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Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 1, 1982 - Issue 5
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Original Articles

Bipyridine Radical Ions

Pages 293-311 | Published online: 19 Dec 2006

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Read on this site (2)

RichardJ. Watts. (1991) Photogeneration of Strong One- and Two-Electron Redox Agents from Transition Metal Complexes. Comments on Inorganic Chemistry 11:5-6, pages 303-337.
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Arnd Vogler & Horst Kunkely. (1990) Optical Ligand to Ligand Charge Transfer of Metal Complexes Including Ligand-Based Mixed-Valence Systems. Comments on Inorganic Chemistry 9:3-4, pages 201-220.
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Articles from other publishers (75)

Chayan Pandya & Akella Sivaramakrishna. (2024) Organoruthenium-bipyridyl complexes – A platform for diverse chemistry and applications. Coordination Chemistry Reviews 504, pages 215655.
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Miona Glišić, Petar P. Čanović, Milan M. Zarić, Radica S. Živković Zarić, Andjela Franich, Snežana Rajković & Marija Živković. (2024) The cytotoxicity of palladium (II) complexes containing 1,2‐ or 1,4‐diazine bridging ligands on squamous cell carcinoma cells in vitro: Insights in the mechanisms of action. Applied Organometallic Chemistry.
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Ge Mu, Ryan B. Gaynor, Baylee N. McIntyre, Bruno Donnadieu & Sidney E. Creutz. (2023) Synthesis and Characterization of Bipyridyl-(Imidazole)n Mn(II) Compounds and Their Evaluation as Potential Precatalysts for Water Oxidation. Molecules 28:20, pages 7221.
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Emily R. Mikeska, Alexander C. Ervin, Kaihua Zhang, Gabriel M. Benitez, Samuel M. R. Powell, Allen G. Oliver, Victor W. Day, Marco Caricato, Chelsea G. Comadoll & James D. Blakemore. (2023) Evidence for Uranium(VI/V) Redox Supported by 2,2′-Bipyridyl-6,6′-dicarboxylate. Inorganic Chemistry 62:39, pages 16131-16148.
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Yunjung Baek, Adam Reinhold, Lei Tian, Philip D. Jeffrey, Gregory D. Scholes & Robert R. Knowles. (2023) Singly Reduced Iridium Chromophores: Synthesis, Characterization, and Photochemistry. Journal of the American Chemical Society 145:23, pages 12499-12508.
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Kirk P. Smith, Rohit Rungta, Andrew A. Wang & Charles W. Monroe. (2023) Multi-Week Cycling of a Nonaqueous Flow Battery Using Tris-Bipyridine Iron (II) Triflate without Additional Supporting Electrolyte. Journal of The Electrochemical Society 170:6, pages 060510.
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Wade C. Henke, Yun Peng, Alex A. Meier, Etsuko Fujita, David C. Grills, Dmitry E. Polyansky & James D. Blakemore. (2023) Mechanistic roles of metal- and ligand-protonated species in hydrogen evolution with [Cp*Rh] complexes. Proceedings of the National Academy of Sciences 120:21.
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Mélanie Guyot, Marie-Noëlle Lalloz, Juan S. Aguirre-Araque, Guillaume Rogez, Cyrille Costentin & Sylvie Chardon-Noblat. (2022) Rhenium Carbonyl Molecular Catalysts for CO 2 Electroreduction: Effects on Catalysis of Bipyridine Substituents Mimicking Anchorage Functions to Modify Electrodes . Inorganic Chemistry 61:40, pages 16072-16080.
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Wade C. Henke, Jonah P. Stiel, Victor W. Day & James D. Blakemore. (2022) Evidence for Charge Delocalization in Diazafluorene Ligands Supporting Low‐Valent [Cp*Rh] Complexes**. Chemistry – A European Journal 28:9.
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Fabio Marchetti & Guido Pampaloni. 2022. Comprehensive Organometallic Chemistry IV. Comprehensive Organometallic Chemistry IV 299 351 .
Daniel A. W. Ross, Joseph I. Mapley, Andrew P. Cording, Roan A. S. Vasdev, C. John McAdam, Keith C. Gordon & James D. Crowley. (2021) 6,6′-Ditriphenylamine-2,2′-bipyridine: Coordination Chemistry and Electrochemical and Photophysical Properties. Inorganic Chemistry 60:16, pages 11852-11865.
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Bin Li, Blaise L. Geoghegan, Christoph Wölper, George E. CutsailIIIIII & Stephan Schulz. (2021) Redox Activity of Noninnocent 2,2′-Bipyridine in Zinc Complexes: An Experimental and Theoretical Study. ACS Omega 6:28, pages 18325-18332.
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Wade C. Henke, Tyler A. Kerr, Thomas R. Sheridan, Lawrence M. Henling, Michael K. Takase, Victor W. Day, Harry B. Gray & James D. Blakemore. (2021) Synthesis, structural studies, and redox chemistry of bimetallic [Mn(CO) 3 ] and [Re(CO) 3 ] complexes . Dalton Transactions 50:8, pages 2746-2756.
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Julie A. Hopkins Leseberg, Davide Lionetti, Victor W. Day & James D. Blakemore. (2021) Electrochemical Kinetic Study of [Cp*Rh] Complexes Supported by Bis(2-pyridyl)methane Ligands. Organometallics 40:2, pages 266-277.
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Danh X. Ngo, Sarah A. Del Ciello, Alexandra T. Barth, Ryan G. Hadt, Robert H. Grubbs, Harry B. Gray & Brendon J. McNicholas. (2020) Electronic Structures, Spectroscopy, and Electrochemistry of [M(diimine)(CN-BR 3 ) 4 ] 2– (M = Fe, Ru; R = Ph, C 6 F 5 ) Complexes . Inorganic Chemistry 59:14, pages 9594-9604.
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Kristjan Kunnus, Lin Li, Charles J. Titus, Sang Jun Lee, Marco E. Reinhard, Sergey Koroidov, Kasper S. Kjær, Kiryong Hong, Kathryn Ledbetter, William B. Doriese, Galen C. O'Neil, Daniel S. Swetz, Joel N. Ullom, Dale Li, Kent Irwin, Dennis Nordlund, Amy A. Cordones & Kelly J. Gaffney. (2020) Chemical control of competing electron transfer pathways in iron tetracyano-polypyridyl photosensitizers. Chemical Science 11:17, pages 4360-4373.
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Robert L. Halbach, Grégory Nocton, Jorge I. Amaro-Estrada, Laurent Maron, Corwin H. Booth & Richard A. Andersen. (2019) Understanding the Multiconfigurational Ground and Excited States in Lanthanide Tetrakis Bipyridine Complexes from Experimental and CASSCF Computational Studies. Inorganic Chemistry 58:18, pages 12083-12098.
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Sarat Chandra Patra, Amit Saha Roy, Saswati Banerjee, Ananya Banerjee, Krishna Das Saha, Ranjan Bhadra, Kausikisankar Pramanik & Prasanta Ghosh. (2019) Palladium( ii ) and platinum( ii ) complexes of glyoxalbis( N -aryl)osazone: molecular and electronic structures, anti-microbial activities and DNA-binding study . New Journal of Chemistry 43:25, pages 9891-9901.
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Julie A. Hopkins, Davide Lionetti, Victor W. Day & James D. Blakemore. (2018) Chemical and Electrochemical Properties of [Cp*Rh] Complexes Supported by a Hybrid Phosphine-Imine Ligand. Organometallics 38:6, pages 1300-1310.
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Emily A. Boyd, Davide Lionetti, Wade C. Henke, Victor W. Day & James D. Blakemore. (2018) Preparation, Characterization, and Electrochemical Activation of a Model [Cp*Rh] Hydride. Inorganic Chemistry 58:6, pages 3606-3615.
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William Moore, Wade Henke, Davide Lionetti, Victor Day & James Blakemore. (2018) Single-Electron Redox Chemistry on the [Cp*Rh] Platform Enabled by a Nitrated Bipyridyl Ligand. Molecules 23:11, pages 2857.
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Chelsea M. Taliaferro, Evgeny O. Danilov & Felix N. Castellano. (2018) Ultrafast Dynamics of the Metal-to-Ligand Charge Transfer Excited States of Ir(III) Proteo and Deutero Dihydrides. The Journal of Physical Chemistry A 122:18, pages 4430-4436.
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M. L. Czyz, G. K. Weragoda, R. Monaghan, T. U. Connell, M. Brzozowski, A. D. Scully, J. Burton, D. W. Lupton & A. Polyzos. (2018) A visible-light photocatalytic thiolation of aryl, heteroaryl and vinyl iodides. Organic & Biomolecular Chemistry 16:9, pages 1543-1551.
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Davide Lionetti, Victor W. Day, Benedikt Lassalle-Kaiser & James D. Blakemore. (2018) Multiple binding modes of an unconjugated bis(pyridine) ligand stabilize low-valent [Cp*Rh] complexes. Chemical Communications 54:14, pages 1694-1697.
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Wade C. Henke, Davide Lionetti, William N. G. Moore, Julie A. Hopkins, Victor W. Day & James D. Blakemore. (2017) Ligand Substituents Govern the Efficiency and Mechanistic Path of Hydrogen Production with [Cp*Rh] Catalysts. ChemSusChem 10:22, pages 4589-4598.
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Samantha I. Johnson, Harry B. Gray, James D. Blakemore & William A. GoddardIIIIII. (2017) Role of Ligand Protonation in Dihydrogen Evolution from a Pentamethylcyclopentadienyl Rhodium Catalyst. Inorganic Chemistry 56:18, pages 11375-11386.
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Yun Peng, Mario V. Ramos-Garcés, Davide Lionetti & James D. Blakemore. (2017) Structural and Electrochemical Consequences of [Cp*] Ligand Protonation. Inorganic Chemistry 56:17, pages 10824-10831.
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Michael W. Rosenzweig, Frank W. Heinemann, Laurent Maron & Karsten Meyer. (2017) Molecular and Electronic Structures of Eight-Coordinate Uranium Bipyridine Complexes: A Rare Example of a Bipy 2– Ligand Coordinated to a U 4+ Ion . Inorganic Chemistry 56:5, pages 2792-2800.
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Xia Wang, Indre Thiel, Alexey Fedorov, Christophe Copéret, Victor Mougel & Marc Fontecave. (2017) Site-isolated manganese carbonyl on bipyridine-functionalities of periodic mesoporous organosilicas: efficient CO 2 photoreduction and detection of key reaction intermediates . Chemical Science 8:12, pages 8204-8213.
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Pinaki Saha, Debasish Samanta & Prasanta Ghosh. (2017) Glyoxalbis(2-methylmercaptoanil) complexes of nickel and ruthenium: radical versus non-radical states. New Journal of Chemistry 41:3, pages 1149-1159.
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Amanda E. King, S. Chantal E. Stieber, Neil J. Henson, Stosh A. Kozimor, Brian L. Scott, Nathan C. Smythe, Andrew D. Sutton & John C. Gordon. (2016) Ni(bpy)(cod): A Convenient Entryway into the Efficient Hydroboration of Ketones, Aldehydes, and Imines. European Journal of Inorganic Chemistry 2016:11, pages 1635-1640.
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Pablo J. Cabrera, Xingyi Yang, James A. Suttil, Rachel E. M. Brooner, Levi T. Thompson & Melanie S. Sanford. (2015) Evaluation of Tris-Bipyridine Chromium Complexes for Flow Battery Applications: Impact of Bipyridine Ligand Structure on Solubility and Electrochemistry. Inorganic Chemistry 54:21, pages 10214-10223.
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Simon Meister, Richard O. Reithmeier, Martin Tschurl, Ueli Heiz & Bernhard Rieger. (2015) Unraveling Side Reactions in the Photocatalytic Reduction of CO 2 : Evidence for Light‐Induced Deactivation Processes in Homogeneous Photocatalysis . ChemCatChem 7:4, pages 690-697.
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Sarat Chandra Patra, Thomas Weyhermüller & Prasanta Ghosh. (2014) Ruthenium, Rhodium, Osmium, and Iridium Complexes of Osazones (Osazones = Bis-Arylhydrazones of Glyoxal): Radical versus Nonradical States. Inorganic Chemistry 53:5, pages 2427-2440.
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Sarat Chandra Patra, Amit Saha Roy, Vadivelu Manivannan, Thomas Weyhermüller & Prasanta Ghosh. (2014) Ruthenium, osmium and rhodium complexes of 1,4-diaryl 1,4-diazabutadiene: radical versus non-radical states. Dalton Trans. 43:36, pages 13731-13741.
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Anant R. Kapdi & Ian J. S. Fairlamb. (2014) Anti-cancer palladium complexes: a focus on PdX 2 L 2 , palladacycles and related complexes . Chem. Soc. Rev. 43:13, pages 4751-4777.
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Tao Yu, Daniel Ping‐Kuen Tsang, Vonika Ka‐Man Au, Wai Han Lam, Mei‐Yee Chan & Vivian Wing‐Wah Yam. (2013) Deep Red to Near‐Infrared Emitting Rhenium(I) Complexes: Synthesis, Characterization, Electrochemistry, Photophysics, and Electroluminescence Studies. Chemistry – A European Journal 19:40, pages 13418-13427.
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Michael Nippe, Rony S. Khnayzer, Julien A. Panetier, David Z. Zee, Babatunde S. Olaiya, Martin Head-Gordon, Christopher J. Chang, Felix N. Castellano & Jeffrey R. Long. (2013) Catalytic proton reduction with transition metal complexes of the redox-active ligand bpy2PYMe. Chemical Science 4:10, pages 3934.
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Thomas R. Dugan, Eckhard Bill, K. Cory MacLeod, Gemma J. Christian, Ryan E. Cowley, William W. Brennessel, Shengfa Ye, Frank Neese & Patrick L. Holland. (2012) Reversible C–C Bond Formation between Redox-Active Pyridine Ligands in Iron Complexes. Journal of the American Chemical Society 134:50, pages 20352-20364.
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Mark IrwinLaurence R. DoyleTobias KrämerRadovan Herchel, John E. McGradyJose M. Goicoechea. (2012) A Homologous Series of First-Row Transition-Metal Complexes of 2,2′-Bipyridine and their Ligand Radical Derivatives: Trends in Structure, Magnetism, and Bonding. Inorganic Chemistry 51:22, pages 12301-12312.
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Tufan K. Mukhopadhyay, Russell K. Feller, Francisca N. Rein, Neil J. Henson, Nathan C. Smythe, Ryan J. Trovitch & John C. Gordon. (2012) Investigation of formally zerovalent Triphos iron complexes. Chemical Communications 48:69, pages 8670.
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Jillian L. Dempsey, Jay R. Winkler & Harry B. Gray. (2011) Redox reactivity of photogenerated osmium(ii) complexes. Dalton Transactions 40:40, pages 10633.
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Jinzhu Chen, David J. Szalda, Etsuko Fujita & Carol Creutz. (2010) Iron(II) and Ruthenium(II) Complexes Containing P, N, and H Ligands: Structure, Spectroscopy, Electrochemistry, and Reactivity. Inorganic Chemistry 49:20, pages 9380-9391.
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Ashley M. McDaniel, Huan-Wei Tseng, Niels H. Damrauer & Matthew P. Shores. (2010) Synthesis and Solution Phase Characterization of Strongly Photooxidizing Heteroleptic Cr(III) Tris-Dipyridyl Complexes. Inorganic Chemistry 49:17, pages 7981-7991.
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Mark IrwinRhiannon K. JenkinsMark S. DenningTobias KrämerFernande Grandjean, Gary J. Long, Radovan Herchel, John E. McGradyJose M. Goicoechea. (2010) Experimental and Computational Study of the Structural and Electronic Properties of Fe II (2,2′-bipyridine)(mes) 2 and [Fe II (2,2′-bipyridine)(mes) 2 ] − , a Complex Containing a 2,2′-Bipyridyl Radical Anion . Inorganic Chemistry 49:13, pages 6160-6171.
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Edward Gore-RandallMark IrwinMark S. DenningJose M. Goicoechea. (2009) Synthesis and Characterization of Alkali-Metal Salts of 2,2′- and 2,4′-Bipyridyl Radicals and Dianions. Inorganic Chemistry 48:17, pages 8304-8316.
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Karl A. Tupper & T. Don Tilley. (2005) Synthesis and characterization of scandium complexes with reduced ligands: Crystal structures of Cp∗ScI2, [Cp∗ScI(bpy)]2, and [Cp∗ScCl(bpy)]2. Journal of Organometallic Chemistry 690:7, pages 1689-1698.
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George R. Newkome, Anil K. Patri, Elisabeth Holder & Ulrich S. Schubert. (2004) Synthesis of 2,2′‐Bipyridines: Versatile Building Blocks for Sexy Architectures and Functional Nanomaterials. European Journal of Organic Chemistry 2004:2, pages 235-254.
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Tomoyoshi Suenobu, Dirk M. Guldi, Seiji Ogo & Shunichi Fukuzumi. (2003) Excited‐State Deprotonation and H/D Exchange of an Iridium Hydride Complex. Angewandte Chemie International Edition 42:44, pages 5492-5495.
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