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Review Article

Mixed Matrix Membranes Based on PIMs for Gas Permeation: Principles, Synthesis, and Current Status

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Fuat Topuz, Mohamed H. Abdellah, Peter M. Budd & Mahmoud A. Abdulhamid. (2024) Advances in Polymers of Intrinsic Microporosity (PIMs)-Based Materials for Membrane, Environmental, Catalysis, Sensing and Energy Applications. Polymer Reviews 64:1, pages 251-305.
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Pei Thing Chang, Qi Hwa Ng, Abdul Latif Ahmad & Siew Chun Low. (2022) A critical review on the techno-economic analysis of membrane gas absorption for CO2 capture. Chemical Engineering Communications 209:11, pages 1553-1569.
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D. A. Kennedy, M. Mujčin, T. Omar & F. H. Tezel. (2022) Synthesis and preliminary gas permeation properties of vitreous composite clinoptilolite membranes. Chemical Engineering Communications 209:5, pages 702-720.
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V. Martin-Gil, M.Z. Ahmad, R. Castro-Muñoz & V. Fila. (2019) Economic Framework of Membrane Technologies for Natural Gas Applications. Separation & Purification Reviews 48:4, pages 298-324.
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Roberto Castro-Muñoz, Violeta Martin-Gil, Mohd Zamidi Ahmad & Vlastimil Fíla. (2018) Matrimid® 5218 in preparation of membranes for gas separation: Current state-of-the-art. Chemical Engineering Communications 205:2, pages 161-196.
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Articles from other publishers (54)

Mridusmita Barooah, Sukanya Kundu, Shubham Kumar, Aviti Katare, Rajashree Borgohain, Ramagopal V.S. Uppaluri, Lal Mohan Kundu & Bishnupada Mandal. (2024) New generation mixed matrix membrane for CO2 separation: Transition from binary to quaternary mixed matrix membrane. Chemosphere 354, pages 141653.
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Dionysios S. Karousos, Danial Qadir, Andreas A. Sapalidis, Faizan Ahmad & Evangelos P. Favvas. (2023) Polymeric, metallic and carbon membranes for hydrogen separation: A review. Gas Science and Engineering 120, pages 205167.
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Pranay Rajendra Lanjekar & Narayan Lal Panwar. (2023) Hydrogen gas separation through membrane technology and sustainability analysis of membrane: a review. Emergent Materials 6:6, pages 1727-1750.
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Chao Ma, Ning Li, Dudu Li, Zhenjie Gu, Zhihua Qiao & Chongli Zhong. (2023) A self-supported aZIF-UC-4 glass membrane for gas separation. Journal of Membrane Science 683, pages 121873.
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Hadiya Amir, Rahma Tamime, Zufishan Shamair, Asim Laeeq Khan, Hamad AlMohamadi & R. Nawaz. (2023) Enhanced gas separation performance of PIM-1 blend membranes incorporating ionic liquid (3-(trimethoxysilyl) propan-1-aminium acetate ([APTMS][Ac])) as filler: Investigation of morphology, compatibility and transport properties. Fuel 349, pages 128669.
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Toshihiro Isobe, Shinya Iijima, Naoki Arimitsu, Sachiko Matsushita & Akira Nakajima. (2023) Effect of magnetic force on O2 gas transmission rate for porous alumina. Ceramics International 49:11, pages 17348-17353.
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Danila S. Bakhtin, Stepan E. Sokolov, Ilya L. Borisov, Vladimir V. Volkov, Alexey V. Volkov & Vadim O. Samoilov. (2023) Mitigation of Physical Aging of Polymeric Membrane Materials for Gas Separation: A Review. Membranes 13:5, pages 519.
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Rujing Hou, Shilong Wang, Lei Wang, Chang Li, Huan Wang, Yingtian Xu, Chongqing Wang, Yichang Pan & Weihong Xing. (2023) Enhanced CO2 separation performance by incorporating KAUST-8 nanosheets into crosslinked poly(ethylene oxide) membrane. Separation and Purification Technology 309, pages 123057.
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Danila S. Bakhtin, Alexander O. Malakhov, Alexey V. Volkov, Leonid A. Kulikov, Inna V. Petrova, Ilya L. Borisov & Stepan D. Bazhenov. (2022) Mitigating of Thin-Film Composite PTMSP Membrane Aging by Introduction of Porous Rigid and Soft Branched Polymeric Additives. Membranes 13:1, pages 21.
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Chunyu Zhao, Woorod Hussain, Hussein Humedy Chlib Alkaaby, Rusul Mohammed AL-Khafaji, Tawfeeq Alghazali, Samar Emad Izzat, Marwah A. Shams, Emad Salaam Abood, Anisimova E. Yu & Mohamed Ehab. (2022) Polymeric nanocomposite membranes for gas separation: Performance, applications, restrictions and future perspectives. Case Studies in Thermal Engineering 38, pages 102323.
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Roberto Castro-Muñoz, Mohd Zamidi Ahmad, Magdalena Malankowska & Joaquín Coronas. (2022) A new relevant membrane application: CO2 direct air capture (DAC). Chemical Engineering Journal 446, pages 137047.
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Rujing Hou, Stefan J. D. Smith, Kristina Konstas, Cara M. Doherty, Christopher D. Easton, Jaesung Park, Heewook Yoon, Huanting Wang, Benny D. Freeman & Matthew R. Hill. (2022) Synergistically improved PIM-1 membrane gas separation performance by PAF-1 incorporation and UV irradiation. Journal of Materials Chemistry A 10:18, pages 10107-10119.
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Y.A. Reyes, M. Pérez, E.L. Barrera, Y. Martínez & K.K. Cheng. (2022) Thermochemical conversion processes of Dichrostachys cinerea as a biofuel: A review of the Cuban case. Renewable and Sustainable Energy Reviews 160, pages 112322.
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Md. Yeasir Hasan, Minhaj Uddin Monir, Mohammad Tofayal Ahmed, Azrina Abd Aziz, Shaik Muntasir Shovon, Faysal Ahamed Akash, Mohammad Forrukh Hossain Khan, Md. Jamal Faruque, Md. Shamiul Islam Rifat, Md. Jafar Hossain, Prionti Kundu, Rafica Akter & Sohag Ali. (2022) Sustainable energy sources in Bangladesh: A review on present and future prospect. Renewable and Sustainable Energy Reviews 155, pages 111870.
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Melinda L Jue & Ryan P Lively. (2022) PIM hybrids and derivatives: how to make a good thing better. Current Opinion in Chemical Engineering 35, pages 100750.
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Nishel Saini & Kamlendra Awasthi. (2022) Insights into the progress of polymeric nano-composite membranes for hydrogen separation and purification in the direction of sustainable energy resources. Separation and Purification Technology 282, pages 120029.
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Alaa Mohamed, Samy Yousef, Andrius Tonkonogovas, Vidas Makarevicius & Arūnas Stankevičius. (2022) High performance of PES-GNs MMMs for gas separation and selectivity. Arabian Journal of Chemistry 15:2, pages 103565.
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Aditya Tripathi, Nilotpala Bej & Satyabati Das. (2021) Membranes for Carbon Dioxide Separation on a Small Scale: State of Art, Challenges and Applications. Journal of Environmental Chemical Engineering 9:6, pages 106860.
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Mahdi Bourassi, Magda Kárászová, Mariia Pasichnyk, Raul Zazpe, Jana Herciková, Vlastimil Fíla, Jan M. Macak & Jana Gaálová. (2021) Removal of Ibuprofen from Water by Different Types Membranes. Polymers 13:23, pages 4082.
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Siraj Ahmad, Shaohan Lian, Yaxin Tan, Run Li, Quan Zhao, Chunfeng Song, Qingling Liu & Shijian Lu. (2021) Solvent influence on the textural properties and CO2/N2 separation performance of novel Pebax-1657/attapulgite mixed matrix membranes. Journal of Environmental Chemical Engineering 9:5, pages 105806.
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Ashwin R. Kamble, Chetan M. Patel & Z.V.P. Murthy. (2021) A review on the recent advances in mixed matrix membranes for gas separation processes. Renewable and Sustainable Energy Reviews 145, pages 111062.
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Zongqi Zhang, Siquan Xu, Yuanfeng Wu, Shengbin Shi & Guomin Xiao. (2021) Recent Advances of Pervaporation Separation in DMF/H2O Solutions: A Review. Membranes 11:6, pages 455.
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Francesca Russo, Francesco Galiano, Adolfo Iulianelli, Angelo Basile & Alberto Figoli. (2021) Biopolymers for sustainable membranes in CO2 separation: a review. Fuel Processing Technology 213, pages 106643.
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Roberto Castro-Muñoz. (2020) Breakthroughs on tailoring pervaporation membranes for water desalination: A review. Water Research 187, pages 116428.
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Roberto Castro-Muñoz, Francesco Galiano & Alberto Figoli. (2020) Recent advances in pervaporation hollow fiber membranes for dehydration of organics. Chemical Engineering Research and Design 164, pages 68-85.
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Saba Raveshiyan, Javad Karimi-Sabet & Seyed Saeid Hosseini. (2020) Influence of Particle Size on the Performance of Polysulfone Magnetic Membranes for O 2 /N 2 Separation . Chemical Engineering & Technology 43:12, pages 2437-2446.
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Rujing Hou, Bader S. Ghanem, Stefan J. D. Smith, Cara M. Doherty, Caitlin Setter, Huanting Wang, Ingo Pinnau & Matthew R. Hill. (2020) Highly permeable and selective mixed-matrix membranes for hydrogen separation containing PAF-1. Journal of Materials Chemistry A 8:29, pages 14713-14720.
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Saba Raveshiyan, Seyed Saeid Hosseini & Javed Karimi-Sabet. (2020) Intensification of O2/N2 separation by novel magnetically aligned carbonyl iron powders /polysulfone magnetic mixed matrix membranes. Chemical Engineering and Processing - Process Intensification 150, pages 107866.
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Aishah Rosli, Abdul Latif Ahmad & Siew Chun Low. (2019) Functionalization of silica nanoparticles to reduce membrane swelling in CO 2 absorption process . Journal of Chemical Technology & Biotechnology 95:4, pages 1073-1084.
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Roberto Castro-Muñoz, Kumar Varoon Agrawal & Joaquín Coronas. (2020) Ultrathin permselective membranes: the latent way for efficient gas separation. RSC Advances 10:21, pages 12653-12670.
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So Young Kim, Younghyun Cho & Sang Wook Kang. (2020) Correlation between Functional Group and Formation of Nanoparticles in PEBAX/Ag Salt/Al Salt Complexes for Olefin Separation. Polymers 12:3, pages 667.
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Roberto Castro-Muñoz, Mohd Zamidi Ahmad & Vlastimil Fíla. (2020) Tuning of Nano-Based Materials for Embedding Into Low-Permeability Polyimides for a Featured Gas Separation. Frontiers in Chemistry 7.
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Roberto Castro-Muñoz & Vlastimil Fíla. 2020. Current Trends and Future Developments on (Bio-) Membranes. Current Trends and Future Developments on (Bio-) Membranes 47 69 .
Peter M. Budd. 2020. Sustainable Nanoscale Engineering. Sustainable Nanoscale Engineering 231 264 .
Roberto Castro-Muñoz & José González-Valdez. (2019) New Trends in Biopolymer-Based Membranes for Pervaporation. Molecules 24:19, pages 3584.
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Roberto Castro-Muñoz, Francesco Galiano, Óscar de la Iglesia, Vlastimil Fíla, Carlos Téllez, Joaquín Coronas & Alberto Figoli. (2019) Graphene oxide – Filled polyimide membranes in pervaporative separation of azeotropic methanol–MTBE mixtures. Separation and Purification Technology 224, pages 265-272.
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Aishah Rosli, Abdul Latif Ahmad & Siew Chun Low. (2019) Anti-wetting polyvinylidene fluoride membrane incorporated with hydrophobic polyethylene-functionalized-silica to improve CO2 removal in membrane gas absorption. Separation and Purification Technology 221, pages 275-285.
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Roberto Castro-Muñoz, Francesco Galiano, Vlastimil Fíla, Enrico Drioli & Alberto Figoli. (2019) Mixed matrix membranes (MMMs) for ethanol purification through pervaporation: current state of the art. Reviews in Chemical Engineering 35:5, pages 565-590.
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Francesco Galiano, Roberto Castro-Muñoz, Raffaella Mancuso, Bartolo Gabriele & Alberto Figoli. (2019) Membrane Technology in Catalytic Carbonylation Reactions. Catalysts 9:7, pages 614.
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Abtin Ebadi Amooghin, Samaneh Mashhadikhan, Hamidreza Sanaeepur, Abdolreza Moghadassi, Takeshi Matsuura & Seeram Ramakrishna. (2019) Substantial breakthroughs on function-led design of advanced materials used in mixed matrix membranes (MMMs): A new horizon for efficient CO2 separation. Progress in Materials Science 102, pages 222-295.
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Muhanned Khdhayyer, Alexandra F. Bushell, Peter M. Budd, Martin P. Attfield, Dongmei Jiang, Andrew D. Burrows, Elisa Esposito, Paola Bernardo, Marcello Monteleone, Alessio Fuoco, Gabriele Clarizia, Fabio Bazzarelli, Amalia Gordano & Johannes C. Jansen. (2019) Mixed matrix membranes based on MIL-101 metal–organic frameworks in polymer of intrinsic microporosity PIM-1. Separation and Purification Technology 212, pages 545-554.
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Roberto Castro-Muñoz & Vlastimil Fíla. (2019) Effect of the ZIF‐8 Distribution in Mixed‐Matrix Membranes Based on Matrimid® 5218‐PEG on CO 2 Separation . Chemical Engineering & Technology 42:4, pages 744-752.
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Rujing Hou, Stefan J. D. Smith, Colin D. Wood, Roger J. Mulder, Cher Hon Lau, Huanting Wang & Matthew R. Hill. (2019) Solvation Effects on the Permeation and Aging Performance of PIM-1-Based MMMs for Gas Separation. ACS Applied Materials & Interfaces 11:6, pages 6502-6511.
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Roberto Castro-Muñoz, Vlastimil Fíla, Violeta Martin-Gil & Clément Muller. (2019) Enhanced CO2 permeability in Matrimid® 5218 mixed matrix membranes for separating binary CO2/CH4 mixtures. Separation and Purification Technology 210, pages 553-562.
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Ke Xie, Qiang Fu, Greg G. Qiao & Paul A. Webley. (2019) Recent progress on fabrication methods of polymeric thin film gas separation membranes for CO2 capture. Journal of Membrane Science 572, pages 38-60.
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Roberto Castro-Muñoz, Óscar de la Iglesia, Vlastimil Fíla, Carlos Téllez & Joaquín Coronas. (2018) Pervaporation-Assisted Esterification Reactions by Means of Mixed Matrix Membranes. Industrial & Engineering Chemistry Research 57:47, pages 15998-16011.
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Xiaoheng Jin, Chung-Yan Poon & Rakesh K. Joshi. 2018. Graphene-based Membranes for Mass Transport Applications. Graphene-based Membranes for Mass Transport Applications 163 187 .
Shunsuke Tanaka, Kazuki Sakamoto, Hideaki Inada, Masashi Kawata, Goya Takasaki & Kota Imawaka. (2018) Vapor-Phase Synthesis of ZIF-8 MOF Thick Film by Conversion of ZnO Nanorod Array. Langmuir 34:24, pages 7028-7033.
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Roberto Castro-Muñoz & Vlastimil Fíla. (2018) Progress on Incorporating Zeolites in Matrimid®5218 Mixed Matrix Membranes towards Gas Separation. Membranes 8:2, pages 30.
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Roberto Castro-Muñoz, Francesco Galiano, Vlastimil Fíla, Enrico Drioli & Alberto Figoli. (2018) Matrimid®5218 dense membrane for the separation of azeotropic MeOH-MTBE mixtures by pervaporation. Separation and Purification Technology 199, pages 27-36.
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Toshikazu Sakaguchi, So Nakao, Satoshi Irie & Tamotsu Hashimoto. (2018) Gas permeability of mixed matrix membranes composed of poly(diphenylacetylene)s and dispersed metal chloride particles. Polymer 140, pages 208-214.
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Canghai Ma & Jeffrey J. Urban. (2018) Polymers of Intrinsic Microporosity (PIMs) Gas Separation Membranes: A mini Review. Proceedings of the Nature Research Society 2.
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Evangelos P. Favvas, Alberto Figoli, Roberto Castro-Muñoz, Vlastimil Fíla & Xuezhong He. 2018. Current Trends and Future Developments on (Bio-) Membranes. Current Trends and Future Developments on (Bio-) Membranes 3 50 .
T. Sakaguchi, Y. Lin & T. Hashimoto. (2017) Enhancement of oxygen permeability by copolymerization of silyl group-containing diphenylacetylenes with tert-butyl group-containing diphenylacetylene and desilylation of copolymer membranes. RSC Advances 7:49, pages 30949-30955.
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