Publication Cover
Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 28, 2007 - Issue 1-2
357
Views
89
CrossRef citations to date
0
Altmetric
Original Articles

ORTHO-PALLADATION OF PRIMARY AMINES: THE MYTH DISPELLED

&
Pages 39-72 | Published online: 25 May 2007

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (2)

A. M. Nassar. (2016) Bioactive Palladium Azomethine Chelates, a Review of Recent Research. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 46:9, pages 1349-1366.
Read now
Kazem Karami, Sara Amouzad, Mahboubeh Hosseini-Kharat & Corrado Rizzoli. (2013) Synthesis, spectral characterization, and X-ray crystal structure of Pd(II) complexes containing the orthometallated C,C-chelating ligand C6H4-PPh2C(H)C(O)CH2Cl. Journal of Coordination Chemistry 66:10, pages 1774-1783.
Read now

Articles from other publishers (87)

Rashmi V. Shenoy, Peter G. Jones, José Vicente & Eloísa Martínez-Viviente. (2023) Synthesis of mono-, di- and tripalladated 1,3,5-benzenetristyryl complexes. CO insertion to give a dipalladated indenone. Dalton Transactions 52:12, pages 3786-3794.
Crossref
Pratibha Chand-Thakuri, Indunil Alahakoon, Daniel Liu, Mohit Kapoor, John F. Kennedy, Kenneth W. JenkinsIIIIII, Allison M. Rabon & Michael C. Young. (2021) Native Amine-Directed ortho-C–H Halogenation and Acetoxylation /Condensation of Benzylamines. Synthesis 54:02, pages 341-354.
Crossref
Alexia Ville, Julien Annibaletto, Sébastien Coufourier, Christophe Hoarau, Rodolphe Tamion, Guillaume Journot, Cédric Schneider & Jean‐François Brière. (2021) Amine‐Directed Palladium‐Catalyzed C−H Halogenation of Phenylalanine Derivatives. Chemistry – A European Journal 27:56, pages 13961-13965.
Crossref
Aurélien Jacquin-Labarre, Sébastien Coufourier, Rodolphe Tamion, Alexandra Le Foll, Vincent Levacher, Carlos Afonso, Vincent Gandon, Guillaume Journot, Jean-François Brière & Christophe Hoarau. (2020) Base-Assisted Intramolecular C–N Coupling Reaction from NH 2 -Bound Cyclopalladated l -Phenylalanine to Indoline-2-carboxylic Acid . Organometallics 39:5, pages 767-773.
Crossref
Miguel Clemente, Ibrahim Halil Polat, Joan Albert, Ramon Bosque, Margarita Crespo, Jaume Granell, Concepción López, Manuel Martínez, Josefina Quirante, Ramon Messeguer, Carme Calvis, Josefa Badía, Laura Baldomà, Mercè Font-Bardia & Marta Cascante. (2018) Platinacycles Containing a Primary Amine Platinum(II) Compounds for Treating Cisplatin-Resistant Cancers by Oxidant Therapy. Organometallics 37:20, pages 3502-3514.
Crossref
Adolfo Fernández‐Figueiras, Fátima Lucio‐Martínez, Paula Munín‐Cruz, Juan M. Ortigueira, Paula Polo‐Ces, Francisco Reigosa, M. Teresa Pereira & José M. Vila. (2018) From Chemical Serendipity to Translational Chemistry: New Findings in the Reactivity of Palladacycles. ChemistryOpen 7:10, pages 754-763.
Crossref
Yutaka Tanji, Naoya Mitsutake, Tetsuaki Fujihara & Yasushi Tsuji. (2018) Steric Effect of Carboxylate Ligands on Pd‐Catalyzed Intramolecular C(sp 2 )–H and C(sp 3 )–H Arylation Reactions . Angewandte Chemie International Edition 57:32, pages 10314-10317.
Crossref
Yutaka Tanji, Naoya Mitsutake, Tetsuaki Fujihara & Yasushi Tsuji. (2018) Steric Effect of Carboxylate Ligands on Pd‐Catalyzed Intramolecular C(sp 2 )–H and C(sp 3 )–H Arylation Reactions . Angewandte Chemie 130:32, pages 10471-10474.
Crossref
László B. Balázs, Wee Shan Tay, Yongxin Li, Sumod A. Pullarkat & Pak-Hing Leung. (2018) Synthesis of Stereoprojecting, Chiral N-C(sp 3 )-E Type Pincer Complexes . Organometallics 37:14, pages 2272-2285.
Crossref
Houguang Jeremy Chen, Ronald Hong Xiang Teo, Yongxin Li, Sumod A. Pullarkat & Pak-Hing Leung. (2017) Stereogenic Lock in 1-Naphthylethanamine Complexes for Catalyst and Auxiliary Design: Structural and Reactivity Analysis for Cycloiridated Pseudotetrahedral Complexes. Organometallics 37:1, pages 99-106.
Crossref
Iwao Omae. (2017) Applications of six-membered ring products from cyclometalation reactions. Journal of Organometallic Chemistry 848, pages 184-195.
Crossref
Kazem Karami, Sara Hashemi, Janusz Lipkowski, Fatemeh Mardani, Amir Abbas Momtazi‐borojeni & Zohreh Mehri Lighvan. (2017) Synthesis, characterization and biological activities of two novel orthopalladated complexes: Interactions with DNA and bovine serum albumin, antitumour activity and molecular docking studies. Applied Organometallic Chemistry 31:10.
Crossref
José Antonio García-López, Roberto Frutos-Pedreño, Delia Bautista, Isabel Saura-Llamas & José Vicente. (2016) Norbornadiene as a Building Block for the Synthesis of Linked Benzazocinones and Benzazocinium Salts through Tetranuclear Carbopalladated Intermediates. Organometallics 36:2, pages 372-383.
Crossref
Ismael Marcos, Vicente Ojea, Digna Vázquez-García, Jesús J. Fernández, Alberto Fernández, Margarita López-Torres, Jorge Lado & José M. Vila. (2017) Preparation and characterization of terdentate [C,N,N] acetophenone and acetylpyridine hydrazone platinacycles: a DFT insight into the reaction mechanism. Dalton Transactions 46:48, pages 16845-16860.
Crossref
Iwao Omae. (2016) Application of five-membered ring products of cyclometalation reactions as sensing materials in sensing devices. Journal of Organometallic Chemistry 823, pages 50-75.
Crossref
Shuguang Zhou, Jinhu Wang, Pei Chen, Kehao Chen & Jin Zhu. (2016) Ruthenium(II)‐Catalyzed Traceless C−H Functionalization Using an N−N Bond as an Internal Oxidant. Chemistry – A European Journal 22:41, pages 14508-14512.
Crossref
Pallavi Agarwal, Natesan Thirupathi & Munirathinam Nethaji. (2016) Syntheses, Structural Aspects, Solution Behavior, and Catalytic Utility of Cyclopalladated N,N ′ ,N ″-Triarylguanidines [κ 2 ( C , N ))Pd(Pyrazole) 2 X] (X = Br, OC(O)CF 3 , and PF 6 ) in Suzuki–Miyaura Coupling Reactions of Aryl Bromides . Organometallics 35:18, pages 3112-3123.
Crossref
Joan Albert, Ramon Bosque, Lucía D’Andrea, José Antonio Durán, Jaume Granell, Mercè Font-Bardia & Teresa Calvet. (2016) Synthesis and crystal structure of the dinuclear cyclopalladated compounds of methyl ( E )-4-(benzylideneamino)benzoate with acetato and chlorido bridge ligands: Study of their splitting reactions with pyridine. Journal of Organometallic Chemistry 815-816, pages 44-52.
Crossref
Roberto Frutos-Pedreño, Eva García-Sánchez, María José Oliva-Madrid, Delia Bautista, Eloísa Martínez-Viviente, Isabel Saura-Llamas & José Vicente. (2016) C–H Activation in Primary 3-Phenylpropylamines: Synthesis of Seven-Membered Palladacycles through Orthometalation. Stoichiometric Preparation of Benzazepinones and Catalytic Synthesis of Ureas. Inorganic Chemistry 55:11, pages 5520-5533.
Crossref
Inmaculada Vicente-Hernandez, María-Teresa Chicote, José Vicente & Delia Bautista. (2016) Synthesis of Aryl-, Benzoyl-, and Iminobenzoyl-Palladium(II) Complexes Derived from N -Phenyl Formamide. Synthesis of a Homoleptic Ball-Shaped Tetranuclear Palladium Complex . Organometallics 35:8, pages 1107-1113.
Crossref
Iwao Omae. (2016) Application of the five-membered ring blue light-emitting iridium products of cyclometalation reactions as OLEDs. Coordination Chemistry Reviews 310, pages 154-169.
Crossref
Iwao Omae. (2016) Applications of Cyclometalation Five-Membered Ring Products and Intermediates as Catalytic Agents. Modern Research in Catalysis 05:03, pages 51-74.
Crossref
María-José Fernández-Rodríguez, Eloísa Martínez-Viviente, José Vicente & Peter G. Jones. (2016) Reactivity towards nitriles, cyanamides, and carbodiimides of palladium complexes derived from benzyl alcohol. Synthesis of a mixed Pd 2 Ag complex . Dalton Transactions 45:2, pages 820-830.
Crossref
Leticia Naya, Digna Vázquez‐García, Alberto Fernández, Margarita López‐Torres, Vicente Ojea, Ismael Marcos, José M. Vila & Jesús J. Fernández. (2015) Preparation of Imidazol‐2‐ylidene Carbene Palladacycles with Bi‐ and Tridentate Schiff Bases – Analyses of the Spectroscopic, Molecular Structure, and DFT Calculation Data. European Journal of Inorganic Chemistry 2016:3, pages 422-431.
Crossref
María-José Fernández-Rodríguez, Eloísa Martínez-Viviente, José Vicente & Peter G. Jones. (2015) Synthesis of Arylpalladium(II) Complexes Derived from Benzyl Alcohol, Reactivity toward Alkyl Halides, and Synthesis of Dinuclear Arylpalladium(II) Complexes. Organometallics 34:13, pages 3282-3291.
Crossref
Marı́a-José Fernández-Rodrı́guez, Eloı́sa Martı́nez-Viviente, José Vicente & Peter G. Jones. (2014) Mono- and Dipalladated Derivatives of 2,5-Distyrylbenzene. Reactivity toward XyNC and Alkynes. Synthesis of Complexes with Indacenediide Ligands. Organometallics 34:11, pages 2240-2254.
Crossref
Minliang Li, Haibin Song & Baiquan Wang. (2015) Synthesis, Structures, and Norbornene Polymerization Behavior of N-Heterocyclic Carbene-Sulfonate-Ligated Palladacycles. Organometallics 34:10, pages 1969-1977.
Crossref
Vadim P. Boyarskiy, Nadezhda A. Bokach, Konstantin V. Luzyanin & Vadim Yu. Kukushkin. (2015) Metal-Mediated and Metal-Catalyzed Reactions of Isocyanides. Chemical Reviews 115:7, pages 2698-2779.
Crossref
Joan Albert, Ramon Bosque, Margarita Crespo, Jaume Granell, Concepción López, Raquel Martín, Asensio González, Anusha Jayaraman, Josefina Quirante, Carme Calvis, Josefa Badía, Laura Baldomà, Mercè Font-Bardia, Marta Cascante & Ramon Messeguer. (2015) Neutral and ionic platinum compounds containing a cyclometallated chiral primary amine: synthesis, antitumor activity, DNA interaction and topoisomerase I–cathepsin B inhibition. Dalton Transactions 44:30, pages 13602-13614.
Crossref
Leticia Naya, Digna Vázquez-García, Alberto Fernández, Margarita López-Torres, Ismael Marcos, Oscar A. Lenis, M. Teresa Pereira, José M. Vila & Jesús J. Fernández. (2014) Novel palladacycle N-heterocyclic carbene complexes with bidentate [C,N] and terdentate [C,N,N] and [C,N,O] Schiff bases. Synthesis, characterization and crystal structure analysis. Journal of Organometallic Chemistry 772-773, pages 192-201.
Crossref
William Raven, Pol Hermes, Irmgard Kalf, Jörn Schmaljohann & Ulli Englert. (2014) A cationic aqua complex of an orthoplatinated primary amine – A versatile intermediate for derivatization. Journal of Organometallic Chemistry 766, pages 34-39.
Crossref
Miguel Guerrero, José Antonio Perez, Josep Ros & Josefina Pons. (2014) Synthesis and structural characterization of new cyclopalladated compounds containing hybrid pyrazole ligands. Inorganic Chemistry Communications 46, pages 234-236.
Crossref
L. Canovese, F. Visentin, C. Santo & V. Bertolasi. (2014) Insertion of Isocyanides across the Pd–C Bond of Phosphinoquinoline Allyl Palladium Complexes Bearing η 1 - and η 3 -Coordinated Allyl Groups. A Synthetic and Mechanistic Study . Organometallics 33:7, pages 1700-1709.
Crossref
Kazem Karami, Mahboubeh Hosseini-Kharat, Corrado Rizzoli, Hossein Tavakol & Janusz Lipkowski. (2014) Structural and theoretical studies of mono and di-insertion of symmetric alkynes into the Pd–C σ bond of cyclopalladated secondary (tert-butyl and ethyl) benzylamines. Journal of Organometallic Chemistry 752, pages 152-160.
Crossref
María-José Oliva-Madrid, José-Antonio García-López, Isabel Saura-Llamas, Delia Bautista & José Vicente. (2013) Reactivity toward Neutral N- and P-Donor Ligands of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C Bond of Orthopalladated Homoveratrylamine and Phentermine. A New Example of the Transphobia Effect. Organometallics 33:1, pages 33-39.
Crossref
Huanfeng Jiang, Hanling Gao, Bifu Liu & Wanqing Wu. (2014) Synthesis of 6-aminophenanthridines via palladium-catalyzed insertion of isocyanides into N-sulfonyl-2-aminobiaryls. RSC Adv. 4:33, pages 17222-17225.
Crossref
Helena Font, Mercè Font-Bardia, Kerman Gómez, Gabriel González, Jaume Granell, Israel Macho & Manuel Martínez. (2014) A kinetico-mechanistic study on the C–H bond activation of primary benzylamines; cooperative and solid-state cyclopalladation on dimeric complexes. Dalton Transactions 43:36, pages 13525.
Crossref
Iwao OmaeIwao Omae. 2014. Cyclometalation Reactions. Cyclometalation Reactions 1 9 .
Antonio Abellán-López, María-Teresa Chicote, Delia Bautista & José Vicente. (2013) Cyclopalladated Complexes Derived from Phenylacetone Oxime. Insertion Reactions of Carbon Monoxide, Isocyanides, and Alkynes. Novel Amidines of the Isoquinoline Series. Organometallics 32:24, pages 7612-7624.
Crossref
Eduardo Laga, Angel García‐Montero, Francisco J. Sayago, Tatiana Soler, Salvador Moncho, Carlos Cativiela, Manuel Martínez & Esteban P. Urriolabeitia. (2013) Cyclopalladation and Reactivity of Amino Esters through CH Bond Activation: Experimental, Kinetic, and Density Functional Theory Mechanistic Studies. Chemistry – A European Journal 19:51, pages 17398-17412.
Crossref
Tim Kluge, Martin Bette, Tobias Rüffer, Clemens Bruhn, Christoph Wagner, Dieter Ströhl, Jürgen Schmidt & Dirk Steinborn. (2013) Activation of Acetyl Ligands through Hydrogen Bonds: A New Way to Platinum(II) Complexes Bearing Protonated Iminoacetyl Ligands. Organometallics 32:23, pages 7090-7106.
Crossref
Pedro Villuendas & Esteban P. Urriolabeitia. (2013) Primary Amines as Directing Groups in the Ru-Catalyzed Synthesis of Isoquinolines, Benzoisoquinolines, and Thienopyridines. The Journal of Organic Chemistry 78:11, pages 5254-5263.
Crossref
Sara Sabater, Jose A. Mata & Eduardo Peris. (2013) Chiral Palladacycles with N-Heterocyclic Carbene Ligands as Catalysts for Asymmetric Hydrophosphination. Organometallics 32:4, pages 1112-1120.
Crossref
Joan Albert, Xavier Ariza, Teresa Calvet, Mercé Font-Bardia, Jordi Garcia, Jaume Granell, Andrea Lamela, Blanca López, Manuel Martinez, Laura Ortega, Aleix Rodriguez & David Santos. (2013) NH 2 As a Directing Group: From the Cyclopalladation of Amino Esters to the Preparation of Benzolactams by Palladium(II)-Catalyzed Carbonylation of N-Unprotected Arylethylamines . Organometallics 32:2, pages 649-659.
Crossref
Nicholas C. Bruno, Matthew T. Tudge & Stephen L. Buchwald. (2013) Design and preparation of new palladium precatalysts for C–C and C–N cross-coupling reactions. Chem. Sci. 4:3, pages 916-920.
Crossref
Kate F. Donnelly, Ralte Lalrempuia, Helge Müller-Bunz & Martin Albrecht. (2012) Regioselective Electrophilic C–H Bond Activation in Triazolylidene Metal Complexes Containing a N-Bound Phenyl Substituent. Organometallics 31:23, pages 8414-8419.
Crossref
José-Antonio García-López, Isabel Saura-Llamas, John E. McGradyDelia Bautista & José Vicente. (2012) Insertion of Allenes into the Pd–C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, ( l )-Phenylalanine Methyl Ester, and ( l )-Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts . Organometallics 31:23, pages 8333-8347.
Crossref
María-José Oliva-Madrid, José-Antonio Garcı́a-López, Isabel Saura-Llamas, Delia Bautista & José Vicente. (2012) Ortho Palladation of the Phenethylamines of Biological Relevance l -Tyrosine Methyl Ester and Homoveratrylamine. Reactivity of the Palladacycles toward CO and Isocyanides. Synthesis of the Natural Alkaloid Corydaldine . Organometallics 31:9, pages 3647-3660.
Crossref
A.R. Balavardhana Rao & Samudranil Pal. (2012) Cyclopalladated complexes with 9-anthraldehyde aroylhydrazones: Synthesis, properties and structures. Journal of Organometallic Chemistry 701, pages 62-67.
Crossref
Jackson M. Chitanda, Shih-Chang Wu, J. Wilson Quail & Stephen R. Foley. (2011) Synthesis of mixed N,N′-(Ar,Ar′-diaryl)iminoisoindolines for applications in palladacycle formations. Inorganica Chimica Acta 379:1, pages 122-129.
Crossref
Chen Xu, Zhi‐Qiang Wang, Ya‐Peng Zhang, Xin‐Ming Dong, Xin‐Qi Hao, Wei‐Jun Fu, Bao‐Ming Ji & Mao‐Ping Song. (2011) Synthesis and Structural Characterization of Palladacycles with Polydentate Ligands by a Stepwise Coupling Route – Palladacycles Containing Halides as Efficient Catalysts and Substrates. European Journal of Inorganic Chemistry 2011:31, pages 4878-4888.
Crossref
José Vicente, Isabel Saura-Llamas, María-José Oliva-Madrid, José-Antonio García-López & Delia Bautista. (2011) A New Method for High-Yield Cyclopalladation of Primary and Secondary Amines. Atom-Efficient Open-to-Air Inexpensive Synthesis of Buchwald-Type Precatalysts. Organometallics 30:17, pages 4624-4631.
Crossref
José Vicente, Rashmi V. Shenoy, Eloísa Martínez-Viviente & Peter G. Jones. (2011) Synthesis of Pd 3 Tl and Pd 6 Tl 2 Complexes Based on a Trinuclear Aryl–Palladium(II) Complex Acting as a Metallaligand Toward Thallium(I) Through Tl–Arene and Tl–I Bonds . Inorganic Chemistry 50:15, pages 7189-7194.
Crossref
A.R. Balavardhana Rao & Samudranil Pal. (2011) Cyclopalladation of indole-3-carboxaldehyde aroylhydrazones. Journal of Organometallic Chemistry 696:13, pages 2660-2664.
Crossref
Kazem Karami & Mina Mohamadi Salah. (2011) Oxygen- versus carbon-coordination of the alpha-stabilized phosphorus ylide Ph3P=C(H)R in palladacycles bearing secondary amines. Transition Metal Chemistry 36:4, pages 363-367.
Crossref
Octavia A. BlackburnBenjamin J. Coe. (2011) Syntheses, Electronic Structures, and Dichroic Behavior of Dinuclear Cyclopalladated Complexes of Push−Pull Azobenzenes. Organometallics 30:8, pages 2212-2222.
Crossref
Sergio Lentijo, Jesús A. Miguel & Pablo Espinet. (2011) Cyclopalladated Complexes of Perylene Imine: Formation of Acetato-Bridged Dinuclear Complexes with 6,6- and 5,6-Membered Metallacycles. Organometallics 30:5, pages 1059-1066.
Crossref
Kanniyappan Gopi, Natesan Thirupathi & Munirathinam Nethaji. (2011) Synthesis, Reactivity, Structural Aspects, and Solution Dynamics of Cyclopalladated Compounds of N,N′,N′′ -Tris(2-anisyl)guanidine . Organometallics 30:3, pages 572-583.
Crossref
Digna Vázquez-García, Alberto Fernández, Margarita López-Torres, Antonio Rodríguez, Nina Gómez-Blanco, Carlos Viader, José M. Vila & Jesús J. Fernández. (2011) Reactivity of C(sp2)-Pd and C(sp3)-Pd bonded palladacycles with diphosphines. Crystal and molecular structure of the novel A-frame complex [{Pd[2,5-Me2C6H2C(H) N(2,4,6-Me3C6H2)-C6]}2(μ-Ph2PCH2PPh2)2(μ-Cl)][PF6]. Journal of Organometallic Chemistry 696:3, pages 764-771.
Crossref
Darko Babić, Manda Ćurić & David M. Smith. (2011) Computational study of the cyclopalladation mechanism of azobenzene with PdCl2 in N,N-dimethylformamide. Journal of Organometallic Chemistry 696:3, pages 661-669.
Crossref
Sergio Lentijo, Jesús A. Miguel & Pablo Espinet. (2011) Cyclopalladated complexes of perylene imine: mononuclear complexes with five- or six-membered metallacycles. Dalton Transactions 40:29, pages 7602.
Crossref
Liladhar B. Kumbhare, Amey Wadawale, Sanjio S. Zade & Vimal K. Jain. (2011) Oligomeric allyl-palladium(ii) complexes of β-substituted ethylselenolates: Syntheses, structures and thermal decomposition. Dalton Transactions 40:31, pages 7957.
Crossref
Blanca López, Aleix Rodriguez, David Santos, Joan Albert, Xavier Ariza, Jordi Garcia & Jaume Granell. (2011) Preparation of benzolactams by Pd( ii )-catalyzed carbonylation of N-unprotected arylethylamines . Chem. Commun. 47:3, pages 1054-1056.
Crossref
David Lapointe & Keith Fagnou. (2010) Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway. Chemistry Letters 39:11, pages 1118-1126.
Crossref
José Vicente, Isabel Saura-Llamas, José-Antonio García-López & Delia Bautista. (2010) Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines. Organometallics 29:19, pages 4320-4338.
Crossref
David Pou, Concepción López, Sonia Pérez, Xavier Solans, Mercè Font‐Bardía, Piet W. N. M. van Leeuwen & Gino P. F. van Strijdonck. (2010) Study on the Lability of the σ(Pd–S) Bond of Novel Palladacycles with [C(sp 2 ,ferrocene),N,S(thienyl)] – Pincer Ligands . European Journal of Inorganic Chemistry 2010:11, pages 1642-1648.
Crossref
Martin Albrecht. (2009) Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends. Chemical Reviews 110:2, pages 576-623.
Crossref
Irina P. Smoliakova, Jessica L. Wood, Valeria A. Stepanova & Relindis Y. Mawo. (2010) Solvent-free cyclopalladation on silica gel. Journal of Organometallic Chemistry 695:3, pages 360-364.
Crossref
José Vicente, José Antonio Abad, María-José López-Sáez & Peter G. Jones. (2009) Carbopalladation of Maleate and Fumarate Esters and 1,1-Dimethylallene with Ortho-Substituted Aryl Palladium Complexes. Organometallics 29:2, pages 409-416.
Crossref
Joan AlbertMargarita CrespoJaume GranellJudit RodríguezJavier ZafrillaTeresa CalvetMercè Font-BardiaXavier Solans. (2009) Cyclopalladation of Schiff Bases from Methyl Esters of α-Amino Acids. Unexpected Activation of the O−Me Bond with Formation of a Bianionic Tridentate Metallacycle. Organometallics 29:1, pages 214-225.
Crossref
José Vicente, José‐Antonio Abad, María‐José López‐Sáez, Peter G. Jones & Delia Bautista. (2009) Reactivity of ortho ‐Substituted Aryl–Palladium Complexes towards Carbodiimides, Isothiocyanates, Nitriles, and Cyanamides . Chemistry – A European Journal 16:2, pages 661-676.
Crossref
Sonia Nieto, Palmira Arnau, Elena Serrano, Rafael Navarro, Tatiana Soler, Carlos Cativiela & Esteban P. Urriolabeitia. (2009) Functionalization of Methyl ( R )-Phenylglycinate Through Orthopalladation: C−Hal, C−O, C−N, and C−C Bond Coupling . Inorganic Chemistry 48:24, pages 11963-11975.
Crossref
José Vicente, Eloísa Martínez-Viviente, María-José Fernández-Rodríguez & Peter G. Jones. (2009) Palladium-Assisted Formation of an Indacenediide Ligand. Organometallics 28:20, pages 5845-5847.
Crossref
José Vicente, Rashmi V. Shenoy, Eloísa Martínez-Viviente & Peter G. Jones. (2009) Synthesis of Mono-, Di-, and Tripalladated 1,3,5-Benzenetricarboxaldehyde Complexes. Organometallics 28:20, pages 6101-6108.
Crossref
Kara J. Stowers & Melanie S. Sanford. (2009) Mechanistic Comparison between Pd-Catalyzed Ligand-Directed C−H Chlorination and C−H Acetoxylation. Organic Letters 11:20, pages 4584-4587.
Crossref
Joan Albert, Lucía D’Andrea, Graciela García, Jaume Granell, Abdelouahab Rahmouni, Mercè Font-Bardia & Teresa Calvet. (2009) Cyclopalladation of (E)-N-(2,6-dichlorobenzylidene)(naphthalen-1-yl)methanamine: Synthesis and X-ray molecular structure of [κ2-N,C1-η2-C3,C4-Pd{(PhCCPh)2–C10H6–CH2–NCH–(2,6-Cl2C6H3)}Cl]·CH2Cl2. Polyhedron 28:13, pages 2559-2564.
Crossref
José Vicente, Isabel Saura-Llamas, Juana Turpín, Delia Bautista, Carmen Ramírez de Arellano & Peter G. Jones. (2009) Insertion of One, Two, and Three Molecules of Alkyne into the Pd−C Bond of Ortho-palladated Primary and Secondary Arylalkylamines. Organometallics 28:14, pages 4175-4195.
Crossref
Judit Rodríguez, Javier Zafrilla, Joan Albert, Margarita Crespo, Jaume Granell, Teresa Calvet & Mercè Font-Bardia. (2009) Cyclometallated platinum(II) compounds with imine ligands derived from amino acids: Synthesis and oxidative addition reactions. Journal of Organometallic Chemistry 694:16, pages 2467-2475.
Crossref
Jesús J. Fernández, Alberto Fernández, Margarita López-Torres, Digna Vázquez-García, Antonio Rodríguez, Alexis Varela & José M. Vila. (2009) Cyclometallated complexes derived from pyrimidin- and pyridazinehydrazones: Structural evidence of intermolecular “chelate metal ring” π–π interactions. Journal of Organometallic Chemistry 694:14, pages 2234-2245.
Crossref
Raquel Martín, Margarita Crespo, Mercè Font-Bardia & Teresa Calvet. (2009) Steric promotion in the cycloplatination of primary amines. Polyhedron 28:7, pages 1369-1373.
Crossref
Jackson M. Chitanda, J. Wilson Quail & Stephen R. Foley. (2009) Mononuclear palladacycles of N,N′-diaryl-2-iminoisoindolines. Journal of Organometallic Chemistry 694:9-10, pages 1542-1548.
Crossref
Chen Xu, Zhi-Qiang Wang, Wei-Jun Fu, Xin-Hua Lou, Ying-Fei Li, Fei-Fei Cen, Hong-Ji Ma & Bao-Ming Ji. (2009) Synthesis and Structural Characterization of Monophosphine-Cyclopalladated Ferrocenylpyrimidine Complexes and Reusable Catalytic System for Amination of Hindered Aryl Chlorides in PEG-400. Organometallics 28:6, pages 1909-1916.
Crossref
José Vicente, Isabel Saura-Llamas, José-Antonio García-López & Delia Bautista. (2008) Insertion of Isocyanides, Isothiocyanates, and Carbon Monoxide into the Pd−C Bond of Cyclopalladated Complexes Containing Primary Arylalkylamines of Biological and Pharmaceutical Significance. Synthesis of Lactams and Cyclic Amidinium Salts Related to the Isoquinoline, Benzo[ g ]isoquinoline, and β-Carboline Nuclei . Organometallics 28:2, pages 448-464.
Crossref
Joan Albert, Lucía D’Andrea, Jesús Bautista, Asensio González, Jaume Granell, Mercè Font-Bardia & Teresa Calvet. (2008) Unexpected Structure of Palladacycles Containing Carboxylated Schiff Bases. Synthesis of Some Water-Soluble Metallacycles. Organometallics 27:19, pages 5108-5117.
Crossref
Valery V. Dunina, Eugeniya I. Turubanova, Michail V. Livantsov, Konstantin A. Lyssenko & Yuri K. Grishin. (2008) New approach to chiral phosphapalladacycles: first optically active phosphinite PC-palladacycle with non-metallocenic planar chirality. Tetrahedron: Asymmetry 19:13, pages 1519-1522.
Crossref
Jose Vicente & Isabel Saura‐Llamas. (2008) ChemInform Abstract: ortho‐Palladation of Primary Amines: The Myth Dispelled. ChemInform 39:13.
Crossref
Jackson M. Chitanda, Demyan E. Prokopchuk, J. Wilson Quail & Stephen R. Foley. (2008) Synthesis of palladacycles employing iminoisoindolines as monoanionic bidentate ligands. Dalton Transactions:43, pages 6023.
Crossref

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.