1,558
Views
73
CrossRef citations to date
0
Altmetric
Original Articles

Review of Physical and Chemical Properties of Tributyl Phosphate/Diluent/Nitric Acid Systems

&
Pages 1753-1762 | Received 01 Nov 2009, Accepted 12 Mar 2010, Published online: 30 Aug 2010

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (11)

Satyabrata Mishra, N. Desigan, K. A. Venkatesan & K. Ananthasivan. (2023) Comparison of Cyclic Irradiation Behavior of Tri-Butyl Phosphate / Tri-Iso-Amyl Phosphate-Dodecane System in Nitric Acid Medium. Solvent Extraction and Ion Exchange 41:3, pages 292-316.
Read now
G. Jegan, B. Sreenivasulu, A. Suresh, C. V. S. Brahmananda Rao, N. Sivaraman & Gopinadhanpillai Gopakumar. (2022) Experimental and theoretical studies on solvent extraction of uranium(VI) with hexapropyl and hexabutyl phosphoramide extractants. Solvent Extraction and Ion Exchange 40:3, pages 312-332.
Read now
Thibault D’halluin, Célia Lepeytre, Antoine Leydier & Carine Julcour. (2021) Degradation mechanism of tributyl phosphate by UV/H2O2 treatment and parameters optimization towards the design of a pilot reactor. Environmental Technology 42:27, pages 4247-4259.
Read now
Subramee Sarkar, A. Suresh & N. Sivaraman. (2020) Extraction Behaviour of Tris(2-methylbutyl) Phosphate with Fission Products and Heavy Metal Ions. Solvent Extraction and Ion Exchange 38:3, pages 304-317.
Read now
Takuya Ohno, Shinsuke Tashiro, Yuki Amano, Ryoichiro Yoshida & Hitoshi Abe. (2020) Rapid Clogging of High-Efficiency Particulate Air Filters During In-Cell Solvent Fires at Reprocessing Facilities. Nuclear Technology 206:1, pages 40-47.
Read now
Satyabrata Mishra, C. Mallika, N. K. Pandey, U. Kamachi Mudali & R. Natarajan. (2015) Effect of Radiolysis in Altering the Physiochemical and Metal Retention Properties of Solvent-Diluent-Acid Systems. Separation Science and Technology 50:11, pages 1671-1676.
Read now
B. Sreenivasulu, A. Suresh, S. Subramaniam, K. N. Sabharwal, N. Sivaraman, K. Nagarajan, T. G. Srinivasan & P. R. Vasudeva Rao. (2015) Separation of U(VI) and Pu(IV) from Am(III) and Trivalent Lanthanides with Tri-iso-amyl Phosphate (TiAP) as the Extractant by Using an Ejector Mixer-Settler. Solvent Extraction and Ion Exchange 33:2, pages 120-133.
Read now
Nirvik Sen, Mayur Darekar, K. K. Singh, S. Mukhopadhyay, K. T. Shenoy & S. K. Ghosh. (2014) Solvent Extraction and Stripping Studies in Microchannels with TBP Nitric Acid System. Solvent Extraction and Ion Exchange 32:3, pages 281-300.
Read now
Carlos F. Jové Colón, Harry K. Moffat & Rekha R. Rao. (2013) Modeling of Liquid-Liquid Extraction (LLE) Equilibria Using Gibbs Energy Minimization (GEM) for the System TBP–HNO3–UO2–H2O–Diluent. Solvent Extraction and Ion Exchange 31:6, pages 634-651.
Read now
M van Soestbergen, S J F Erich, H P Huinink & O C G Adan. (2013) Dissolution properties of cerium dibutylphosphate corrosion inhibitors. Corrosion Engineering, Science and Technology 48:3, pages 234-240.
Read now

Articles from other publishers (62)

Yilin Qin, Shilong Shi, Tianzhen Ye, Chuyan Xiao, Tu Lan, Feize Li, Songdong Ding, Jijun Yang, Yuanyou Yang, Jiali Liao & Ning Liu. (2024) Understanding the extraction behavior and mechanism of Th(Ⅳ) and U(Ⅵ) by the irradiated tri-iso-amyl phosphate with At-211 as an α-source. Separation and Purification Technology 336, pages 126242.
Crossref
Selva Kumar R, R. Bhaskar, Harish K. Sharma, S.K. Ashok Kumar & Suban K. Sahoo. (2024) Historical overview and recent progress on supramolecular sensors for thorium recognition. TrAC Trends in Analytical Chemistry 172, pages 117551.
Crossref
Lei Chen, Junfeng Li & Jianlong Wang. (2024) Cementation of degraded residues of spent radioactive organic solvents by fenton oxidation. Progress in Nuclear Energy 168, pages 105013.
Crossref
Arya Das & Sk. Musharaf Ali. (2024) Structure and dynamics of dissociated and undissociated forms of nitric acid and their implications in interfacial mass transfer: insights from molecular dynamics simulations. Physical Chemistry Chemical Physics 26:8, pages 6916-6938.
Crossref
Jonathan George, Ramsey Salcedo, Rachel Greenberg, Hossam Elshendidi, Donna McGregor, Benjamin Burton-Pye, Lynn C. Francesconi, Alena Paulenova, Artem V. Gelis & Frederic Poineau. (2023) Structural Investigation of Technetium Dibutylphosphate Species Using X-ray Absorption Fine Structure Spectroscopy. Inorganic Chemistry 62:40, pages 16378-16387.
Crossref
Jiayang Sun, Yinyong Ao, Yue Wang, Hang Zhang, Maolin Zhai, Jiuqiang Li, Jing Peng & Huibo Li. (2023) Effect of radiolysis and radiolytic products of tri-iso-amyl phosphate on the extraction behavior of uranium. Journal of Radioanalytical and Nuclear Chemistry 332:10, pages 4089-4099.
Crossref
T. Aneesh, S. Sagunthala Devi, Neeraja Chandran, S. Usha, Bhavya S. Nair, D. Jebaraj Mahildoss, K. Dhamodharan & K. Ananthasivan. (2023) Spectrophotometric determination of di-butyl phosphate in PUREX solvent using peroxo disulfate as oxidizing agent. Journal of Radioanalytical and Nuclear Chemistry 332:7, pages 2725-2732.
Crossref
Yulia V. Serenko, Ivan V. Skvortsov, Alexander V. Ponomarev & Elena V. Belova. (2023) Effect of vaporization on thermal stability of model PUREX-process raffinates. Journal of Radioanalytical and Nuclear Chemistry 332:7, pages 2733-2739.
Crossref
Alok Rout & Satyabrata Mishra. (2023) Ligand Effect on Physicochemical Properties of Ionic Liquid. ChemPhysChem 24:10.
Crossref
Shizong Wang, Guoce Yu & Jianlong Wang. (2023) Treatment of tributyl phosphate by fenton oxidation: Optimization of parameter, degradation kinetics and pathway. Chemosphere 317, pages 137889.
Crossref
Alok Rout, Satyabrata Mishra & Nagarajan Ramanathan. (2023) Presence of a Molecular Ligand alters the Solvent Behavior of an Ionic Liquid: A Combined Physicochemical Properties, FTIR Spectroscopy and Dynamic Light Scattering Investigation. ChemistrySelect 8:5.
Crossref
Satyabrata Mishra, P. Vishnu Anand, Chayan Patra, Pranay Kumar Sinha, Chandan Mukhopadhyay, Jammu Ravi, D. Sivakumar, N. Desigan, Puspalata Rajesh, R. Rajeev, K. Dhamodharan, P. Velavendan, K. A. Venkatesan & K. Ananthasivan. (2023) Solvent wash studies for the removal of di-butyl phosphate from spent solvent under simulated PUREX condition. Journal of Radioanalytical and Nuclear Chemistry 332:2, pages 343-353.
Crossref
Satyabrata Mishra, Chandan Mukhopadhyaya, Chayan Patra, Vishnu Anand Panantharayil, Puspalata Rajesh, Dasari Sivakumar, Narasimhan Desigan, Krishnan Dhamodharan, Periyakaruppan Velavendan, Ramachandran Pillai Rajeev, Konda Athmaram Venkatesan & Krishnamurthy Ananthasivan. (2023) Comparison of the performance of solvent wash reagents used for the primary cleanup of degraded PUREX solvent. Radiochimica Acta 111:1, pages 53-62.
Crossref
M. M. Belova, A. V. Ponomarev, A. V. Smirnov & E. V. Belova. (2023) Influence of Isopar-M on Radiation and Thermal Degradation of Tri-n-Butyl Phosphate in Solutions. Radiochemistry 64:6, pages 705-712.
Crossref
I. A. Bol’shakova, A. V. Ponomarev, A. V. Smirnov & E. V. Belova. (2023) Thermal and Hydrolytic Stability of Irradiated Tri-n-Butyl Phosphate. Radiochemistry 64:6, pages 698-704.
Crossref
Thea Lyseid Authen, Behabitu Ergette Tekikachew, Mark R. St. J. Foreman, Andreas Wilden & Christian Ekberg. (2022) A comparison on the use of DEHBA or TBP as extracting agent for tetra- and hexavalent actinides in the CHALMEX Process. Journal of Radioanalytical and Nuclear Chemistry 331:12, pages 5137-5145.
Crossref
Yu.V. Serenko, E.V. Belova, A.V. Ponomarev & N.V. Yudin. (2022) The effect of radiolysis and thermally stimulated acid hydrolysis on tributyl phosphate and its solutions in ISOPAR-M. Radiation Physics and Chemistry 195, pages 110080.
Crossref
G. Jegan, Satyabrata Mishra, B. Sreenivasulu, Puspalatha Rajesh, A. Suresh, C.V.S. Brahmananda Rao & N. Sivaraman. (2022) Thermophysical properties of hexapropyl and hexabutyl phosphoramides in n-dodecane. Results in Chemistry 4, pages 100346.
Crossref
Mathilde Coquil, Nathalie Boubals, Magali Duvail, Marie-Christine Charbonnel & Jean-François Dufrêche. (2022) On interactions in binary mixtures used in solvent extraction: Insights from combined Isothermal Titration Calorimetry experiments and Molecular Dynamics simulations. Journal of Molecular Liquids 345, pages 116985.
Crossref
Nirvik Sen, K.K. Singh, S. Mukhopadhyay & K.T. Shenoy. (2022) Microfluidic extraction of uranium from dilute streams using TiAP in ionic liquid as the solvent. Chemical Engineering Research and Design 177, pages 83-95.
Crossref
Subramee Sarkar, Suresh Ammath, Subashree Kirubananthan & Asokan Sudha Suneesh. (2021) Investigation of the Phase Splitting Behaviour of U(VI) and Th(IV) loaded Trialkyl Phosphate Solvents in the Absence of Aqueous Phase. ChemistrySelect 6:48, pages 13725-13735.
Crossref
Gehui Pang, Shintaro Morisada, Hidetaka Kawakita, Takeshi Hanamoto, Tatsuya Umecky, Keisuke Ohto & Xi-Ming Song. (2021) Allosteric extraction of a second gallium anion assisted by the first, loaded onto a fluorinated secondary amide reagent. Separation and Purification Technology 278, pages 119036.
Crossref
YuV. Serenko, N.V. Yudin, R.T. Gritcenko, A.V. Rodin, E.V. Belova & A.V. Ponomarev. (2021) Competitive processes of tributyl phosphate degradation in HNO3-saturated solution in Isopar-M during radiolysis and aging. Radiation Physics and Chemistry 185, pages 109495.
Crossref
Imran Ali, E.A. Zakharchenko, G.V. Myasoedova, N.P. Molochnikova, A.A. Rodionova, V.E. Baulin, A.E. Burakov, I.V. Burakova, A.V. Babkin, E.A. Neskoromnaya, A.V. Melezhik, A.G. Tkachev, Mohamed A. Habila, Adel El-Marghany, Mohamed Sheikh & Ayman Ghfar. (2021) Preparation and characterization of oxidized graphene for actinides and rare earth elements removal in nitric acid solutions from nuclear wastes. Journal of Molecular Liquids 335, pages 116260.
Crossref
Satyabrata Mishra, N. Desigan, K.A. Venkatesan & K. Ananthasivan. (2021) Hydrolytic degradation of tri-iso-amyl phosphate-dodecane system. Journal of Molecular Liquids 334, pages 116512.
Crossref
Jegan Govindaraj, Sreenivasulu Balija, Suresh Ammath, Brahmananda Rao C. V. Siva & Sivaraman Nagarajan. (2021) Extraction behavior of Pu(IV), Th(IV), and fission product elements with hexapropyl and hexabutyl phosphoramides. Radiochimica Acta 109:6, pages 419-430.
Crossref
Z. V. Dzhivanova, M. I. Kadyko, Yu.V. Nikitina, A. V. Rodin & E. V. Belova. (2021) A Study of the Radiolysis Products of the Tri-n-Butyl-Phosphate–Isopar-M–HNO3 System before and after Regeneration with Carbonates of Organic Bases. Protection of Metals and Physical Chemistry of Surfaces 57:1, pages 100-105.
Crossref
Meng-Ke Tian, Shuang-Ling Tang, Hong-Bin Tang & Xue-Hai Ju. (2020) Theoretical Study on the Mechanism for the Formation of Nitro Compounds in Red Oil. Journal of Chemistry 2020, pages 1-10.
Crossref
Subramee Sarkar, A. Suresh & N. Sivaraman. (2020) Alpha and gamma degradation behavior of tri-n-alkyl phosphates and tris(2-methylbutyl) phosphate: A comparative study. Radiation Physics and Chemistry 176, pages 108923.
Crossref
Norhazirah Azhar, Khaironie Mohamed Takip, Roshasnorlyza Hazan, Wilfred Selyvester Paulus, Nur Aqilah Sapiee & Jacqueline Kones. (2020) Solvent extraction of Thorium from Malaysian xenotime using Tributyl Phosphate (TBP). IOP Conference Series: Materials Science and Engineering 785:1, pages 012015.
Crossref
Z.V. Dzhivanova, A.V. Smirnov, Yu.S. Pavlov & E.V. Belova. (2020) Thermal stability of the extraction system “30% TBP – Isopar-M – HNO3” in isochoric mode. Progress in Nuclear Energy 119, pages 103174.
Crossref
Ch Venkateswara Rao, Alok Rout & K.A. Venkatesan. (2020) Investigations on the radiation stability of incinerable CHON based ionic liquid containing diglycolamide. Journal of Molecular Liquids 298, pages 112020.
Crossref
Zayana Dzhivanova, Mikhail Kadyko, Anton Smirnov & Elena Belova. (2019) Study of the products of radiation and thermal destruction in the extraction system of 30 vol% TBP–Isopar-M–HNO3. Journal of Radioanalytical and Nuclear Chemistry 321:2, pages 439-447.
Crossref
Subramee Sarkar, K. Chandran, M. Lavanya, N. Ramanathan, P.C. Clinsha, A. Suresh & N. Sivaraman. (2019) Thermal hazard assessment of tris(2-methyl butyl) phosphate: A comparison with tri-n-butyl phosphate and tri-n-amyl phosphate. Thermochimica Acta 671, pages 181-192.
Crossref
M. Masum Billah, M. Mehedi Hasan Rocky, Iqbal Hossen, Irin Hossain, M. Nur Hossain & Shamim Akhtar. (2018) Densities, viscosities, and refractive indices for the binary mixtures of tri-n-butyl phosphate (TBP) with toluene and ethylbenzene between (303.15 and 323.15) K. Journal of Molecular Liquids 265, pages 611-620.
Crossref
A. Suresh, S. Jayalakshmi, Subramee Sarkar & N. Sivaraman. (2018) Effects of temperature on the extraction of U(VI) and Pu(IV) by tris(2-methylbutyl) phosphate from nitric acid media. Radiochimica Acta 106:4, pages 281-289.
Crossref
Arya Das & Sk. Musharaf Ali. (2018) Molecular dynamics simulation for the test of calibrated OPLS-AA force field for binary liquid mixture of tri-iso-amyl phosphate and n -dodecane . The Journal of Chemical Physics 148:7.
Crossref
K. Chandran, B. Sreenivasulu, N. Ramanathan, P.C. Clinsha, A. Suresh & N. Sivaraman. (2017) Thermal decomposition behaviour of irradiated tri n -butyl phosphate and mixture of di and mono n -butyl phosphate-nitric acid systems. Thermochimica Acta 657, pages 1-11.
Crossref
R. Kumaresan, T. Prathibha, B. Robert Selvan, K. A. Venkatesan & M. P. Antony. (2017) Synthesis and evaluation of N,N-di-alkyl-2-methoxyacetamides for the separation of U(VI) and Pu(IV) from nitric acid medium. Radiochimica Acta 105:9, pages 699-707.
Crossref
Arya Das, Pooja Sahu & Sk. Musharaf Ali. (2017) Molecular Dynamics Simulation for the Calibration of the OPLS Force Field Using DFT Derived Partial Charges for the Screening of Alkyl Phosphate Ligands by Studying Structure, Dynamics, and Thermodynamics. Journal of Chemical & Engineering Data 62:8, pages 2280-2295.
Crossref
Deepak D. Dicholkar, Vilas. G. Gaikar, Shekhar Kumar & R. Natarajan. (2017) Steam pyrolysis of N, N, N’, N’ – Tetrabutyl diglycolamide (TBDGA) part-I: Experimental investigations. Journal of Analytical and Applied Pyrolysis 126, pages 132-142.
Crossref
Mohamad Saab, Florent Réal, Martin Šulka, Laurent Cantrel, François Virot & Valérie Vallet. (2017) Facing the challenge of predicting the standard formation enthalpies of n -butyl-phosphate species with ab initio methods . The Journal of Chemical Physics 146:24.
Crossref
Meena B. Singh, Sonal G. Nayak, Ankit D. Kanthe, Rituja B. Patil & Vilas G. Gaikar. (2017) Insight into acidity driven third phase formation of TBP in organic solutions by MD simulation. Journal of Molecular Liquids 232, pages 1-8.
Crossref
B. Sreenivasulu, A. Suresh, S. Rajeswari, N. Ramanathan, M. P. Antony, Nagarajan Sivaraman & M. Joseph. (2017) Physicochemical properties and radiolytic degradation studies on tri-iso-amyl phosphate (TiAP). Radiochimica Acta 105:3, pages 249-261.
Crossref
Qi Sun, Lin Jiang, Liang Gong & Jin-Hua Sun. (2016) Experimental study on thermal hazard of tributyl phosphate-nitric acid mixtures using micro calorimeter technique. Journal of Hazardous Materials 314, pages 230-236.
Crossref
B. Sreenivasulu, K. Chandran, P. C. Clinsha, A. Suresh, N. Sivaraman & S. Anthonysamy. (2016) Effect of gamma irradiation on thermal decomposition of tri-iso-amyl phosphate–nitric acid biphasic systems. Journal of Thermal Analysis and Calorimetry 125:1, pages 483-495.
Crossref
Luther W. McDonaldIVIV, James A. Campbell, Thomas Vercouter & Sue B. Clark. (2016) Characterization of Actinides Complexed to Nuclear Fuel Constituents Using ESI-MS. Analytical Chemistry 88:5, pages 2614-2621.
Crossref
B. Sreenivasulu, A. Suresh, N. Sivaraman & P. R. Vasudeva Rao. (2014) Solvent extraction studies with some fission product elements from nitric acid media employing tri-iso-amyl phosphate and tri-n-butyl phosphate as extractants. Journal of Radioanalytical and Nuclear Chemistry.
Crossref
Shikha Sharma, Sunil K. Ghosh, Devidas B. Naik, Prem S. Dhami & Joti N. Sharma. (2014) Comparative studies on radiolytic degradation of deuterium labeled and unlabeled tributyl phosphates. Journal of Radioanalytical and Nuclear Chemistry 302:1, pages 583-591.
Crossref
Shengting Cui, Valmor F. de Almeida & Bamin Khomami. (2014) Molecular Dynamics Simulations of Tri- n -butyl-phosphate/ n -Dodecane Mixture: Thermophysical Properties and Molecular Structure . The Journal of Physical Chemistry B 118:36, pages 10750-10760.
Crossref
K.R. Barnard, N.J. Kelly & D.W. Shiers. (2014) Chemical reactivity between bis(2-ethylhexyl)phosphoric acid (DEHPA) and tributyl phosphate. Hydrometallurgy 146, pages 1-7.
Crossref
Vikesh G. Lade, Achyut D. Pakhare & Virendra K. Rathod. (2014) Mass Transfer Studies in Pulsed Sieve Plate Extraction Column for the Removal of Tributyl Phosphate from Aqueous Nitric Acid. Industrial & Engineering Chemistry Research 53:12, pages 4812-4820.
Crossref
Mani Lal Singh, Subhash C. Tripathi, P. P. K. Venkata & Vilas G. Gaikar. (2014) Correlations among Composition, Temperature, and Density, Viscosity, or Derived Thermodynamic Properties of Binary Mixtures of Tri- n -butyl Phosphate with n -Hexane or n -Dodecane . Industrial & Engineering Chemistry Research 53:10, pages 3795-3804.
Crossref
S. Balasubramonian, Shekhar Kumar, D. Sivakumar & U. Kamachi Mudali. (2014) Application of COSMO-RS Method for the Prediction of Liquid-Liquid Equilibrium of Water/n-Dodecane/1-Butanol. ISRN Thermodynamics 2014, pages 1-6.
Crossref
Tatiana G. LevitskaiaJames M. PetersonEmily L. CampbellAmanda J. CasellaDean R. PetermanSamuel A. Bryan. (2013) Fourier Transform Infrared Spectroscopy and Multivariate Analysis for Online Monitoring of Dibutyl Phosphate Degradation Product in Tributyl Phosphate/ n -Dodecane/Nitric Acid Solvent . Industrial & Engineering Chemistry Research 52:49, pages 17607-17617.
Crossref
Deepak D. Dicholkar, Pradipta Kumar, Parminder Kaur Heer, Vilas G. Gaikar, Shekhar Kumar & R. Natarajan. (2013) Synthesis of N,N,N′,N′-Tetraoctyl-3-oxapentane-1,5-diamide (TODGA) and Its Steam Thermolysis-Nitrolysis as a Nuclear Waste Solvent Minimization Method. Industrial & Engineering Chemistry Research 52:7, pages 2457-2469.
Crossref
P. Velavendan, S. Ganesh, N. K. Pandey, R. Geetha, M. K. Ahmed, U. Kamachi Mudali & R. Natarajan. (2012) Studies on solubility of TBP in aqueous solutions of fuel reprocessing. Journal of Radioanalytical and Nuclear Chemistry 295:2, pages 1113-1117.
Crossref
Shaila Lalkuwar Bajoria, Virendra Kisan Rathod, N. K. Pandey, U. Kamachi Mudali & R. Natarajan. (2012) Effect of tri-n-butyl phosphate on physical properties of dodecane–nitric acid system. Journal of Radioanalytical and Nuclear Chemistry 295:1, pages 271-276.
Crossref
Lalit K. Patil, Vilas G. Gaikar, Shekhar Kumar, U. Kamachi Mudali & R. Natarajan. (2012) Thermal Decomposition of Nitrated Tri- n -Butyl Phosphate in a Flow Reactor . ISRN Chemical Engineering 2012, pages 1-9.
Crossref
Deepak D. Dicholkar, Vilas G. Gaikar, Shekhar Kumar & R. Natarajan. (2012) Modeling and optimizing of steam pyrolysis of dimethyl formamide by using response surface methodology coupled with Box-Behnken design. Journal of Analytical and Applied Pyrolysis 96, pages 6-15.
Crossref
Po-Ching Lee, Chi-Wang Li, Jie-Yuan Chen, Ying-Sheng Li & Shiao-Shing Chen. (2011) Dissolution of D2EHPA in liquid–liquid extraction process: Implication on metal removal and organic content of the treated water. Water Research 45:18, pages 5953-5958.
Crossref
S.P. Hlushak, J.P. Simonin, B. Caniffi, P. Moisy, C. Sorel & O. Bernard. (2011) Description of partition equilibria for uranyl nitrate, nitric acid and water extracted by tributyl phosphate in dodecane. Hydrometallurgy 109:1-2, pages 97-105.
Crossref

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.