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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 13
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Original Articles

Modified Borohydride Agents1a-d Methyltriphenylphosphonium Tetrahydroborate; MePh3P+BH4− as a Selective and An Efficient Reducing Agent

H. Firouazabadi Department of Chemistry, Shiraz University, Shiraz, 71454, Iran
&
M. Adibi Department of Chemistry, Shiraz University, Shiraz, 71454, Iran
Pages 2429-2441 | Received 31 Dec 1995, Published online: 23 Aug 2006

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Habib Firouzabadi & Mina Adibi. (1998) METHYLTRIPHENYLPHOSPHONIUM TETRAHYDROBORATE (MePh3PBH4). A STABLE, SELECTIVE AND VERSATILE REDUCING AGENT. Phosphorus, Sulfur, and Silicon and the Related Elements 142:1, pages 125-147.
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H. Firouzabadi, M. Adibi & B. Zeynizadeh. (1998) Modified Borohydride Agents; Efficient Reduction of Azides with (1,4-Diazabicyclo[2.2.2]octane) (Tetrahydroborato)zinc Complex [Zn(BH4)2(dabco)] and Methyltriphenylphosphonium Tetrahydroborate [MePh3P+BH4 −]. Synthetic Communications 28:7, pages 1257-1273.
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Articles from other publishers (16)

Seyed Reza Nokhbeh, Mostafa Gholizadeh, Alireza Salimi, Behnaz Delaram & Faezeh Makari. (2021) Synthesis, crystal and structural characterization, Hirshfeld surface analysis and DFT calculations of three symmetrical and asymmetrical phosphonium salts. Journal of Molecular Structure 1242, pages 130718.
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Richard C. LarockRichard C. Larock & Cristiano Raminelli. 2018. Comprehensive Organic Transformations. Comprehensive Organic Transformations 1 69 .
Davood Setamdideh, Zahra Karimi & Avat Alipouramjad. (2013) NaBH 4 /DOWEX(R)50WX4: A Convenient Reducing System for Fast and Efficient Reduction of Carbonyl Compounds to Their Corresponding Alcohols . Journal of the Chinese Chemical Society 60:6, pages 590-596.
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Mina Mohamadi, Davood Setamdideh & Behrooz Khezri. (2013) Regioselective and Chemoselective Reduction of , -Unsaturated Carbonyl Compounds by /Ba as a Reducing System . Organic Chemistry International 2013, pages 1-5.
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Behzad Zeynizadeh & Mehri Kouhkan. (2011) A Rapid and Practical Protocol for Solvent-Free Reduction of Oximes to Amines with NaBH 4 /ZrCl 4 /Al 2 O 3 System . Bulletin of the Korean Chemical Society 32:9, pages 3448-3452.
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M. Reza Naimi‐Jamal, Javad Mokhtari, Mohammad G. Dekamin & Gerd Kaupp. (2009) Sodium Tetraalkoxyborates: Intermediates for the Quantitative Reduction of Aldehydes and Ketones to Alcohols through Ball Milling with NaBH 4 . European Journal of Organic Chemistry 2009:21, pages 3567-3572.
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Behzad Zeynizadeh. (2005) Titanyl Acetylacetonate as an Efficient Catalyst for Regioselective 1,2-Reduction of α,β-Unsaturated Carbonyl Compounds and Conversion of α-Diketones & Acyloins to Vicinal Diols with Sodium Borohydride. Journal of the Chinese Chemical Society 52:3, pages 525-530.
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Behzad Zeynizadeh & Tarifeh Behyar. (2005) Wet THF as a Suitable Solvent for a Mild and Convenient Reduction of Carbonyl Compounds with NaBH4. Bulletin of the Chemical Society of Japan 78:2, pages 307-315.
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. (2003) A Mild and Convenient Method for the Reduction of Carbonyl Compounds with NaBH 4 in the Presence of Catalytic Amounts of MoCl 5 . Bulletin of the Korean Chemical Society 24:11, pages 1664-1670.
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Behzad Zeynizadeh & Karam Zahmatkesh. (2019) Mild and Convenient Method for Reduction of Aliphatic and Aromatic Carboxylic Acids and Anhydrides with (Pyridine)(Tetrahydroborato)Zinc Complex as a New Stable Ligand-Metal Tetrahydroborate Agent. Journal of Chemical Research 2003:8, pages 522-525.
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. (2003) (Pyridine)(tetrahydroborato)zinc Complex, [Zn(BH 4 ) 2 (py)], as a New Stable, Efficient and Chemoselective Reducing Agent for Reduction of Carbonyl Compounds . Bulletin of the Korean Chemical Society 24:4, pages 453-459.
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. (2003) Mild and Efficient Reduction of α,β-Unsaturated Carbonyl Compounds, α-Diketones and Acyloins with Sodium Borohydride/Dowex1-x8 System. Bulletin of the Korean Chemical Society 24:3, pages 295-298.
Crossref
Behzad Zeynizadeh. (2003) Modified Hydroborate Agent: (2,2′-Bipyridyl)(tetrahydroborato)zinc Complex, [Zn(BH4)2(bpy)], as a New, Stable, Efficient Ligand-Metal Hydroborate and Chemoselective Reducing Agent. Bulletin of the Chemical Society of Japan 76:2, pages 317-326.
Crossref
Michael B. Smith. 2002. Compendium of Organic Synthetic Methods. Compendium of Organic Synthetic Methods 12 44 .
N. J. Lawrence. (1997) Chapter 8. Synthetic methods. Annual Reports Section "B" (Organic Chemistry) 93, pages 249.
Crossref
H. FIROUAZABADI & M. ADIBI. (2010) ChemInform Abstract: Modified Borohydride Agents. Methyltriphenylphosphonium Tetrahydroborate: MePh3P+BH‐ 4 as a Selective and Efficient Reducing Agent.. ChemInform 27:39.
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