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Original Articles

Solution Behavior of Poly(n-Isopropylacrylamide) in Water: Effect of Additives

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Pages 1111-1118 | Received 09 Apr 2010, Accepted 27 Apr 2010, Published online: 28 Jul 2011

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (4)

Ceyda Şimşek & Candan Erbil. (2022) Poly(N-isopropylacrylamide) based pH- and temperature-sensitive ampholytic hydrogels with tunable mechanical, swelling and drug release properties. International Journal of Polymeric Materials and Polymeric Biomaterials 71:15, pages 1148-1163.
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Fatıma Cemre Şahin, Ceyda Şimşek & Candan Erbil. (2021) Study on preparation, compression strength and theophylline/diclofenac sodium release ability of NIPAAm/DMAPMAAm hydrogels. Journal of Biomaterials Science, Polymer Edition 32:17, pages 2267-2292.
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Maria Andrei, Gabriel Turturica, Paul O. Stanescu & Mircea Teodorescu. (2016) Thermosensitive injectable hydrogels from poly(N-isopropylacrylamide)–dextran aqueous solutions: Thermogelation and drug release properties. Soft Materials 14:3, pages 162-169.
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Zhiguo Zhang, Peizhu Zheng, Dongxing Cai, Xueqin An & Weiguo Shen. (2014) Interaction of Ionic Surfactants with a Hydrophobic Modified Thermosensitive Polymer. Journal of Dispersion Science and Technology 35:5, pages 695-705.
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Articles from other publishers (29)

Jason D. Linn, Fabian A. Rodriguez & Michelle A. Calabrese. (2024) Cosolvent incorporation modulates the thermal and structural response of PNIPAM/silyl methacrylate copolymers. Soft Matter 20:15, pages 3322-3336.
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Jasmin Simons, Nabanita Hazra, Alexander V. Petrunin, Jérôme J. Crassous, Walter Richtering & Max Hohenschutz. (2024) Nonionic Microgels Adapt to Ionic Guest Molecules: Superchaotropic Nanoions. ACS Nano 18:10, pages 7546-7557.
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Isaac J. Gresham, Edwin C. Johnson, Hayden Robertson, Joshua D. Willott, Grant B. Webber, Erica J. Wanless, Andrew R.J. Nelson & Stuart W. Prescott. (2024) Comparing polymer-surfactant complexes to polyelectrolytes. Journal of Colloid and Interface Science 655, pages 262-272.
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Mafumi Hishida, Rikuto Kanno & Takaya Terashima. (2023) Hydration State on Poly(ethylene glycol)-Bearing Homopolymers and Random Copolymer Micelles: In Relation to the Thermoresponsive Property and Micellar Structure. Macromolecules 56:18, pages 7587-7596.
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Isaac J. Gresham, Joshua D. Willott, Edwin C. Johnson, Peixun Li, Grant B. Webber, Erica J. Wanless, Andrew R.J. Nelson & Stuart W. Prescott. (2023) Effect of surfactants on the thermoresponse of PNIPAM investigated in the brush geometry. Journal of Colloid and Interface Science 631, pages 260-271.
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Long Bai, Yong Jin, Xiang Shang, Hongyu Jin, Wenhua Zeng & Liangjie Shi. (2023) Dual thermo-responsive multifunctional ionic conductive hydrogel by salt modulation strategy for multilevel encryption and visual monitoring. Chemical Engineering Journal 456, pages 141082.
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A. D. Drozdov & J. deClaville Christiansen. (2022) Swelling of Thermo-Responsive Gels in Aqueous Solutions of Salts: A Predictive Model. Molecules 27:16, pages 5177.
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Jéssica Bassi da Silva, Peter Haddow, Marcos Luciano Bruschi & Michael Thomas Cook. (2022) Thermoresponsive poly(di(ethylene glycol) methyl ether methacrylate)-ran-(polyethylene glycol methacrylate) graft copolymers exhibiting temperature-dependent rheology and self-assembly. Journal of Molecular Liquids 346, pages 117906.
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Jelena Tsurko & Werner Kunz. (2021) SALTING-IN AND SALTING-OUT EFFECTS OF POLYPHENOLS, AROMATIC COMPOUNDS, AND AMINO ACIDS ON POLY (N-ISOPROPYLACRYLAMIDE) AND EGG WHITE AQUEOUS SOLUTIONS. Science and Innovation 17:4, pages 72-78.
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Sachit Shah & Lorraine Leon. (2021) Structural dynamics, phase behavior, and applications of polyelectrolyte complex micelles. Current Opinion in Colloid & Interface Science 53, pages 101424.
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Jagoda Litowczenko, Jacek Gapiński, Roksana Markiewicz, Anna Woźniak, Jacek K. Wychowaniec, Barbara Peplińska, Stefan Jurga & Adam Patkowski. (2021) Synthesis, characterization and in vitro cytotoxicity studies of poly-N-isopropyl acrylamide gel nanoparticles and films. Materials Science and Engineering: C 118, pages 111507.
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Ilse A. van Hees, Anton H. Hofman, Marco Dompé, Jasper van der Gucht & Marleen Kamperman. (2020) Temperature-responsive polyelectrolyte complexes for bio-inspired underwater adhesives. European Polymer Journal 141, pages 110034.
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Paul O. Stănescu, Ionuţ C. Radu, Constantin Drăghici & Mircea Teodorescu. (2020) Controlling the thermal response of poly(N-isopropylacrylamide)-poly(ethylene glycol)- poly(N-isopropylacrylamide) triblock copolymers in aqueous solution by means of additives. Reactive and Functional Polymers 152, pages 104610.
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Payal Narang, Tiago E. de Oliveira, Pannuru Venkatesu & Paulo A. Netz. (2020) The role of osmolytes in the temperature-triggered conformational transition of poly( N -vinylcaprolactam): an experimental and computational study . Physical Chemistry Chemical Physics 22:9, pages 5301-5313.
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Sachit Shah & Lorraine Leon. (2019) Structural transitions and encapsulation selectivity of thermoresponsive polyelectrolyte complex micelles. Journal of Materials Chemistry B 7:41, pages 6438-6448.
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I. A. van Hees, P. J. M. Swinkels, R. G. Fokkink, A. H. Velders, I. K. Voets, J. van der Gucht & M. Kamperman. (2019) Self-assembly of oppositely charged polyelectrolyte block copolymers containing short thermoresponsive blocks. Polymer Chemistry 10:23, pages 3127-3134.
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Anna Karatza & Stergios Pispas. (2018) Poly(hydroxyl propyl methacrylate)‐ b ‐Poly(oligo ethylene glycol methacrylate) Thermoresponsive Block Copolymers by RAFT Polymerization . Macromolecular Chemistry and Physics 219:12.
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Andleeb Z. Naqvi & Kabir-ud-Din. (2018) Clouding phenomenon in amphiphilic systems: A review of five decades. Colloids and Surfaces B: Biointerfaces 165, pages 325-344.
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Maria Andrei, Paul O. Stǎnescu, Constantin Drǎghici & Mircea Teodorescu. (2017) Degradable thermosensitive injectable hydrogels with two-phase composite structure from aqueous solutions of poly(N-isopropylacrylamide-co-5,6-benzo-2-methylene-1,3-dioxepane)—poly(ethylene glycol) triblock copolymers and biopolymers. Colloid and Polymer Science 295:10, pages 1805-1816.
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Payal Narang & Pannuru Venkatesu. (2017) New endeavours involving the cooperative behaviour of TMAO and urea towards the globular state of poly(N-isopropylacrylamide). RSC Advances 7:54, pages 34023-34033.
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Timothy J. Murdoch, Ben A. Humphreys, Joshua D. Willott, Kasimir P. Gregory, Stuart W. Prescott, Andrew Nelson, Erica J. Wanless & Grant B. Webber. (2016) Specific Anion Effects on the Internal Structure of a Poly( N -isopropylacrylamide) Brush . Macromolecules 49:16, pages 6050-6060.
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Gabriel Turturicǎ, Maria Andrei, Paul O. Stǎnescu, Constantin Drǎghici, Dumitru Mircea Vuluga, Anamaria Zaharia, Andrei Sârbu & Mircea Teodorescu. (2016) ABA triblock copolymers of poly(N-isopropylacrylamide-co-5,6-benzo-2-methylene -1,3-dioxepane) (A) and poly(ethylene glycol) (B): synthesis and thermogelation and degradation properties in aqueous solutions. Colloid and Polymer Science 294:4, pages 743-753.
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Ben A. Humphreys, Joshua D. Willott, Timothy J. Murdoch, Grant B. Webber & Erica J. Wanless. (2016) Specific ion modulated thermoresponse of poly(N-isopropylacrylamide) brushes. Physical Chemistry Chemical Physics 18:8, pages 6037-6046.
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Maria C.M. Costa, Sérgio M.C. Silva & Filipe E. Antunes. (2015) Adjusting the low critical solution temperature of poly(N-isopropyl acrylamide) solutions by salts, ionic surfactants and solvents: A rheological study. Journal of Molecular Liquids 210, pages 113-118.
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M. Khimani, S. Yusa, A. Nagae, R. Enomoto, V.K. Aswal, E. Kesselman, D. Danino & P. Bahadur. (2015) Self-assembly of multi-responsive poly(N-isopropylacrylamide)-b-poly(N,N-dimethylaminopropylacrylamide) in aqueous media. European Polymer Journal 69, pages 96-109.
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Hui Guo, Annie Brûlet, Pattuparambil R. Rajamohanan, Alba Marcellan, Nicolas Sanson & Dominique Hourdet. (2015) Influence of topology of LCST-based graft copolymers on responsive assembling in aqueous media. Polymer 60, pages 164-175.
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Bastian EbelingBastian Ebeling. 2015. Smart Nanohybrids of RAFT Polymers and Inorganic Particles. Smart Nanohybrids of RAFT Polymers and Inorganic Particles 171 198 .
Bastian EbelingBastian Ebeling. 2015. Smart Nanohybrids of RAFT Polymers and Inorganic Particles. Smart Nanohybrids of RAFT Polymers and Inorganic Particles 3 51 .
Bastian Ebeling, Steffen Eggers, Michael Hendrich, Annika Nitschke & Philipp Vana. (2014) Flipping the Pressure- and Temperature-Dependent Cloud-Point Behavior in the Cononsolvency System of Poly( N -isopropylacrylamide) in Water and Ethanol . Macromolecules 47:4, pages 1462-1469.
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