Chi-Ming Che. (2005) Dichlororuthenium(IV) Complex ofmeso-Tetrakis(2,6-dichlorophenyl)porphyrin: Active and Robust Catalyst for Highly Selective Oxidation of Arenes, Unsaturated Steroids, and Electron-Deficient Alkenes by Using 2,6-DichloropyridineN-Oxide. Chemistry - A European Journal 11:13, pages 3899-3914.
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Jian Guo Cui, Cui Wu Lin, Long Mei Zeng & Jing Yu Su. (2002) Synthesis of polyhydroxysterols (III): synthesis and structural elucidation of 24-methylenecholest-4-en-3β,6α-diol. Steroids 67:13-14, pages 1015-1019.
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Hideharu Seto, Shozo Fujioka, Suguru Takatsuto, Hiroyuki Koshino, Takeshi Shimizu & Shigeo Yoshida. (2000) Synthesis of 6-oxy functionalized campest-4-en-3-ones: efficient hydroperoxidation at C-6 of campest-5-en-3-one with molecular oxygen and silica gel. Steroids 65:8, pages 443-449.
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James R. Hanson & Ismail Kiran. (2019) The Oxidation of Some Steroidal Dienes and Trienes with Chromic Acid. Journal of Chemical Research 23:10, pages 594-595.
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Sheng-Hui Li & Tong-Shuang Li. (1998) Steroidal 5-en-3-ones, intermediates of the transformation of steroidal 5-en-3β-ols to steroidal 4-en-3,6-diones oxidized by pyridinium dichromate and pyridinium chlorochromate. Steroids 63:2, pages 76-79.
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James R. Hanson. (1998) Steroids: reactions and partial synthesis. Natural Product Reports 15:3, pages 261.
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A. NANGIA & A. ANTHONY. (2010) ChemInform Abstract: Facile Synthesis of Steroidal δ4‐3,6‐Diones from δ5‐3‐Ols Using Pyridinium Chlorochromate.. ChemInform 27:23.
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