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Original Articles

Preparations of Cyclopentadienylruthenium Complexes with Trimethylphosphine Ligands

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Pages 205-218 | Received 19 Nov 1979, Accepted 26 Dec 1979, Published online: 03 Jan 2007

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P.M. Treichel, D.A. Komar & P.J. Vincenti. (1984) Preparation of Several Homologous Series of Cyclopentadienylruthenium Complexes and Their Solvolysis in Polar Solvents. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 14:3, pages 383-400.
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Articles from other publishers (33)

Duy-Khoi Dang, Damla Cehreli, Benjamin S. Rich, Terry E. Haas, Frank R. Fronczek & Rein U. Kirss. (2023) Phosphine substitution and linkage isomerization in cyclopentadienylruthenium bis(triphenylphosphine)thiocyanide and selenocyanide, CpRu(PPh 3 ) 2 NCS and CpRu(PPh 3 ) 2 SeCN . Dalton Transactions.
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Lukas Hintermann. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis 1 7 .
Josef B. G. Gluyas, Neil J. Brown, Julian D. Farmer & Paul J. Low. (2017) Optimised Syntheses of the Half-Sandwich Complexes FeCl(dppe)Cp*, FeCl(dppe)Cp, RuCl(dppe)Cp*, and RuCl(dppe)Cp. Australian Journal of Chemistry 70:1, pages 113.
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David Hill, Connor Delaney, Miles Clark, Mathew Eaton, Bakar Hassan, Olivia Hendricks, Duy Khoi Dang & Rein U. Kirss. (2017) Kinetics of phosphine substitution in CpRu(PPh 3 ) 2 X (X = Cl, Br, I, N 3 , and NCO) . RSC Advances 7:55, pages 34425-34434.
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Michael J. Verschoor-Kirss, Olivia Hendricks, Lawrence Renna, David Hill & Rein U. Kirss. (2014) Phosphine substitution reactions of (η 5 -cyclopentadienyl)ruthenium bis(triarylphosphine) chloride, CpRu(PAr 3 ) 2 Cl {PAr 3 = PPh 3 , P(p-CH 3 C 6 H 4 ) 3 , P(p-FC 6 H 4 ) 3 , P(p-CH 3 OC 6 H 4 ) 3 , and PPh 2 (p-CH 3 C 6 H 4 )}: a tale of two mechanisms . Dalton Trans. 43:40, pages 15221-15227.
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Bruno Therrien, Trieu-Tien Thai, Julien Freudenreich, Georg Süss-Fink, Sergey S. Shapovalov, Alexandr A. Pasynskii & Laurent Plasseraud. (2010) Bimetallic ruthenium–tin chemistry: Synthesis and molecular structure of arene ruthenium complexes containing trichlorostannyl ligands. Journal of Organometallic Chemistry 695:3, pages 409-414.
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Man Lok Man, King Chung Lam, Wing Nga Sit, Siu Man Ng, Zhongyuan Zhou, Zhenyang Lin & Chak Po Lau. (2006) Synthesis of Heterobimetallic RuMn Complexes and the Coupling Reactions of Epoxides with Carbon Dioxide Catalyzed by these Complexes. Chemistry – A European Journal 12:4, pages 1004-1015.
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Maxim V. Ovchinnikov, Arkady M. Ellern, Ilia A. Guzei & Robert J. Angelici. (2001) Reactions of the Protonated Dinuclear Ruthenium Complex [{( η 5 -C 5 H 3 ) 2 (SiMe 2 ) 2 }Ru 2 (CO) 4 ( μ -H)] + with Nucleophiles . Inorganic Chemistry 40:27, pages 7014-7019.
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Samuel T. N. Freeman, Frederick R. Lemke, Christopher M. Haar, Steven P. Nolan & Jeffrey L. Petersen. (2000) Effect of Ancillary Ligation on the Relative Bond Disruption Enthalpies of Ru−H and Ru−Cl Bonds in Cp(PR 3 ) 2 RuX (PR 3 = PMe 3 , PMe 2 Ph, PMePh 2 , PPh 3 ; X = H, Cl) . Organometallics 19:23, pages 4828-4833.
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Taku Katayama, Kiyotaka Onitsuka & Shigetoshi Takahashi. (2000) Multiple ligand transfer reaction between [CpRu(L)(AN)2][PF6] (L=AN, CO, P(OMe)3; AN=acetonitrile) and CpFe(CO)L′X (L′=CO, PMe3, PMe2Ph, PMePh2, PPh3, P(OPh)3; X=Cl, Br, I). Journal of Organometallic Chemistry 610:1-2, pages 31-37.
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Li Fan, Frederick W. B. Einstein & Derek Sutton. (2000) Ruthenium Cyclopentadienyl Aryldiazenido Complexes. Synthesis of [Cp‘Ru(PR 3 ) 2 (N 2 C 6 H 4 OMe)][BF 4 ] 2 and [Cp‘RuCl(PPh 3 )(N 2 C 6 H 4 OMe)][BF 4 ] (Cp‘ = Cp, Cp*) and X-ray Crystal Structure of [CpRu(PPh 3 ) 2 (N 2 C 6 H 4 OMe)][BF 4 ] 2 , an Aryldiazenido Complex with a Large N−N−C(aryl) Angle and Near-Linear Ru−N−N−C(aryl) Skeleton . Organometallics 19:4, pages 684-694.
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M. Rakowski DuBois, K. G. Parker, C. Ohman & B. C. Noll. (1997) Nucleophilic Substitution of η 5 -Pyrrolyl Ligands in Ruthenium(II) Complexes . Organometallics 16:11, pages 2325-2334.
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Matthias Tamm, Thomas Jentzsch & Wolfgang Werncke. (1997) Ruthenium(II) Complexes with (2,4,6-Cycloheptatrien-1-ylidene)ethenylidene Ligands:  Strongly Polarized Allenylidene Complexes. Organometallics 16:7, pages 1418-1424.
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K Mohan Rao & U C Agarwala. (1996) Reactions ofη 5-cyclopentadienylruthenium(II) complexes withγ-hydroxyacetylenes. Proceedings / Indian Academy of Sciences 108:4.
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Frederick R. Lemke, Richard S. Simons & Wiley J. Youngs. (1996) (η 1 -Pentamethylcyclopentadienyl)silyl Complexes of Ruthenium. Preparation, Reactivity, and X-ray Crystal Structure of Cp(PMe 3 ) 2 RuSiCl 2 (η 1 -Cp*) . Organometallics 15:1, pages 216-221.
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Martin A. Bennett, Karl Khan & Eric Wenger. 1995. Comprehensive Organometallic Chemistry II. Comprehensive Organometallic Chemistry II 473 548 .
W.M. Laidlaw & R.G. Denning. (1993) Synthesis, characterization and electrochemistry of cyclopentadienyl phosphine nitrosyl cyanide complexes of ruthenium(II) and osmium(II). Preparation of the dicyano ruthenium(II) complex, [(η5-C5H5) Ru(PPh3)(CN)2]Na. Journal of Organometallic Chemistry 463:1-2, pages 199-204.
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M. J. Newlands. 1991. Inorganic Reactions and Methods. Inorganic Reactions and Methods 290 293 .
Fiona M. Conroy-Lewis, Alan D. Redhouse & Stephen J. Simpson. (1990) Synthesis and crystal structure of the six-coordinate ruthenium nitrosyl complex [(η5-C5H5)Ru(PPh3)(NO)(Cl)]PF6. Journal of Organometallic Chemistry 399:3, pages 307-315.
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David C. Miller & Robert J. Angelici. (1990) Electrophilic and nucleophilic reactions of complexes formed from 2,5-dithiahex-3-yne (MeSCCSMe) and tungsten carbonyls. Journal of Organometallic Chemistry 394:1-3, pages 235-250.
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Neil G. Connelly, Andrew C. Loyns, Ian Manners, David L. Mercer, Karen E. Richardson & Philip H. Rieger. (1990) Reduction–oxidation properties of organotransition-metal complexes. Part 31. Reductive elimination, oxidative addition and substitution, and migratory insertion in pentaphenylcyclopentadienylruthenium nitrosyl chemistry. J. Chem. Soc., Dalton Trans.:8, pages 2451-2458.
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Herbert Lehmkuhl, Marita Bellenbaum, Jürgen Grundke, Heiko Mauermann & Carl Krüger. (2006) HC‐Bindungsspaltungen durch (η 5 ‐Cyclopentadienyl)bis‐(triorganophosphan)rutheniumorganyl‐Komplexe . Chemische Berichte 121:10, pages 1719-1728.
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Kollipara Mohan Rao, Lallan Mishra & Umesh Chandra Agarwala. (1987) Substitution reaction of η5-cyclopentadienylruthenium(II) complexes with nitrogen, oxygen and sulfur donor ligands. Polyhedron 6:6, pages 1383-1390.
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Nicholas C. Thomas. (1986) Substituted ruthenium carbonyl halides. Coordination Chemistry Reviews 70, pages 121-156.
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R.F.N. Ashok, M. Gupta, K.S. Arulsamy & U.C. Agarwala. (1985) Cyclopentadienyl ruthenium complexes. Part I. Reactivity of some η5-cyclopentadienylbistriphenylphosphineruthenium(II) complexes with N-donor heterocyclic ligands. Inorganica Chimica Acta 98:3, pages 161-167.
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J. E. Macintyre, D. J. Cardin, S. A. Cotton, R. J. Cross, M. Green, P. G. Harrison, G. R. Knox, R. Lalanandham, J. B. Leach, A. McKillop, J. D. Smith, K. Smith, A. C. Sullivan, B. J. Wakefield, D. R. M. Walton, J. L. Wardell & C. White. 1985. Dictionary of Organometallic Compounds. Dictionary of Organometallic Compounds 278 311 .
Neil J. Coville & Elizabeth A. Darling. (1984) Metal dimers as catalysts. Journal of Organometallic Chemistry 277:1, pages 105-111.
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P.M. Treichel, D.A. Komar & P.J. Vincenti. (1984) Electron rich complexes: rates of halide ion solvolysis in RuX(L)2(η-C5H5 as a function of ligand. Inorganica Chimica Acta 88:2, pages 151-152.
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R. Usón, L.A. Oro, M.A. Ciriano, M.M. Naval, M.C. Apreda, C. Foces-Foces, F.H. Cano & S. Garcia-Blanco. (1983) Cyclopentadienylruthenium complexes with chelating diamines and diolefins. Crystal structures of [Ru(nbd)(PPh3)(ϑ-C5H5)]ClO4 and [Ru{(η6-C6H5)Ph2PO}(η-C5H5)]ClO4. A new mode of coordination of triphenylphosphine oxide. Journal of Organometallic Chemistry 256:2, pages 331-347.
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K.R. Seddon. (1982) Ruthenium. Coordination Chemistry Reviews 41, pages 79-157.
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M.A. Bennett, M.I. Bruce & T.W. Matheson. 1982. Comprehensive Organometallic Chemistry. Comprehensive Organometallic Chemistry 691 820 .
P.M. Treichel & D.A. Komar. (1981) New cyclopentadienyliron trimethylphosphine complexes. Journal of Organometallic Chemistry 206:1, pages 77-88.
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P.M. Treichel & D.A. Komar. (1980) Syntheses of olefin and acetylene complexes, [Ru(C5H5)(PMe3)2(un)]PF6. Inorganica Chimica Acta 42, pages 277-280.
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