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Original Articles

Effect of Temperature on the Protonation of the TALSPEAK Ligands: Lactic and Diethylenetrinitropentaacetic Acids

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Pages 1718-1724 | Received 20 Oct 2009, Accepted 20 Mar 2010, Published online: 30 Aug 2010

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (2)

Kenneth L. Nash. (2015) The Chemistry of TALSPEAK: A Review of the Science. Solvent Extraction and Ion Exchange 33:1, pages 1-55.
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Travis S. Grimes, Richard D. Tillotson & Leigh R. Martin. (2014) Trivalent Lanthanide/Actinide Separation Using Aqueous-Modified TALSPEAK Chemistry. Solvent Extraction and Ion Exchange 32:4, pages 378-390.
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Articles from other publishers (19)

Ling Yuan, Hailun Yang, Pengge Ning, Jiawei Wen, Zhi Sun & Hongbin Cao. (2022) Green separation and recovery of cobalt and nickel from sulphuric acid achieved by complexation-assisted solvent extraction. Separation and Purification Technology 286, pages 120343.
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Peter R. Zalupski, Travis S. Grimes, Corey D. Pilgrim, Colt R. Heathman, Santa Jansone-Popova, Katherine R. Johnson, Vyacheslav Bryantsev & Robert C. ChapleskiJrJr. 2021. Including Actinides. Including Actinides 1 162 .
Mahmoud El-Maghrabey, Mohamed A. El Hamd, Rania El-Shaheny, Naoya Kishikawa & Naotaka Kuroda. 2021. Green Sustainable Process for Chemical and Environmental Engineering and Science. Green Sustainable Process for Chemical and Environmental Engineering and Science 121 147 .
Yan-Mei Chen, Cong-Zhi Wang, Qun-Yan Wu, Jian-Hui Lan, Zhi-Fang Chai, Chang-Ming Nie & Wei-Qun Shi. (2020) Complexation of trivalent lanthanides and actinides with diethylenetriaminepentaacetic acid: Theoretical unraveling of bond covalency. Journal of Molecular Liquids 299, pages 112174.
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Xingliang Li, Zhicheng Zhang, Bijun Liu, Wanjun Mu, Yuchuan Yang, Leigh R. Martin, Shunzhong Luo & Linfeng Rao. (2019) Complexation of Light Trivalent Lanthanides with N -(2-Hydroxyethyl)ethylenediamine- N , N ′, N ′-triacetic Acid in Aqueous Solutions: Thermodynamic Analysis and Coordination Modes . Inorganic Chemistry 58:22, pages 15618-15628.
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Andrej Skerencak-Frech, Franziska Taube, Pier Luigi Zanonato, Margret Acker, Petra J. Panak & Plinio Di Bernardo. (2019) A potentiometric and microcalorimetric study of the complexation of trivalent europium with lactate: The ionic strength dependency of log β’n, ΔrHm,n and ΔrSm,n. Thermochimica Acta 679, pages 178316.
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Mitchell T. Friend & Nathalie A. Wall. (2019) Stability constants for Zirconium(IV) complexes with EDTA, CDTA, and DTPA in perchloric acid solutions. Inorganica Chimica Acta 484, pages 357-367.
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Johan Schijf & Isabel J. Christy. (2018) Effect of Mg and Ca on the Stability of the MRI Contrast Agent Gd–DTPA in Seawater. Frontiers in Marine Science 5.
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Simon L. Clegg & Peter R. Zalupski. (2016) Ion Interaction Models and Measurements of Eu 3+ Complexation: DTPA in Aqueous Solutions at 25 °C Containing 1:1 Na + Salts and Malonate pH Buffer . Industrial & Engineering Chemistry Research 55:7, pages 2097-2118.
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Xingliang Li, Zhicheng Zhang, Francesco Endrizzi, Leigh R. Martin, Shunzhong Luo & Linfeng Rao. (2015) Effect of temperature on the protonation of N-(2-hydroxyethyl)ethylenediamine-N,N′,N′-triacetic acid in aqueous solutions: Potentiometric and calorimetric studies. The Journal of Chemical Thermodynamics 85, pages 35-41.
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Guoxin Tian, Zhiyong Zhang, Leigh R. Martin & Linfeng Rao. (2015) Complexation of Curium(III) with DTPA at 10–70 °C: Comparison with Eu(III)–DTPA in Thermodynamics, Luminescence, and Coordination Modes. Inorganic Chemistry 54:4, pages 1232-1239.
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Ilya A. Shkrob, Timothy W. Marin & Mark P. Jensen. (2014) Ionic Liquid Based Separations of Trivalent Lanthanide and Actinide Ions.. Industrial & Engineering Chemistry Research 53:9, pages 3641-3653.
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Xiaoqi Sun, Chi-Linh Do-Thanh, Huimin Luo & Sheng Dai. (2014) The optimization of an ionic liquid-based TALSPEAK-like process for rare earth ions separation. Chemical Engineering Journal 239, pages 392-398.
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Travis S. Grimes & Kenneth L. Nash. (2014) Acid Dissociation Constants and Rare Earth Stability Constants for DTPA. Journal of Solution Chemistry 43:2, pages 298-313.
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Mickaël Mendes, Sébastien Leguay, Claire Le Naour, Séna Hamadi, Jérôme Roques, Philippe Moisy, Dominique Guillaumont, Sylvain Topin, Jean Aupiais, Christophe Den Auwer & Christoph Hennig. (2013) Thermodynamic Study of the Complexation of Protactinium(V) with Diethylenetriaminepentaacetic Acid. Inorganic Chemistry 52:13, pages 7497-7507.
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Xiaoqi Sun, Huimin Luo & Sheng Dai. (2013) Mechanistic investigation of solvent extraction based on anion-functionalized ionic liquids for selective separation of rare-earth ions. Dalton Transactions 42:23, pages 8270.
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Travis S. Grimes, Mark P. Jensen, Lisa Debeer-Schmidt, Ken Littrell & Kenneth L. Nash. (2012) Small-Angle Neutron Scattering Study of Organic-Phase Aggregation in the TALSPEAK Process. The Journal of Physical Chemistry B 116:46, pages 13722-13730.
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Travis S. Grimes, Guoxin Tian, Linfeng Rao & Kenneth L. Nash. (2012) Optical Spectroscopy Study of Organic-Phase Lanthanide Complexes in the TALSPEAK Separations Process. Inorganic Chemistry 51:11, pages 6299-6307.
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Guoxin Tian, Leigh R. Martin & Linfeng Rao. (2010) Complexation of Lactate with Neodymium(III) and Europium(III) at Variable Temperatures: Studies by Potentiometry, Microcalorimetry, Optical Absorption, and Luminescence Spectroscopy. Inorganic Chemistry 49:22, pages 10598-10605.
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