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Journal of Coordination Chemistry Volume 55, 2002 - Issue 5
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Original Articles

Synthesis, Spectroscopic and Electrochemical Studies of Isomeric Dichloro-bis-[ N (1)-Alkyl-2-(Arylazo)Imidazole]-Osmium(II). Single Crystal X-ray Structures of Blue-Violet Dichloro-Bis-[ N (1)-Methyl-2-(Arylazo)Imidazole]-Osmium(II) Species

P. Byabartta Department of Chemistry, The University of Burdwan, Burdwan, 713 104, India
,
S. Pal Department of Chemistry, The University of Burdwan, Burdwan, 713 104, India
,
T.K. Misra Department of Chemistry, The University of Burdwan, Burdwan, 713 104, India
,
C. Sinha Department of Chemistry, The University of Burdwan, Burdwan, 713 104, India
,
F.-L. Liao Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan
,
K. Panneerselvam Department of Physics, National Tsing Hua University, Hsinchu, Taiwan
&
T.-H. LU Department of Physics, National Tsing Hua University, Hsinchu, Taiwan
 show all
Pages 479-496 | Published online: 15 Sep 2010

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Pei Peng, Lei Luo & Yong Wang. (2022) Synthesis and spectroscopic properties of osmium based polypyridyl compound, cis-OsII(phen)2Cl2, and its one-electron oxidation product [cis-OsIII(phen)2Cl2](PF6). Journal of Coordination Chemistry 75:19-24, pages 2582-2591.
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J. Dinda, S. Pal, B.K. Ghosh, C. Sinha, J. Cheng, F.-L. Liao & T.-H. Lu. (2002) Synthesis, Spectra and Electrochemistry of Isomeric DichloroBis-[1-Alkyl-2-(Naphthyl-(α/β)-Azo)Imidazole]Osmium(II): Single Crystal X-Ray Structure of Blue-Violet DichloroBis-[1-Ethyl-2-(Naphthyl-α-Azo) Imidazole]Osmium(II). Journal of Coordination Chemistry 55:11, pages 1271-1281.
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Articles from other publishers (36)

Soumendranath Nandi, Kuheli Das, Amitabha Datta, Suman Roy, Eugenio Garribba, Takashiro Akitsu & Chittaranjan Sinha. (2017) A rare cobalt(III) paramagnetic derivative incorporating 1-alkyl-2-[(o-thioalkyl)phenylazo]imidazole (SMeaaiNEt): EPR, redox and magnetic interpretation. Inorganica Chimica Acta 462, pages 75-81.
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Mousa Al-Noaimi, Obadah S. Abdel-Rahman, Ismail I. Fasfous, Mohammad El-khateeb, Firas F. Awwadi & Ismail Warad. (2014) Ruthenium(II) bipyridine complexes bearing quinoline–azoimine (NN′N″) tridentate ligands: Synthesis, spectral characterization, electrochemical properties and single-crystal X-ray structure analysis. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 125, pages 375-383.
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Yong Wang, Xiao Ma, Shengmin Hu, Yuehong Wen, Zhenzhen Xue, Xiaoquan Zhu, Xudong Zhang, Tianlu Sheng & Xintao Wu. (2014) Syntheses, crystal structures, MMCT and magnetic properties of four one-dimensional cyanide-bridged complexes comprised of M II –CN–Fe III (M = Fe, Ru, Os) . Dalton Trans. 43:46, pages 17453-17462.
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Mamdouh Saad Masoud, Ekram Abd El-Moniem Khalil, Saeda Abou El-Thana Abou El Enein & Hesham Mostafa Kamel. (2011) Solvatochromism and potentiometic studies of some active nitroso- and nitroso-azo- compounds. European Journal of Chemistry 2:3, pages 420-432.
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Avijit Pramanik & Gopal Das. (2010) Aryl azo imidazole assisted self-assembly of d10 metal complexes: Influence of halogen substitution and counter ions. Polyhedron 29:15, pages 2999-3007.
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K.K. Sarker, S. Saha Halder, D. Banerjee, T.K. Mondal, A.R. Paital, P.K. Nanda, P. Raghavaiah & C. Sinha. (2010) Copper–thioarylazoimidazole complexes: Structures, photochromism and redox interconversion between Cu(II)↔Cu(I) and correlation with DFT calculation. Inorganica Chimica Acta 363:12, pages 2955-2964.
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G. Saha, K.K. Sarkar, P. Datta, P. Raghavaiah & C. Sinha. (2010) Synthesis, spectroscopic properties, structural characterization and electrochemistry of mixed ligand complexes of copper(I) halide with PPh3 and naphthylazoimidazole. Polyhedron 29:9, pages 2098-2104.
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Avijit Pramanik, Subhojit Majumdar & Gopal Das. (2010) Aryl azo imidazoles assisted assembly of anion/anion–water through salt formation. CrystEngComm 12:1, pages 250-259.
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P. Byabartta. (2009) Ruthenium azo complexes: Synthesis, spectra, and electrochemistry of dithiocyanato-bis{1-(alkyl)-2-(arylazo)imidazole}ruthenium(II). Russian Journal of Coordination Chemistry 35:9, pages 687-691.
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Avijit Pramanik & Gopal Das. (2008) Molecular to Supramolecular Structure: Influence of Coordination Environment in Azo-dye Complexes. Crystal Growth & Design 8:8, pages 3107-3113.
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P. Byabartta. (2011) Ruthenium(II) phenylazopyridinearylazoimidazoles: Synthesis, spectral studies and redox properties. Russian Journal of Coordination Chemistry 34:3, pages 220-224.
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Prithwiraj Byabartta. (2007) Heteroleptic tris-chelates of ruthenium(II): Synthesis, spectral characterisation and electrochemical properties. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 66:3, pages 521-533.
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T.K. Mondal, T. Mathur, A.M.Z. Slawin, J.D. Woollins & C. Sinha. (2007) Imidazole→imidazolidine. Preparation by reduction of with NaBH4 and characterisation of the products (PyaiR=1-alkyl-2-{3′-(pyridylazo)}imidazole). Journal of Organometallic Chemistry 692:7, pages 1472-1481.
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T.K. Mondal, Joydev Dinda, Alexandra M.Z. Slawin, J. Derek Woollins & C. Sinha. (2007) Osmium-carbonyl complexes of naphthylazoimidazoles. Single crystal X-ray structure of [Os(H)(CO)(PPh3)2(α-NaiEt)](PF6) {α-NaiEt=1-ethyl-2-(naphthyl-α-azo)imidazole}. Polyhedron 26:3, pages 600-606.
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P. Bhuina, U.S. Ray, G. Mostafa, J. Ribas & C. Sinha. (2006) One-dimensional azido bridge [1-ethyl-2-(phenylazo)imidazole]manganese(II): Structure of low bridge angle system and magnetism. Inorganica Chimica Acta 359:14, pages 4660-4666.
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Umasankar Ray, Kamal Krishna Sarker, Golam Mostafa, Tian-Huey Lu, M. Salah El Fallah & Chittaranjan Sinha. (2006) Copper(II) azide complexes of 1-alkyl-2-(arylazo)imidazoles: Structure and magnetism. Polyhedron 25:14, pages 2764-2772.
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Sushanta Saha, Prodyut Kumar Sarkar & Ambikesh Mahapatra. (2006) Kinetics and Mechanism of the Reactions of Picolinic Acid with Dichloro-{1-alkyl-2-(arylazo)imidazole}palladium(II) Complexes. Transition Metal Chemistry 31:3, pages 389-395.
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J. Dinda, S. Senapoti, T. Mondal, A.D. Jana, M.Y. Chiang, T.-H. Lu & C. Sinha. (2006) Synthesis, spectral characterisation, and electrochemistry of bis-(2,2′-bipyridine)(1-alkyl-2-(naphthylazo)imidazole)ruthenium(II) complexes: X-ray crystal structure of [bis-(2,2′-bipyridine)-{1-ethyl-2-(naphthyl-α-azo)imidazole}ruthenium(II) perchlorate. Polyhedron 25:5, pages 1125-1132.
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Prithwiraj Byabartta. (2006) Sulphur-bridged ruthenium – molybdenum complexes: [(R-aapm)2Ru(μ-S)2Mo(OH)2]. Synthesis, spectroscopic and electro-chemical characterization. R-AAPM = 2-(arylazo)pyrimidine. Journal of Chemical Sciences 118:2, pages 171-177.
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Kamal Krishna Sarker, Brojo Gopal Chand, Atish Dipankar Jana, Golam Mostafa & Chittaranjan Sinha. (2006) Cd(II)–NCS/NCO complexes of 1-alkyl-2-(arylazo)imidazole: Single crystal X-ray structure of [Cd(HaaiMe)2(SCN)2]. Inorganica Chimica Acta 359:2, pages 695-700.
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Prithwiraj Byabartta. (2005) Ruthenium-mediated Selective Aromatic Thiolation in the Complex [RuII{o-S—C6H4-(p-R-)—N=N—C3H2NN(1)—R′}2]. Synthesis, Spectroscopic, e.p.r., Electro-chemical Characterization and Spectro-electrochemical Correlation. Transition Metal Chemistry 30:8, pages 978-986.
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Sk. Jasimuddin, Tanmoy Mathur & Chittaranjan Sinha. (2005) Bis-chelated-arylazoimidazole-1,10-phenanthroline–osmium(II) complexes. Structure, spectra and electrochemistry. Inorganica Chimica Acta 358:13, pages 3601-3609.
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Prithwiraj Byabartta. (2005) Reaction of BSA, CT-DNA, Adenine and Guanine with [Pt(RaaiR′)Cl2] and Characterization of the Products [Pt(RaaiR′)(NB)(H2O)](PF6)2] [RaaiR′=1-alkyl-2-(arylazo)imidazole]. Transition Metal Chemistry 30:6, pages 751-757.
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Prithwiraj Byabartta. (2005) A novel series of sulphur-bridged ruthenium-molybdenum complexes: [(RaaiR′)2 Ru(μ-S)2Mo(OH)2]. Synthesis, spectroscopic and electrochemical characterization. RaaiR′=1-alkyl-2-(arylazo) imidazole. Transition Metal Chemistry 30:5, pages 575-581.
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Umasankar Ray, Debasis Banerjee, Jian-Cheng Liou, Chun-Nan Lin, Tian-Huey Lu & Chittaranjan Sinha. (2005) Iron(II) and nickel(II)-thiocyanato complexes of 1-alkyl-2-(arylazo)imidazole: single crystal X-ray structure of [Fe(MeaaiEt)2(NCS)2] (MeaaiEt=1-ethyl-2(p-tolylazo)imidazole) and [Ni(MeaaiMe)(NCS)2(H2O)2]·2DMF (MeaaiMe=1-methyl-2(p-tolylazo)imidazole). Inorganica Chimica Acta 358:4, pages 1019-1026.
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Brojogopal Chand, Umasankar Ray, Golam Mostafa, Tian-Huey Lu & Chittaranjan Sinha. (2004) 2D Extended supramolecular structures via π–π interactions of 1D coordination polymers of cadmium(II) complexes of arylazoimidazole using azido and thiocyanato bridging ligands. Polyhedron 23:10, pages 1669-1676.
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Sk Jasimuddin, G Mostafa & C Sinha. (2004) Mixed ligand complexes of osmium(II)-2,2′-bipyridine: synthesis, spectral characterization and electrochemical properties of bis-chelated-arylazoimidazole-bipyridine-osmium(II) and X-ray crystal structure of [(2,2′-bipyridine)-bis-{1-methyl-2-(p-tolylazo)imidazole}osmium(II) hexafluorophosphate. Inorganica Chimica Acta 357:7, pages 1975-1984.
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Sk. Jasimuddin, P. Byabartta, G. Mostafa, T.-H. Lu & C. Sinha. (2004) Synthesis, spectral studies, crystal structure and redox properties of homoleptic tris-chelated ruthenium(II)-arylazoimidazoles. Polyhedron 23:5, pages 727-733.
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B.G Chand, U.S Ray, G Mostafa, Tian-Huey Lu, Lawrence R Falvello, Tatiana Soler, Milagres Tomás & C Sinha. (2003) Anion-directed structural diversity in the complexes of Cd(II)-arylazoimidazole: synthesis, spectral characterization and crystal structure. Polyhedron 22:24, pages 3161-3169.
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Martin N Ackermann, Marisa P Robinson, Ian A Maher, Eric B LeBlanc & Richard V Raz. (2003) Synthesis and characterization of cis-Mo(CO)4(L–L′) and cis-Mo(CO)2(L–L′)2 complexes of N(1)-methyl-2-(arylazo)imidazoles (L–L′). Correlations of spectroscopic data with substituent effects. Journal of Organometallic Chemistry 682:1-2, pages 248-254.
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Umasankar Ray, Brojogopal Chand, Golam Mostafa, Jack Cheng, Tian-Huey Lu & Chittaranjan Sinha. (2003) Mono- and binuclear cobalt(II)-azido complexes of arylazoimidazole: synthesis, spectral characterization, electrochemistry and crystal structure. Polyhedron 22:18, pages 2587-2594.
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U. S. Ray, D. Banerjee & C. Sinha. (2003) Synthesis, spectral characterization and redox properties of iron (II) complexes of 1-alkyl-2-(arylazo)imidazole. Journal of Chemical Sciences 115:3, pages 169-174.
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B.G. Chand, U.S. Ray, J. Cheng, T.-H. Lu & C. Sinha. (2003) Studies on the zinc(II)-azoimine system. Single-crystal X-ray structure of Zn(MeaaiMe)Cl2·H2O and Zn(HaaiMe)2(NCS)2 (MeaaiMe=1-methyl-2-(p-tolylazo)imidazole, HaaiMe=1-methyl-2-(phenylazo) imidazole). Polyhedron 22:9, pages 1213-1219.
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P. Byabartta, S.K. Jasimuddin, G. Mostafa, T.-H. Lu & C. Sinha. (2003) The synthesis, spectral studies and electrochemistry of 1,10-(phenanthroline)-bis-{1-alkyl-2-(arylazo)imidazole}ruthenium(II) perchlorate. Single crystal X-ray structure of [Ru(phen)(HaaiMe)2](ClO4)2 [phen=1,10-phenanthroline, HaaiMe=1-methyl-2-(phenylazo)imidazole]. Polyhedron 22:6, pages 849-859.
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Suman Sengupta, Indranil Chakraborty & Animesh Chakravorty. (2003) New Rhenium( I ) and Rhenium( II ) Species Assembled by Stereospecific Azopyridine Chelation . European Journal of Inorganic Chemistry 2003:6, pages 1157-1160.
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Yong Wang. (2022) Synthesis and Spectroscopic Properties of Osmium Based Polypyridyl Compound Cis-Osii(Phen)2cl2 and its One-Electron Oxidation Product [Cis-Osiii(Phen)2cl2](Pf6). SSRN Electronic Journal.
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