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Original Articles

Imidazole-2-Thiones: Synthesis, Structure, Properties

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Pages 389-421 | Received 31 Jan 1990, Published online: 04 Oct 2006

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John R. Miecznikowski, Matthew A. Lynn, Jerry P. Jasinski, Eric Reinheimer, Daniel W. Bak, Mekhala Pati, Elizabeth E. Butrick, Anne Elise R. Drozdoski, Kerry A. Archer, Christine E. Villa, Elise G. Lemons, Erin Powers, Margaret Siu, Camile D. Gomes & Kaitlyn N. Morio. (2014) Synthesis, characterization, and computational study of three-coordinate SNS-copper(I) complexes based on bis-thione precursors. Journal of Coordination Chemistry 67:1, pages 29-44.
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Articles from other publishers (41)

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Ola A. Abu Ali, W. Abd El-Fattah, Mohammad Y. Alfaifi, Ali A. Shati, Serag Eldin I. Elbehairi, Ali H. Abu Almaaty, Reda F.M. Elshaarawy & Eman Fayad. (2023) New Mn(III)/Fe(III) complexes with thiohydantoin-supported imidazolium ionic liquids for breast cancer therapy. Inorganica Chimica Acta 551, pages 121460.
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Lamia A. Ismail, R. Zakaria, Eman M. Hassan, Mohammad Y. Alfaifi, Ali A. Shati, Serag Eldin I. Elbehairi, A. A. El-Bindary & Reda F. M. Elshaarawy. (2022) Novel imidazolium-thiohydantoin hybrids and their Mn( iii ) complexes for antimicrobial and anti-liver cancer applications . RSC Advances 12:44, pages 28364-28375.
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Gülşah KURT & Fatih SEVGİ. (2022) Synthesis and Biological Evaluation of Imidazole-2-thione Fused Furazan as a New Biheterocyclic ScaffoldYeni İki Hetero halkalı Bir Yapı Olarak İmidazol-2-tiyon ile Kaynaşmış Furazan Sentezi ve Biyolojik Değerlendirmesi. Düzce Üniversitesi Bilim ve Teknoloji Dergisi 10:1, pages 14-26.
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Andrey N. Komogortsev, Valeriya G. Melekhina, Boris V. Lichitsky & Mikhail E. Minyaev. (2021) Multicomponent one‐pot synthesis of novel imidazole‐2‐thione derivatives containing allomaltol fragment . Journal of Heterocyclic Chemistry 58:3, pages 864-872.
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Deepika Rani, Gursharan Singh & Seema Sharma. (2021) Reactions of MoO2Cl2 and MoOCl4 with 2-Mercaptopyridine, 4-Phenylimidazole-2-thiol and 6-Mercaptopurine Monohydrate. Oriental Journal Of Chemistry 37:1, pages 46-52.
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Deepika Rani. (2020) Reactions of MoCl5 and MoO2Cl2 with 4-Phenylimidazole-2-thiol and 2-Thiazoline-2-thiol. Oriental Journal Of Chemistry 36:6, pages 1096-1102.
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Diego Plaza‐Lozano, Daniel Morales‐Martínez, Felipe J. González & Juan Olguín. (2020) Homoleptic Mononuclear Tris‐Chelate Complexes of Fe II , Co II , Ni II , and Zn II Based on a Redox‐Active Imidazolyl‐2‐thione Ligand: Structural and Electrochemical Correlation . European Journal of Inorganic Chemistry 2020:17, pages 1562-1573.
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Patrick J. Quinlivan, Mahnaz Rostami Chaijan, Joshua H. Palmer, Daniel G. Shlian & Gerard Parkin. (2019) Coordination of 1-methyl-1,3-dihydro-2H-benzimidazole-2-selone to zinc and cadmium: Monotonic and non-monotonic bond length variations for [H(sebenzimMe)]2MCl2 complexes (M = Zn, Cd, Hg). Polyhedron 164, pages 185-194.
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Mohamed Farag, Wael Abdel-Mageed, Omer Basudan & Ali El-Gamal. (2018) Persicaline, A New Antioxidant Sulphur-Containing Imidazoline Alkaloid from Salvadora persica Roots. Molecules 23:2, pages 483.
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D. M. Egorov, Yu. L. Piterskaya, E. B. Erkhitueva, N. I. Svintsitskaya & A. V. Dogadina. (2017) 3-Phosphorylated thioazoles. Russian Journal of General Chemistry 87:9, pages 1924-1933.
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D. Yancheva, S. Stoyanov, N. Anastassova & A.Ts. Mavrova. (2017) IR study on the electrochemical generation of a nitro radical anion by a hepatotoxic N,N′-disubstituted benzimidazole-2-thione. Vibrational Spectroscopy 92, pages 200-214.
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Mehbub I. K. Momin, Deresh Ramjugernath, Rebamang A. Mosa, Andrew R. Opoku & Neil A. Koorbanally. (2014) Synthesis and in vitro antiplatelet aggregation screening of novel fluorinated diethyl-2-(benzylthio)-2,3-dihydro-1H-imidazole-4,5-dicarboxylate derivatives. Medicinal Chemistry Research 24:5, pages 2075-2084.
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Joshua H. Palmer & Gerard Parkin. (2015) Protolytic Cleavage of Hg–C Bonds Induced by 1-Methyl-1,3-dihydro-2 H -benzimidazole-2-selone: Synthesis and Structural Characterization of Mercury Complexes . Journal of the American Chemical Society 137:13, pages 4503-4516.
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Joshua H. Palmer & Gerard Parkin. (2014) Synthesis and structural characterization of 1-arylimidazole-2-thiones and N,N′-aryldiethoxyethylthioureas with electronically diverse substituents: a manifold of hydrogen bonding networks. New Journal of Chemistry 38:9, pages 4071.
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Paresh Kumar Majhi, Susanne Sauerbrey, Alexander Leiendecker, Gregor Schnakenburg, Anthony J. Arduengo III & Rainer Streubel. (2013) Synthesis and first complexes of C4/5 P-bifunctional imidazole-2-thiones. Dalton Transactions 42:36, pages 13126.
Crossref
Zvi RappoportM. T. Molina, M. Yáñez, O. Mó, R. Notario & J.‐L. M. Abboud. 2010. Patai's Chemistry of Functional Groups. Patai's Chemistry of Functional Groups.
Derek M. Wolfe & Peter R. Schreiner. (2007) Oxidative Desulfurization of Azole‐2‐thiones with Benzoyl Peroxide: Syntheses of Ionic Liquids and Other Azolium Salts. European Journal of Organic Chemistry 2007:17, pages 2825-2838.
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Wolfgang Kirmse. (2005) Carbene Complexes of Nonmetals. European Journal of Organic Chemistry 2005:2, pages 237-260.
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Agnieszka Majchrzak, Aleksandra Janczak, Grzegorz Mlostoń, Anthony Linden & Heinz Heimgartner. (2003) Reactions of Stable α ‐Chlorosulfanyl Chlorides with CS‐Functionalized Compounds . Helvetica Chimica Acta 86:6, pages 2272-2283.
Crossref
E D Shtefan & V Yu Vvedenskii. (1996) The tautomerism of heterocyclic thiols. Five-membered heterocycles. Russian Chemical Reviews 65:4, pages 307-314.
Crossref
B. V. Trzhtsinskaya, A. E. Aleksandrova, N. D. Abramova, L. V. Andriyankova, T. I. Vinogradova & R. A. Shchegoleva. (1992) Synthesis and tuberculostatic activity of derivatives of imidazole-2-thiones. Pharmaceutical Chemistry Journal 26:4, pages 346-349.
Crossref
B. V. TRZHTSINSKAYA & N. D. ABRAMOVA. (2010) ChemInform Abstract: Imidazole‐2‐thiones: Synthesis, Structure, Properties. ChemInform 22:51.
Crossref
Linta Mary Jose & Susmita De. (2021) Electronic Structure and Bonding in N-Hetero Cyclic Carbene Stabilized Naked Group 16 Atoms – In-Plane Hyperconjugation and Bond Polarity. SSRN Electronic Journal.
Crossref

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