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Separation Science and Technology Volume 45, 2010 - Issue 12-13: The Sixteenth Symposium on Separation Science and Technology for Energy Applications
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Original Articles

Selective Extraction of Minor Actinides from Acidic Media Using Symmetric and Asymmetric Dithiophosphinic Acids

D. R. Peterman Idaho National Laboratory, Idaho Falls, ID, USACorrespondence[email protected]
,
M. R. Greenhalgh Idaho National Laboratory, Idaho Falls, ID, USA
,
R. D. Tillotson Idaho National Laboratory, Idaho Falls, ID, USA
,
J. R. Klaehn Idaho National Laboratory, Idaho Falls, ID, USA
,
M. K. Harrup Idaho National Laboratory, Idaho Falls, ID, USA
,
T. A. Luther Idaho National Laboratory, Idaho Falls, ID, USA
&
J. D. Law Idaho National Laboratory, Idaho Falls, ID, USA
 show all
Pages 1711-1717 | Received 02 Nov 2009, Accepted 26 Apr 2010, Published online: 30 Aug 2010

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Cheriyan Ebenezer & R. Vijay Solomon. (2024) Computational Tools and Techniques in Designing Ligands for the Selective Separation of Actinide and Lanthanide: A Review. Comments on Inorganic Chemistry 0:0, pages 1-75.
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V. Babain, M. Alyapyshev, I. Voronaev, L. Tkachenko & E. Kenf. (2021) Extraction of Actinides with Tributyl Phosphate in Carbonates of Fluorinated Alcohols. Solvent Extraction and Ion Exchange 39:3, pages 255-270.
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Yan-Ning Niu, Peng Ren, Fang Zhang & Ze-Yi Yan. (2018) Solvent extraction of Eu3+ with 4-oxaheptanediamide into ionic liquid system. Separation Science and Technology 53:17, pages 2750-2755.
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Jonathan D. Burns & Abraham Clearfield. (2018) Kinetics of Ion Exchange of Zr/Sn(IV) Phosphonate–Phosphate Hybrid Materials for Separation of Lanthanides from Oxidized Actinides. Solvent Extraction and Ion Exchange 36:7, pages 674-686.
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Peter R. Zalupski, John R. Klaehn & Dean R. Peterman. (2015) Complete Recovery of Actinides from UREX-like Raffinates Using a Combination of Hard and Soft Donor Ligands. II. Soft Donor Structure Variation. Solvent Extraction and Ion Exchange 33:6, pages 523-539.
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Mark P. Jensen, Renato Chiarizia, Joseph S. Ulicki, Brian D. Spindler, Daniel J. Murphy, M. Mahmun Hossain, Adrián Roca-Sabio, Andrés de Blas & Teresa Rodríguez-Blas. (2015) Solvent Extraction Separation of Trivalent Americium from Curium and the Lanthanides. Solvent Extraction and Ion Exchange 33:4, pages 329-345.
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A.K. Singha Deb, Sk.M. Ali, K.T. Shenoy & S.K. Ghosh. (2015) Adsorption of Eu3+ and Am3+ ion towards hard donor-based diglycolamic acid-functionalised carbon nanotubes: density functional theory guided experimental verification. Molecular Simulation 41:5-6, pages 490-503.
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A.S. Suneesh, R. Kumaresan, S. Rajeswari, Prasant Kumar Nayak, K.V. Syamala, K.A. Venkatesan, M.P. Antony & P.R.Vasudeva Rao. (2013) Development and Demonstration of Americium (III)-Europium (III) Separation Using Diglycolamic Acid. Separation Science and Technology 48:13, pages 1998-2006.
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Peter R. Zalupski, Dale D. Ensor, Catherine L. Riddle & Dean R. Peterman. (2013) Complete Recovery of Actinides from UREX-like Raffinates using a Combination of Hard and Soft Donor Ligands. Solvent Extraction and Ion Exchange 31:4, pages 430-441.
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Articles from other publishers (39)

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Ning Pu, Chao Xu & Jing Chen. (2023) Probing Substituent Effect on Nickel–Sulfur Bond Covalency in Ni(II)–Dithiophosphinate Complexes by Sulfur K-Edge XAS and DFT Calculations. Inorganic Chemistry 62:38, pages 15565-15574.
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Qin Wang, Ziyi Liu, Yu-Fei Song & Dongqi Wang. (2023) Recent Advances in the Study of Trivalent Lanthanides and Actinides by Phosphinic and Thiophosphinic Ligands in Condensed Phases. Molecules 28:17, pages 6425.
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Jinlong Fan, Li Duan, Yufeng Wang, Pengju Qiu, Mao Fan, Pei Shang, Yajiao He & Tai Kang. (2023) Adsorption of actinides (Ⅲ) and lanthanides (Ⅲ) on silica-based BCPDTPA resin: Kinetics, thermodynamics, and isotherms. Colloids and Surfaces A: Physicochemical and Engineering Aspects 670, pages 131547.
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Yusheng Zhang, Wuhua Duan, Qiang Wang, Lei Zheng, Jianchen Wang, Jing Chen & Taoxiang Sun. (2022) Covalency between the uranyl ion and dithiophosphinate by sulfur K -edge X-ray absorption spectroscopy and density functional theory . Journal of Synchrotron Radiation 29:1, pages 11-20.
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Nathan Bessen, Qiang Yan, Ning Pu, Jing Chen, Chao Xu & Jenifer Shafer. (2021) Extraction of the trivalent transplutonium actinides americium through einsteinium by the sulfur donor Cyanex 301. Inorganic Chemistry Frontiers 8:18, pages 4177-4185.
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Meena B. Singh, Yuqing Fu, Ilja Popovs, Santa Jansone-Popova, Sheng Dai & De-en Jiang. (2021) Molecular Dynamics Simulations of Complexation of Am(III) with a Preorganized Dicationic Ligand in an Ionic Liquid. The Journal of Physical Chemistry B 125:30, pages 8532-8538.
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Christine A. Phipps, Joanna M. Rosenberger, McKenzie M. Miller, Sean R. Parkin & Jessie L. Brown. (2021) Synthetic route to vanadium(III) dichalcogenidophosphinate complexes, V(S 2 PPh 2 ) 3 and V(Se 2 PPh 2 ) 3 : A spectroscopic and structural comparative study with analogous complexes of chromium(III), Cr(E 2 PPh 2 ) 3 (E=S, Se) . Zeitschrift für anorganische und allgemeine Chemie 647:11, pages 1182-1192.
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Nathan P. Bessen, Erin R. Bertelsen & Jenifer C. Shafer. (2021) Permanganometric Titration for the Quantification of Purified Bis(2,4,4-trimethylpentyl)dithiophosphinic Acid in n -Dodecane . ACS Omega 6:12, pages 8463-8468.
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N.P. Bessen, J.A. Jackson, M.P. Jensen & J.C. Shafer. (2020) Sulfur donating extractants for the separation of trivalent actinides and lanthanides. Coordination Chemistry Reviews 421, pages 213446.
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Ning Pu, Jing Su, Lei Xu, Taoxiang Sun, Enrique R. Batista, Jing Chen, Ping Yang, Jenifer C. Shafer & Chao Xu. (2019) “Sweeping” Ortho Substituents Drive Desolvation and Overwhelm Electronic Effects in Nd 3+ Chelation: A Case of Three Aryldithiophosphinates . Inorganic Chemistry 59:1, pages 161-171.
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Zhipeng Wang, Ning Pu, Yin Tian, Chao Xu, Fang Wang, Ying Liu, Lirong Zhang, Jing Chen & Songdong Ding. (2018) Highly Selective Separation of Actinides from Lanthanides by Dithiophosphinic Acids: An in-Depth Investigation on Extraction, Complexation, and DFT Calculations. Inorganic Chemistry 58:9, pages 5457-5467.
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Ning Pu, Lei Xu, Taoxiang Sun, Jing Chen & Chao Xu. (2019) Tremendous impact of substituent group on the extraction and selectivity to Am(III) over Eu(III) by diaryldithiophosphinic acids: experimental and DFT analysis. Journal of Radioanalytical and Nuclear Chemistry 320:1, pages 219-226.
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Brian L. Scott, Samantha K. Cary & Justin N. Cross. 2012. Encyclopedia of Inorganic and Bioinorganic Chemistry. Encyclopedia of Inorganic and Bioinorganic Chemistry 1 32 .
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Aurora E. Clark, Ping Yang & Jenifer C. Shafer. 2018. Experimental and Theoretical Approaches to Actinide Chemistry. Experimental and Theoretical Approaches to Actinide Chemistry 237 282 .
Chao Xu, Taoxiang Sun & Linfeng Rao. (2017) Interactions of Bis(2,4,4-trimethylpentyl)dithiophosphinate with Trivalent Lanthanides in a Homogeneous Medium: Thermodynamics and Coordination Modes. Inorganic Chemistry 56:5, pages 2556-2565.
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Dongping Su, Ying Liu, Shimeng Li, Songdong Ding, Yongdong Jin, Zhipeng Wang, Xiaoyang Hu & Lirong Zhang. (2017) Selective Extraction of Americium(III) over Europium(III) Ions with Pyridylpyrazole Ligands: Structure–Property Relationships. European Journal of Inorganic Chemistry 2017:3, pages 651-658.
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Andrea Leoncini, Jurriaan Huskens & Willem Verboom. (2017) Ligands for f-element extraction used in the nuclear fuel cycle. Chemical Society Reviews 46:23, pages 7229-7273.
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Jessica Veliscek-Carolan. (2016) Separation of actinides from spent nuclear fuel: A review. Journal of Hazardous Materials 318, pages 266-281.
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Michel Ephritikhine. (2016) Molecular actinide compounds with soft chalcogen ligands. Coordination Chemistry Reviews 319, pages 35-62.
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R. Rama, Alok Rout, K. A. Venkatesan & M. P. Antony. (2016) Voltammetric Studies on the Complexing Behavior of Eu(III) with Acidic Extractants in 1-Butyl-1-methylpyrrolidinium Bis(trifluoromethanesulfonyl)imide. Journal of The Electrochemical Society 163:14, pages H1113-H1121.
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Chao Xu  & Linfeng Rao. (2014) Interactions of Bis(2,4,4‐trimethylpentyl)dithiophosphinate with Nd III and Cm III in a Homogeneous Medium: A Comparative Study of Thermodynamics and Coordination Modes . Chemistry – A European Journal 20:45, pages 14807-14815.
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Lin Li, Haijun Dang, Qichu Xu, Wengang Jiang, Mei Li & Jihong Zhang. (2014) A novel Np–Pu separation procedure based on extraction with di-(chlorophenyl)-dithiophosphinic acid in nitric solution. Journal of Radioanalytical and Nuclear Chemistry 301:3, pages 789-795.
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Melissa E. Freiderich, Dean R. Peterman, John R. Klaehn, Philippe Marc & Lætitia H. Delmau. (2014) Chemical Degradation Studies on a Series of Dithiophosphinic Acids. Industrial & Engineering Chemistry Research 53:9, pages 3606-3611.
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Kevin S. Boland, David E. Hobart, Stosh A. Kozimor, Molly M. MacInnes & Brian L. Scott. (2014) The coordination chemistry of trivalent lanthanides (Ce, Nd, Sm, Eu, Gd, Dy, Yb) with diphenyldithiophosphinate anions. Polyhedron 67, pages 540-548.
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Fang Wang, Cai Jia, Dengfang Pan & Jing Chen. (2013) Study on Short, Straight Alkyl Chain Substituted Dithiophosphinic Acids for Actinides and Lanthanides Extraction Separation. Industrial & Engineering Chemistry Research 52:51, pages 18373-18378.
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Fang Wang, Cai Jia & Jing Chen. (2013) Convenient synthesis of (o-CF3Ph)2PS2H and evaluation in selective extraction of actinides over lanthanides. Journal of Radioanalytical and Nuclear Chemistry 298:1, pages 531-536.
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Petra J. Panak & Andreas Geist. (2013) Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N -Donor Ligands . Chemical Reviews 113:2, pages 1199-1236.
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