Boron chlorination on a CpRh-coordinated bis(2-mercapto-1-arylimidazolyl)borate [H₂B(tim^Ar)₂]⁻: [CpRh{κ²-S,S′-ClHB(tim^Ar)₂}Cl] and [Cp*Rh{κ³-H,S,S′-ClHB(tim^Ar)₂}][BF₄]⋅H₂O

Fang-Fang FanInstitute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, PR China

Qing MaInstitute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, PR China

Ai-Quan JiaInstitute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, PR China

Xiang-Hong HuangCollege of Biology and Environmental Engineering, Zhejiang Shuren University, Hangzhou, PR China

Qian-Feng ZhangInstitute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, PR ChinaCorrespondence[email protected]

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Boron chlorination on a CpRh-coordinated bis(2-mercapto-1-arylimidazolyl)borate [H₂B(tim^Ar)₂]⁻: [CpRh{κ²-S,S′-ClHB(tim^Ar)₂}Cl] and [Cp*Rh{κ³-H,S,S′-ClHB(tim^Ar)₂}][BF₄]⋅H₂O

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Boron chlorination on a Cp*Rh-coordinated bis(2-mercapto-1-arylimidazolyl)borate [H2B(timAr)2]−: [Cp*Rh{κ2-S,S′-ClHB(timAr)2}Cl] and [Cp*Rh{κ3-H,S,S′-ClHB(timAr)2}][BF4]⋅H2O

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Boron chlorination on a CpRh-coordinated bis(2-mercapto-1-arylimidazolyl)borate [H₂B(tim^Ar)₂]⁻: [CpRh{κ²-S,S′-ClHB(tim^Ar)₂}Cl] and [Cp*Rh{κ³-H,S,S′-ClHB(tim^Ar)₂}][BF₄]⋅H₂O