pH-dependent assembly of saturated to dilacunary Keggin-based silicotungstate: [Cu(en)₂(H₂O)][H₂en]{γ-SiW₁₀O₃₆[Cu(en)₂(H₂O)]₂}·7.5H₂O

Lei Yang Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, P.R. China; The Department of Physics-Chemistry, Henan Polytechnic University, Jiaozuo, P.R. China

Lili Hou Pharmaceutical College, Henan University, Kaifeng, P.R. China

Pengtao Ma Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, P.R. China

Jingyang Niu Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, P.R. ChinaCorrespondence[email protected]

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Hanxi Xiao, Yuzhe Han, Qian Fang, Qing Cai & Qian Deng. (2015) An inorganic-organic hybrid supramolecular complex (H3O)4[(CoC14H12N2O10)1.5(SiW12O40)]·2H2O: synthesis, structure, properties, and application to catalytic elimination methanol. Journal of Coordination Chemistry 68:15, pages 2587-2600.
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Wei-Qiu Kan, Ji-Ming Xu, Yu-He Kan, Jiao Guo & Shi-Zheng Wen. (2014) Syntheses, structures, and photocatalysis of five inorganic–organic hybrid compounds constructed from Keggin polyoxometalate clusters and multidentate N-donor ligands. Journal of Coordination Chemistry 67:2, pages 195-214.
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Majid M. Heravi & Masoud Mirzaei. 2023. Polyoxometalate-Based Hybrids and their Applications. Polyoxometalate-Based Hybrids and their Applications 1 100 .

Joscha Breibeck, Nadiia I. Gumerova & Annette Rompel. (2022) Oxo-Replaced Polyoxometalates: There Is More than Oxygen. ACS Organic & Inorganic Au 2:6, pages 477-495.
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Soumyabrata Roy, Dundappa Mumbaraddi, Ankit Jain, Subi J. George & Sebastian C. Peter. (2017) Crystal Engineering in Supramolecular Polyoxometalate Hybrids through pH Controlled in Situ Ligand Hydrolysis. Inorganic Chemistry 57:2, pages 590-601.
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Chika Nozaki Kato, Wataru Unno, Sakie Kato, Tsukasa Ogasawara, Toshifumi Kashiwagi, Hidemitsu Uno, Kosuke Suzuki & Noritaka Mizuno. (2016) Organozirconium Complex with Keggin-Type Mono-Aluminum-Substituted Silicotungstate: Synthesis, Molecular Structure, and Catalytic Performance for Meerwein–Ponndorf–Verley Reduction. Catalysis Letters 146:10, pages 2119-2128.
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Soumyabrata Roy, Sumanta Sarkar, Jaysree Pan, Umesh V. Waghmare, R. Dhanya, Chandrabhas Narayana & Sebastian C. Peter. (2016) Crystal Structure and Band Gap Engineering in Polyoxometalate-Based Inorganic–Organic Hybrids. Inorganic Chemistry 55:7, pages 3364-3377.
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Xiuli Wang, Na Han, Hongyan Lin, Aixiang Tian, Guocheng Liu & Juwen Zhang. (2014) pH and amine-induced various octamolybdate-based metal–organic complexes: assembly, structures and properties. Dalton Trans. 43:5, pages 2052-2060.
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pH-dependent assembly of saturated to dilacunary Keggin-based silicotungstate: [Cu(en)₂(H₂O)][H₂en]{γ-SiW₁₀O₃₆[Cu(en)₂(H₂O)]₂}·7.5H₂O

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pH-dependent assembly of saturated to dilacunary Keggin-based silicotungstate: [Cu(en)2(H2O)][H2en]{γ-SiW10O36[Cu(en)2(H2O)]2}·7.5H2O

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pH-dependent assembly of saturated to dilacunary Keggin-based silicotungstate: [Cu(en)₂(H₂O)][H₂en]{γ-SiW₁₀O₃₆[Cu(en)₂(H₂O)]₂}·7.5H₂O